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Silica Functionalized Cu(I) as a Green and Recyclable Heterogeneous Catalyst for the Huisgen 1,3-Dipolar Cycloaddition in Water at Room Temperature

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Abstract

Silica functionalized Cu(I) is reported as a green and recyclable heterogeneous catalyst for the regioselective synthesis of 1,4-disubstituted-1,2,3-triazoles via Huisgen 1,3-dipolar cycloaddition reaction between terminal alkynes, benzyl/allyl/alkyl halides and NaN3 in water at room temperature. The azide intermediate do not need to be isolated, which make this procedure highly economical. Further, silica functionalized Cu(I) could be recovered by simple filtration and recycled up to 7 consecutive runs without loss of significant activity. The catalyst is characterized by FTIR, thermal analysis, SEM, TEM and AAS.

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Acknowledgement

We are grateful to SAIF, Punjab University, Chandigarh for SEM and TEM; Head, Institute Instrumentation Centre, Indian Institute of Technology, Roorkee for TGA; and SAIF, Nagpur University, Nagpur for AAS analysis.

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  1. Department of Chemistry, University of Jammu, Jammu, 180 006, India

    Tahira Shamim & Satya Paul

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  1. Tahira Shamim
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  2. Satya Paul
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Correspondence to Satya Paul.

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Shamim, T., Paul, S. Silica Functionalized Cu(I) as a Green and Recyclable Heterogeneous Catalyst for the Huisgen 1,3-Dipolar Cycloaddition in Water at Room Temperature. Catal Lett 136, 260–265 (2010). https://doi.org/10.1007/s10562-010-0330-3

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