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Highly Dispersed Palladium Nanoparticle-Loaded Magnetic Catalyst (FeS@EP–AG–Pd) for Suzuki Reaction in Water

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Abstract

In this work, an efficient epichlorohydrin–aminoguanidine-modified Fe3O4@SiO2 magnetic nanoparticles (FeS@EP–AG–Pd) with highly dispersed Palladium nanoparticles (Pd NPs) was reported for Suzuki reaction in water. After preparation of Fe3O4@SiO2 (FeS), special epichlorohydrin–aminoguanidine linker as a ligand with high content of heteroatoms was covalently bonded onto the FeS MNPs to increase their electron density. PdII ions were then loaded on surface of FeS@EP–AG MNPs and reduced for achieving the uniformly dispersed Pd NPs. FeS@EP–AG–Pd MNPs were performed in Suzuki reaction as an efficient catalyst in water as a green non-toxic solvent. Magnetically separable and recyclable FeS@EP–AG–Pd MNPs were then fully characterized by FTIR, SEM, TEM, TGA, VSM, XRD, and ICP–OES. The heterogeneous catalyst could also easily be recovered and reused with no loss of activity over 6 cycles.

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Acknowledgements

The authors gratefully acknowledged for partially financial support of this study (Grant No. 3/41258) by Research Council of Ferdowsi University of Mashhad.

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Authors and Affiliations

  1. Department of Chemistry, Ferdowsi University of Mashhad, Mashhad, 91775-1436, Islamic Republic of Iran

    Iraj Sarvi, Mostafa Gholizadeh & Mohammad Izadyar

Authors
  1. Iraj Sarvi
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  2. Mostafa Gholizadeh
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  3. Mohammad Izadyar
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Corresponding author

Correspondence to Mostafa Gholizadeh.

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Sarvi, I., Gholizadeh, M. & Izadyar, M. Highly Dispersed Palladium Nanoparticle-Loaded Magnetic Catalyst (FeS@EP–AG–Pd) for Suzuki Reaction in Water. Catal Lett 147, 1162–1171 (2017). https://doi.org/10.1007/s10562-017-2009-5

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