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Water-Promoted Palladium Catalysts for Methane Oxidation

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Abstract

A water-tolerant, active and high-selective palladium catalyst, (2,2′-bipyridine) dichloropalladium(II) is proposed for the oxidation of methane to a methanol derivative with molecular oxygen as the oxidant at temperatures below 120 °C, and its activity can be increased by three times at 100 °C when the volume ratio of water to CF3COOH solvent is 1:5. In addition, the addition of perfluorooctane can enhance the yield of methanol further.

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Acknowledgments

This study was supported by the National Natural Sciences Foundation of China (Grant No. 20776013), Beijing Natural Science Foundation (Grant No. 2102034) and the Special Fund of Basic Research in Central Universities (Grant No. JD1107). We thank Prof. Chao Lu for kindly providing gas chromatograph machine.

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Authors and Affiliations

  1. Department of Environmental Science and Engineering, Beijing University of Chemical Technology, Beijing, 100019, People’s Republic of China

    Jiongliang Yuan & Yan Wang

  2. Department of Experimental Teaching, Tianjin University of Traditional Chinese Medicine, and Tianjin Key Laboratory of Chemistry and Analysis of Chinese Materia Medica, Tianjin, 300193, People’s Republic of China

    Cunjiang Hao

Authors
  1. Jiongliang Yuan
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  2. Yan Wang
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  3. Cunjiang Hao
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Correspondence to Jiongliang Yuan.

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Yuan, J., Wang, Y. & Hao, C. Water-Promoted Palladium Catalysts for Methane Oxidation. Catal Lett 143, 610–615 (2013). https://doi.org/10.1007/s10562-013-1000-z

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