Abstract
A series of Mg–Al layered-double hydroxides (LDHs) intercalated by sulphonato-Schiff base complexes were prepared for the selective oxidation of glycerol (GLY) with O2 as oxidant. The results revealed the LDH hosted complexes were effective catalysts, and their catalytic performance were closely related to the structures and composition of catalysts, the base environments of reaction mixtures as well as the reaction conditions. Among them, LDH hosted copper complex displayed the highest catalytic performance, and the GLY conversion could reach 82.5 with 86.1 % of the selectivity to glyceric acid (GLYAC). Moreover, the catalytic performance remained after being recycled seven times.
Graphical Abstract
LDH hosted transition metal complex catalysts were promising catalysts for the selective oxidation of GLY to glyceric acid with O2. The catalytic performance of catalysts and the product distribution were found to be closely related to the structures and composition of catalysts, the base environments of reaction mixtures as well as the reaction conditions. The best GLY conversion reached 82.5 with 86.1 % of the selectivity to GLYAC.
Similar content being viewed by others
References
Zhou CHH, Beltramini JN, Lin CHX, Xu ZHP, Lu GQ, Tanksale A (2011) Catal Sci Technol 1:111
Shul’pin GB, Kozlov YN, Shul’pina LS, Strelkova TV, Mandelli D (2010) Catal Lett 138:193
Sankar M, Dimitratos N, Knight DW, Carley AF, Tiruvalam R, Kiely CJ, Thomas D, Hutchings GJ (2009) Chem Sus Chem 2:1145
Prati L, Spontoni P, Gaiassi A (2009) Top Catal 52:288
Zhou ChH, Beltramini JN, Fan YX, Lu GQ (2008) Chem Soc Rev 37:527
Katryniok B, Kimura J, Skrzyńska E, Girardon JS, Fongarland P, Capron M, Ducoulombier R, Mimura N, Paul S, Dumeignil F (2011) Green Chem 13:1960
McMorn P, Roberts G, Hutchings GJ (1999) Catal Lett 63:193
Prati L, Villa A, Chan-Thaw CE, Arrigo R, Wang D, Su DS (2011) Faraday Discuss 152:353
Tsuji A, Rao KTV, Nishimura Sh, Takagaki A, Ebitani K (2011) Chem Sus Chem 4:542
Wang FF, Shao S, Liu CL, Xu CL, Yang RZ, Dong WS (2015) Chem Eng J 264:336
Zhang MY, Nie RF, Wang L, Shi JJ, Du WC, Hou ZY (2015) Catal Commun 59:5
Brett GL, He Q, Hammond C, Miedziak PJ, Dimitratos N, Sankar M, Herzing AA, Conte M, Lopez-Sanchez JA, Kiely ChJ, Knight DW, Taylor SH, Hutchings GJ (2011) Angew Chem Int Ed 50:1
Zope BN, Hibbitts DD, Neurock M, Davis RJ (2010) Science 330:74
Sankar M, Dimitratos N, Knight DW, Carley AF, Tiruvalam R, Kiely ChJ, Thomas D, Hutchings GJ (2009) Chem Sus Chem 2:1145
Kapkowski M, Bartczak P, Korzec M, Sitko R, Szade J, Balin K, Lelątko J, Polanski J (2014) J Catal 319:110
Skrzyńska E, Ftouni J, Mamede AS, Addad A, Trentesaux M, Girardon JS, Capron M, Dumeignil F (2014) J Mol Catal A: Chem 382:71
Savanur AP, Nandibewoor ST, Chimatadar SA (2009) Transit Met Chem 34:711
Oliveira LCA, Portilho MF, Silva AC, Taroco HA, Souza PP (2012) Appl Catal B: Envioron 117–118:29
Wang XL, Wu GD, Wang F, Ding KQ, Zhang F, Liu XF, Xue YB (2012) Catal Commun 28:73
Crotti C, Farnetti E (2015) J Mol Catal A: Chem 396:353
Oliveira VL, Morais C, Servat K, Napporn TW, Tremiliosi-Filho G, Kokoh KB (2013) J Electroanal Chem 703:56
Wu GD, Wang XL, Huang YA, Liu XF, Zhang F, Ding KQ, Yang XL (2013) J Mol Catal A: Chem 379:185
Wu GD, Wang XL, Li JP, Zhao N, Wei W, Sun YH (2008) Catal Today 131:402
Choudary BM, Ramani T, Maheswaran H, Prashant L, Ranganath KVS, Kumarb KV (2006) Adv Synth Catal 348:493
Bhattacharjee S, Anderson JA (2006) J Mol Catal A: Chem 249:103
Cantrell DG, Gillie LJ, Lee AF, Wilson K (2005) Appl Catal A: Gen 287:183
Zhou H, Zhuo GL, Jiang XZ (2006) J Mol Catal A: Chem 248:26
Cavani F, Trifiro F, Vaccari A (1991) Catal Today 11:173
Belal R, Meunier B (1988) J Mol Catal A: Chem 44:187
Aurangzeb N (1994) J Chem Soc Chem Commun 1153
Lau SH, Caps V, Yeung KW, Wong KY, Tsang SC (1999) Micropor Mesopor Mat 32:279
Torto N (2009) Bioelectrochem 76:195
Acknowledgments
The authors acknowledge the financial supports from the National Natural Science Foundation of China (21003073, 21203093), the Natural Science Foundation of Jiangsu Province (BK20141388), the Qing Lan Project of Jiangsu Province, the Academic Talents Training Project of Nanjing Institute of Technology, and the College students practice innovation training program of Jiangsu Province.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Rights and permissions
About this article
Cite this article
Wang, X., Wu, G., Liu, X. et al. Selective Oxidation of Glycerol with O2 Catalyzed by LDH Hosted Transition Metal Complexes. Catal Lett 146, 620–628 (2016). https://doi.org/10.1007/s10562-015-1687-0
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-015-1687-0