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Entangled Cu Complex Over Fe3O4@SiO2 as Supported Catalyst for Synthesis of Alkenyl Nitriles with Aromatic Aldehydes and Acetonitrile

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Abstract

An efficient, green and practical approach to synthesize alkenyl nitriles using new supported Cu(II) catalyst via aromatic aldehydes and acetonitrile was developed. The novel catalyst was characterized by FT-IR, XRD, SEM/EDX, TEM, TGA and VSM. Interestingly, the catalyst was found to be active for synthesis of alkenyl nitriles, which were readily obtained in good yields under mild conditions. But most importantly, the original catalyst could be conveniently recovered and recycled from the reaction system by applying an external magnet and reused in four cycles without significant loss in catalytic activity.

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Acknowledgments

The authors are grateful to the National Natural Science Foundation of China (21402066), the Natural Science Foundation of Jiangsu Province, China (BK2012547), (BK2012547) and (BK20140139), MOE & SAFEA for the 111 Project (B13025) for financial support.

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Authors and Affiliations

  1. The Key Laboratory of Food Colloids and Biotechnology, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi, 214122, Jiangsu, China

    Zhen Gu, Yanfang Wang, Yuan Yao, Xiaofeng Xia, Haijun Wang & Wei Li

Authors
  1. Zhen Gu
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  2. Yanfang Wang
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  3. Yuan Yao
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  4. Xiaofeng Xia
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  5. Haijun Wang
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  6. Wei Li
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Corresponding authors

Correspondence to Haijun Wang or Wei Li.

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Gu, Z., Wang, Y., Yao, Y. et al. Entangled Cu Complex Over Fe3O4@SiO2 as Supported Catalyst for Synthesis of Alkenyl Nitriles with Aromatic Aldehydes and Acetonitrile. Catal Lett 145, 2046–2054 (2015). https://doi.org/10.1007/s10562-015-1602-8

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  • DOI: https://doi.org/10.1007/s10562-015-1602-8

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