Abstract
Abstract
Silica and three mixed silica oxides (silica–alumina, silica–niobia, and silica–zirconia) with nominally 5 wt% of the added element (Al, Nb and Zr) were prepared and used as supports for dispersing monometallic Pt-nanoparticles. The presence of the second oxide component on the silica surface influenced some properties of the final samples, like surface area and acidity. The samples acidity was measured in a recirculation adsorption line with 2-phenylethylamine probe, by performing the titrations both in cyclohexane and in methanol to gather the intrinsic and effective acidity, respectively. The acid site density of silica–alumina was the highest compared with the other oxides; in general, an important decrease of acid sites density was determined in methanol. The order of the effective acidity in methanol was different from that determined in cyclohexane only for silica–zirconia and silica–niobia, confirming the peculiar acidity of Nb-oxide compounds in polar liquids: Colloidal spherical platinum nanoparticles were synthesized and then deposited (1 wt%) on the oxide supports. The obtained metallic nanophases were studied in the reduction of 5-hydroxymethylfurfural (HMF) to valuable chemicals such as dimethylfuran, dimethyltetrahydro-furan, 2-hexanol. In particular, this study focused on the impact of the acidity of the oxide supports on reaction selectivity when 2-butanol is used as solvent. When Pt is not present, Nb-doped silica is the most effective catalyst to di-hydroxymethyl furan diether (DHMFDE) derived from Meerwein–Ponndorf–Verley reaction, maintaining its Lewis character also in protic medium. In the presence of Pt, Nb-doped silica, however, presents the higher selectivity to hydrogenolysis products, 5-methyl furan (5-MF).
Graphical Abstract
Similar content being viewed by others
References
Gervasini A, Bellussi G, Fenyvesi J, Auroux A (1995) J Phys Chem 99:5117
Gervasini A, Fenyvesi J, Auroux A (1996) Langmuir 12:5356
Tanabe K, Sumiyoshi T, Shibata K, Kiyoura T, Kitagawa (1974) J Bull Chem Soc Jpn 47:1064
Seiyama T (1978) Metal oxides and their catalytic actions. Kodansha Scientific Books, Tokyo
Carniti P, Gervasini A (2013) Auroux A (ed) Springer Ser Mater Sci 154 17:543
Carniti P, Gervasini A, Biella S. (2005) Adsorpt Sci Technol 23:739
Carniti P, Gervasini A, Marzo M, (2010) Catal Today 152:42
Daniel MC, Astruc D (2004) Chem Rev 104:293
Prati L, Villa A (2014) Acc Chem Res 47:855
Chan-Thaw CE, Villa A, Prati L (2015) In: Prati L, Villa A (eds) Gold catalysis: preparation, characterization, and applications. Pan Stanford Publishing, Boca Raton
Zhang HT, Ding J, Chow GM (2008) Langmuir 24:375
Carniti P, Gervasini A, Bennici S (2005) J Phys Chem B 109:1528
Silvester L, Lamonier JF, Vannier RN, Lamonier C, Capron M, Mamede AS, Pourpoint F, Gervasini A, Dumeignil F (2014) J Mater Chem A 2:11073
Campos Molina MJ, López Granados M, Gervasini A, Carniti P (2015) Catal Today 254:90
Román-Leshkov YC, Barrett J, Liu ZY, Dumesic JA (2007) Nature 447:982
Komanoya T, Nakajima K, Kitano M, Hara M (2015) J Phys Chem C 119:26540
Nowak I, Ziolek M (1999) Chem Rev 99:3603
Tanabe K. (2003) Catal Today 78:65
Ziolek M (2003) Catal Today 78:47
Carniti P, Gervasini A, Bossola F, Dal Santo V (2016) Appl Catal B 193:93
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Ly, N., Al-Shamery, K., Chan-Thaw, C.E. et al. Impact of Support Oxide Acidity in Pt-Catalyzed HMF Hydrogenation in Alcoholic Medium. Catal Lett 147, 345–359 (2017). https://doi.org/10.1007/s10562-016-1945-9
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-016-1945-9