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Synthesis, Characterization, and Application of PVP-Pd NP in the Aerobic Oxidation of 5-Hydroxymethylfurfural (HMF)

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Abstract

PVP stabilized Pd nanoparticles (Pd NP) were prepared in ethylene glycol at three different NaOH/Pd ratios and characterized by XRD, transmission electron microscopy (TEM), and small-angle X-ray scattering (SAXS). The Pd NP were applied in the aerobic oxidation of 5-hydroxymethylfurfural (HMF) into 2,5-furandicarboxylic acid (FDCA) in an alkaline aqueous solution (T = 90 °C, pO2 = 1 bar). The highest yield of FDCA (90 %) was obtained in the presence of Pd NP with a mean diameter of 1.8 nm, prepared with a 4:1 molar ratio of NaOH:Pd. Thus prepared Pd NP could be stored in their alkaline synthesis solution under ambient conditions and showed consistently good catalytic performances after up to one month storage time, in contrast to Pd NP prepared with 2:1 and 1:1 ratio and stored in neutral or acidic environment.

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Acknowledgments

Financial support by Tishreen University Latakia (Syria) and the German Academic Exchange Service (DAAD) (scholarship for B.S.) is gratefully acknowledged.

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Authors and Affiliations

  1. Leibniz-Institut für Katalyse e.V an der Universität Rostock, Albert-Einstein-Str. 29a, 18059, Rostock, Germany

    Baraa Siyo, Matthias Schneider, Marga-Martina Pohl, Peter Langer & Norbert Steinfeldt

  2. Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059, Rostock, Germany

    Baraa Siyo & Peter Langer

Authors
  1. Baraa Siyo
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  2. Matthias Schneider
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  3. Marga-Martina Pohl
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  4. Peter Langer
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  5. Norbert Steinfeldt
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Correspondence to Norbert Steinfeldt.

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Siyo, B., Schneider, M., Pohl, MM. et al. Synthesis, Characterization, and Application of PVP-Pd NP in the Aerobic Oxidation of 5-Hydroxymethylfurfural (HMF). Catal Lett 144, 498–506 (2014). https://doi.org/10.1007/s10562-013-1186-0

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  • DOI: https://doi.org/10.1007/s10562-013-1186-0

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