Skip to main content
SpringerLink
Log in

Polypyrrole–Palladium Nanocomposite-Coated Latex Particles as a Heterogeneous Catalyst in Water

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Polypyrrole–palladium nanocomposite-coated cross-linked polystyrene latex particles (PS/PPy–Pd) showed an excellent catalytic activity for Suzuki and Heck reactions in aqueous media. The PS/PPy–Pd can be recovered easily and quantitatively through the repeated uses with simple filtration and they maintain their high catalytic activities.

Graphical Abstract

Polypyrrole–palladium nanocomposite on cross-linked polystyrene latex micro-beads (PS/PPy–Pd particles) showed an excellent catalytic activity for Suzuki and Heck reactions in water and were reused without any loss of catalytic activity.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Scheme 1
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Grieco PA (1998) Organic synthesis in water. Blackie Academic & Professional, London

    Google Scholar 

  2. Li CJ (2005) Chem Rev 105:3095

    Article  CAS  Google Scholar 

  3. Li CJ, Chen L (2006) Chem Soc Rev 35:68

    Article  Google Scholar 

  4. Walsh PJ, Li H, de Parrodi CA (2007) Chem Rev 107:2503

    Article  CAS  Google Scholar 

  5. Lamblin M, Nassar-Hardy L, Hierso JC, Fouquet E, Felpin FX (2010) Adv Synth Catal 352:33

    Article  CAS  Google Scholar 

  6. Ikegami S, Hamamoto H (2009) Chem Rev 109:583

    Article  CAS  Google Scholar 

  7. Gu Y, Ogawa C, Kobayashi J, Mori Y, Kobayashi S (2006) Angew Chem Int Ed 45:7217

    Article  CAS  Google Scholar 

  8. Uozumi Y (2004) Top Curr Chem 242:77

    CAS  Google Scholar 

  9. Bergbreiter DE (2004) Top Curr Chem 242:113

    CAS  Google Scholar 

  10. Djakovitch L, Koehler K, De Vries JG (2008) Nanoparticles and catalysis. Wiley-VCH, Weinheim, pp 303–348

    Google Scholar 

  11. Ogasawara S, Kato S (2010) J Am Chem Soc 132:4608

    Article  CAS  Google Scholar 

  12. Astruc D (2007) Inorg Chem 46:1884

    Article  CAS  Google Scholar 

  13. Astruc D, Lu F, Aranzaes JR (2005) Angew Chem Int Ed 44:7852

    Article  CAS  Google Scholar 

  14. Moreno-Mañas M, Pleixats R (2003) Acc Chem Res 36:638

    Article  Google Scholar 

  15. Saha D, Chattopadhyay K, Ranu BC (2009) Tetrahedron Lett 50:1003

    Article  CAS  Google Scholar 

  16. Bhattacharya S, Srivastava A, Sengupta S (2005) Tetrahedron Lett 46:3557

    Article  CAS  Google Scholar 

  17. Sin E, Yi SS, Lee YS (2010) J Mol Catal A Chem 315:99

    Article  CAS  Google Scholar 

  18. Ohtaka A, Teratani T, Fujii R, Ikeshita K, Shimomura O, Nomura R (2009) Chem Commun 7188

  19. Ohtaka A, Tamaki Y, Igawa Y, Egami K, Shimomura O, Nomura R (2010) Tetrahedron 66:5642

    Article  CAS  Google Scholar 

  20. Bernechea M, de Jesús E, López-Mardomingo C, Terreros P (2009) Inorg Chem 48:4491

    Article  CAS  Google Scholar 

  21. Diallo AK, Ornelas C, Salmon L, Aranzaes JR, Astruc D (2007) Angew Chem Int Ed 46:8644

    Article  CAS  Google Scholar 

  22. Garcia-Martinez JC, Lezutekong R, Crooks RM (2005) J Am Chem Soc 127:5097

    Article  CAS  Google Scholar 

  23. Choudary BM, Roy M, Roy S, Kantam ML, Sreedhar B, Kumar KV (2006) Adv Synth Catal 348:1734

    Article  CAS  Google Scholar 

  24. Houdayer A, Schneider R, Billaud D, Ghanbaja J, Lambert J (2005) Appl Organomet Chem 19:1239

    Article  CAS  Google Scholar 

  25. Kantam ML, Roy M, Roy S, Sreedhar B, Madhavendra SS, Choudary BM, Lal De R (2007) Tetrahedron 63:8002

    Article  CAS  Google Scholar 

  26. Gallon BJ, Kojima RW, Kaner RB, Diaconescu PL (2007) Angew Chem Int Ed 46:7251

    Article  CAS  Google Scholar 

  27. Athawale AA, Bhagwat SV, Katre PP (2006) Sens Actuators B 114263

  28. Vasilyeva SV, Vorotyntsev MA, Bezverkhyy I, Lesniewska E, Heintz O, Chassagnon R (2008) J Phys Chem C 112:19878

    Article  CAS  Google Scholar 

  29. Harish S, Mathiyarasu J, Phani KLN, Yegnaraman V (2009) Catal Lett 128:197

    Article  CAS  Google Scholar 

  30. Bai Z, Yang L, Li L, Lv J, Wang K, Zhang J (2009) J Phys Chem C 113:10568

    Article  CAS  Google Scholar 

  31. Fujii S, Nishimura Y, Aichi A, Matsuzawa S, Nakamura Y, Akamatsu K, Nawafune H (2010) Synth Met 160:1433

    Article  CAS  Google Scholar 

  32. Fujii S, Aichi A, Akamatsu K, Nawafune H, Nakamura Y (2007) J Mater Chem 17:3777

    Article  CAS  Google Scholar 

  33. Fujii S, Matsuzawa S, Nakamura Y, Ohtaka A, Teratani T, Akamatsu K, Tsuruoka T, Nawafune H (2010) Langmuir 26:6230

    Article  CAS  Google Scholar 

  34. Lovell PA, El-Aasser MS (1997) Emulsion polymerization and emulsion polymers. Wiley, Chichester

    Google Scholar 

  35. Okubo M, Izumi J, Takekoh R (1999) Colloid Polym Sci 277:875

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was grateful to the Nanomaterials and Microdevices Research Center (NMRC) of OIT for financial and instrumental supports. The financial support of this study from Iketani Science and Technology Foundation (No. 0191107-A) is gratefully acknowledged. This work was supported in part by the Core-to-Core Program promoted by the Japan Society for the Promotion of Science (Project No. 18004). We wish to thank Prof. Kensuke Akamatsu and Prof. Hidemi Nawafune of Konan University for assistance with the TEM measurements. We also thank Dr. Tsutomu Shinagawa and Dr. Yukiyasu Kashiwagi of Osaka Municipal Technical Research Institute for the ICP-AES measurements.

Author information

Authors and Affiliations

  1. Department of Applied Chemistry, Faculty of Engineering, Osaka Institute of Technology, 5-16-1 Ohmiya Asahi-ku, Osaka, 535-8585, Japan

    Atsushi Ohtaka, Yuki Kono, Takuto Teratani, Syuji Fujii, Soichiro Matsuzawa, Yoshinobu Nakamura & Ryôki Nomura

  2. Nanomaterials and Microdevices Research Center, Osaka Institute of Technology, 5-16-1 Ohmiya, Asahi-ku, Osaka, 535-8585, Japan

    Yoshinobu Nakamura & Ryôki Nomura

Authors
  1. Atsushi Ohtaka
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yuki Kono
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Takuto Teratani
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Syuji Fujii
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Soichiro Matsuzawa
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Yoshinobu Nakamura
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Ryôki Nomura
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding authors

Correspondence to Atsushi Ohtaka or Syuji Fujii.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Ohtaka, A., Kono, Y., Teratani, T. et al. Polypyrrole–Palladium Nanocomposite-Coated Latex Particles as a Heterogeneous Catalyst in Water. Catal Lett 141, 1097–1103 (2011). https://doi.org/10.1007/s10562-011-0630-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-011-0630-2

Keywords

Search

Navigation