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Molybdenum Oxoanions as Dispersing Agents in the Preparation of Pd/C Catalysts for the Selective Oxidation of Glyoxal

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Abstract

Catalysts Pd/C were prepared in the presence of Mo oxoanions. The size of Mo precursor and the electrostatic interactions with the Pd precursor during the synthesis were found to be responsible for high Pd dispersions. These catalysts were very active for glyoxal oxidation into glyoxalic acid.

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References

  1. Pope MT, Muller A (1991) Angew Chem Int Ed Engl 30:34

    Article  Google Scholar 

  2. Jeannin YP (1998) Chem Rev 98:51

    Article  CAS  Google Scholar 

  3. Gouzerh P, Proust A (1998) Chem Rev 98:77

    Article  CAS  Google Scholar 

  4. Dolbecq A, Dumas E, Mayer CR, Mialane P (2010) Chem Rev 110:6009

    Article  CAS  Google Scholar 

  5. Mestl G, Ilkenhans T, Spielbauer D, Dieterle M, Timpe O, Kröhnert J, Jentoft F, Knözinger H, Schlögl R (2001) Appl Catal A 210:13

    Article  CAS  Google Scholar 

  6. Okuhara T, Mizuno N, Misono M (1996) Adv Catal 41:113

    Article  CAS  Google Scholar 

  7. Mizuno N, Misono M (1998) Chem Rev 98:199

    Article  CAS  Google Scholar 

  8. Kozhevnikov IV (1998) Chem Rev 98:171

    Article  CAS  Google Scholar 

  9. Fawang C, Changwen H (2011) Prog Chem 23:19

    Google Scholar 

  10. Putaj P, Lefebvre F (2011) Coord Chem Rev 255:1642

    Article  CAS  Google Scholar 

  11. Xianjun L, Ruiling L, Zhen L, Chungu X (2008) Prog Chem 20:469

    Google Scholar 

  12. Mizuno N, Kamata K, Yamaguchi K (2010) Top Catal 53:876

    Article  CAS  Google Scholar 

  13. Matveev KI, Odyakov VF, Zhizhina EG (1996) J Mol Catal A 114:151

    Article  CAS  Google Scholar 

  14. Corma A (1995) Chem Rev 95:559

    Article  CAS  Google Scholar 

  15. Ueda T, Kotsuki H (2008) Heterocycles 76:73

    Article  CAS  Google Scholar 

  16. Rocchiccioli-Deltcheff C, Aouissi A, Launay S, Fournier M (1996) J Mol Catal A 114:331

    Article  CAS  Google Scholar 

  17. Bardin BB, Davis RJ (2000) Appl Catal A 200:219

    Article  CAS  Google Scholar 

  18. Rives A, Payen E, Hubaut R, Vázquez P, Pizzio L, Cáceres C, Blanco M (2001) Catal Lett 71:193

    Article  CAS  Google Scholar 

  19. Kozhevnikov IV, Sinnema A, Jansen RJJ, van Bekkum H (1994) Catal Lett 27:187

    Article  CAS  Google Scholar 

  20. Timofeeva MN, Matrosova MM, Reshetenko TV, Avdeeva LB, Budneva AA, Ayupov AB, Paukshtis EA, Chuvilin AL, Volodin AV, Likholobov VA (2004) J Mol Catal A 211:131

    Article  CAS  Google Scholar 

  21. Pizzio LR, Vázquez PG, Cáceres CV, Blanco MN (2003) Appl Catal A 256:125

    Article  CAS  Google Scholar 

  22. Garrigue P, Delville M-H, Labrugère C, Cloutet E, Kulesza PJ, Morand J-P, Kuhn A (2004) Chem Mater 16:2984

    Article  CAS  Google Scholar 

  23. Solar JM, Derbyshire FJ, de Beer VHJ, Radovic LR (1991) J Catal 129:330

    Article  CAS  Google Scholar 

  24. Timofeeva MN, Matrosova MM, Il’inich GN, Reshetenko TV, Avdeeva LB, Kvon RI, Chuvilin AL, Budneva AA, Paukshtis EA, Likholobov VA (2003) Kinet Catal 44:778

    Article  CAS  Google Scholar 

  25. Gall RD, Hill CL, Walker JE (1996) Chem Mater 8:2523

    Article  CAS  Google Scholar 

  26. Cui Z, Kulesza PJ, Li CM, Xing W, Jiang SP (2011) Int J Hydrogen Energy 36:8508

    Article  CAS  Google Scholar 

  27. Regalbuto JR (2009) In: de Jong KP (ed) Synthesis of solid catalysts. Wiley-VCH, Weinheim

    Google Scholar 

  28. Deffernez A, Hermans S, Devillers M (2007) J Phys Chem C 111:9448

    Article  CAS  Google Scholar 

  29. Hermans S, Deffernez A, Devillers M (2010) Catal Today 157:77

    Article  CAS  Google Scholar 

  30. Hermans S, Deffernez A, Devillers M (2011) Appl Catal A 395:19

    Article  CAS  Google Scholar 

  31. Burmeister R, Deller K, Despeyroux B, Hatte C (1994) Patent no. EP635472-A, DE 43 24 442 C1

  32. Da Silveira RS, De Oliveira AM, Pergher SBC, Da Silva VT, Baibich IM (2009) Catal Lett 129:259

    Article  Google Scholar 

  33. Consul JMD, Costilla I, Gigola CE, Baibich IM (2008) Appl Catal A 339:151

    Article  CAS  Google Scholar 

  34. Fernandez MB, Piqueras CM, Tonetto GM, Crapiste G, Damiani DE (2005) J Mol Catal A 233:133

    Article  CAS  Google Scholar 

  35. Zina MS, Ghorbel A (2004) Solid State Sci 6:973

    Article  Google Scholar 

  36. Pawelec B, Navarro RM, Campos-Martin JM, Agudo AL, Vasudevan PT, Fierro JLG (2003) Catal Today 86:73

    Article  CAS  Google Scholar 

  37. Tonetto GM, Damiani DE (2003) J Mol Catal A 202:289

    Article  CAS  Google Scholar 

  38. Sica AM, Baibich IM, Gigola CE (2003) J Mol Catal A 195:225

    Article  CAS  Google Scholar 

  39. Li ZR, Fu YL, Jiang M, Meng M, Xie YN, Hu TD, Liu T (2000) Catal Lett 65:43

    Article  CAS  Google Scholar 

  40. Noronha FB, Baldanza MAS, Schmal M (1999) J Catal 188:270

    Article  CAS  Google Scholar 

  41. Konopny LW, Juan A, Damiani DE (1998) Appl Catal B Environ 15:115

    Article  CAS  Google Scholar 

  42. Pavlova SN, Maksimovskaya RI, Kuznetsova LI (1991) Kinet Catal 32:361

    Google Scholar 

  43. Gallezot P, de Mésanstourne R, Christidis Y, Mattioda G, Schouteeten A (1992) J Catal 133:479

    Article  CAS  Google Scholar 

  44. Alardin F, Delmon B, Ruiz P, Devillers M (2000) Catal Today 61:255

    Article  CAS  Google Scholar 

  45. Alardin F, Ruiz P, Delmon B, Devillers M (2001) Appl Catal A 215:125

    Article  CAS  Google Scholar 

  46. Alardin F, Wullens H, Hermans S, Devillers M (2005) J Mol Catal A 225:79

    Article  CAS  Google Scholar 

  47. Hermans S, Devillers M (2005) Catal Lett 99:55

    Article  CAS  Google Scholar 

  48. Deffernez A, Hermans S, Devillers M (2005) Appl Catal A 282:303

    Article  CAS  Google Scholar 

  49. Mattioda G, Christidis Y (1989) Ullmann’s encyclopedia of industrial chemistry, 5th ed., vol. A 12. VCH, Weinheim, p 495

    Google Scholar 

  50. Hermans S, Wenkin M, Devillers M (1998) J Mol Catal A 136:59

    Article  CAS  Google Scholar 

  51. Besson M, Gallezot P (2000) Catal Today 57:127

    Article  CAS  Google Scholar 

  52. Detusheva LG, Kuznetsova LI, Fedotov MA, Dovlitova LS, Vlasov AA, Likholobov VA, Malakhov VV (2003) Russ J Inorg Chem 48:1685

    Google Scholar 

  53. Schweglerl MA, Vinke P, van der Eijk M, van Bekkum H (1992) Appl Catal A 80:41

    Article  Google Scholar 

  54. Jansen RJJ, van Veldhuizen HM, van Bekkum H (1996) J Mol Catal A 107:241

    Article  CAS  Google Scholar 

  55. de la Puente G, Centeno A, Gil A, Grange P (1998) J Colloid Interface Sci 202:155

    Article  Google Scholar 

  56. Martin Gullon A, Prado Burguete C, Rodriguez Reinoso F (1993) Carbon 31:1099

    Article  CAS  Google Scholar 

  57. Rondon S, Wilkinson WR, Proctor A, Houalla M, Hercules DM (1995) J Phys Chem 99:16709

    Article  CAS  Google Scholar 

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Acknowledgments

The authors gratefully acknowledge financial support from the Belgian National Fund for Scientific Research (FNRS, Brussels) and the “Communauté Française de Belgique” (Concerted Research Programme). They also wish to thank G. Ploegaerts and V. Dubois (Institut Meurice, Brussels) for ICP and chemisorption measurements, J. -F. Statsijns for technical assistance, and the NORIT firm for supplying the carbon support.

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Authors and Affiliations

  1. Institute of Condensed Matter and Nanosciences (IMCN), Université catholique de Louvain, Place Louis Pasteur, 1/3, 1348, Louvain-la-Neuve, Belgium

    S. Hermans, F. Thiltges, A. Deffernez & M. Devillers

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  1. S. Hermans
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  2. F. Thiltges
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  3. A. Deffernez
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  4. M. Devillers
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Correspondence to S. Hermans.

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Hermans, S., Thiltges, F., Deffernez, A. et al. Molybdenum Oxoanions as Dispersing Agents in the Preparation of Pd/C Catalysts for the Selective Oxidation of Glyoxal. Catal Lett 142, 521–530 (2012). https://doi.org/10.1007/s10562-012-0804-6

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  • DOI: https://doi.org/10.1007/s10562-012-0804-6

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