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Heterogeneous Hydrothiolation of Alkynes with Thiols Catalyzed by Diphosphino-Functionalized MCM-41 Anchored Rhodium Complex

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Abstract

A novel diphosphino-functionalized MCM-41 anchored rhodium complex [MCM-41-2P-RhCl(PPh3)] was conveniently synthesized by the reaction of diphosphino-functionalized MCM-41 (MCM-41-2P) with RhCl(PPh3)3. It was found that this rhodium complex is an efficient catalyst for the hydrothiolation of terminal alkynes with thiols and can be recovered and recycled by a simple filtration of the reaction solution and used for at least ten consecutive trials without any decreases in activity.

Graphical Abstract

The diphosphino-functionalized MCM-41 anchored rhodium complex [MCM-41-2P-RhCl(PPh3)] is an efficient catalyst for the hydrothiolation of terminal alkynes with thiols and can be recovered and recycled by a simple filtration of the reaction solution and used for at least ten consecutive trials without any decreases in activity.

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Acknowledgments

We thank the National Natural Science Foundation of China (Project No. 20862008) and the Natural Science Foundation of Jiangxi Province in China (2008GQH0034, 2010GZH0062) for financial support.

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Authors and Affiliations

  1. School of Chemistry and Chemical Engineering, Guangdong Pharmaceutical University, 510006, Guangzhou, People’s Republic of China

    Hong Zhao

  2. Department of Chemistry, Jiangxi Normal University, 330022, Nanchang, People’s Republic of China

    Jian Peng & Mingzhong Cai

Authors
  1. Hong Zhao
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  2. Jian Peng
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  3. Mingzhong Cai
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Correspondence to Hong Zhao or Mingzhong Cai.

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Zhao, H., Peng, J. & Cai, M. Heterogeneous Hydrothiolation of Alkynes with Thiols Catalyzed by Diphosphino-Functionalized MCM-41 Anchored Rhodium Complex. Catal Lett 142, 138–142 (2012). https://doi.org/10.1007/s10562-011-0732-x

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  • DOI: https://doi.org/10.1007/s10562-011-0732-x

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