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High-Temperature NO x Storage and Sulfur-Resistance of the Lithium-Based Lean-Burn NO x Trap Catalyst Pt/Li/TiO2–Al2O3

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Abstract

A series of lithium-based lean-burn NO x trap catalysts Pt/Li/TiO2–Al2O3 were prepared by sequential impregnation. The doping of TiO2 into the support Al2O3 significantly enhances the sulfur-resistance performance of the catalyst Pt/Li/Al2O3. On TiO2–Al2O3 mixed oxides, the Pt and lithium species are more highly dispersed, giving higher NO x storage capacity, as compared with those on Al2O3 and TiO2. In situ DRIFTS reveals that the NO x storage on Pt/Li/TiO2–Al2O3 mainly proceeds on –OLi sites forming bidentate nitrate species at 500 °C. The catalyst Pt/Li/TiO2–Al2O3 with 40% TiO2 in the support is the most promising one applicable to the lean-burn NO x abatement.

Graphical Abstract

The sulfated NSR catalyst Pt/Li/TA(40) is easier to reduce than the sulfated Pt/Ba/TA(40), showing better regeneration ability.

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References

  1. Shinjoh H, Takahashi N, Yokota K, Sugiura M (1998) Appl Catal B 15:189

    Article  CAS  Google Scholar 

  2. Matsumoto S (2004) Catal Today 90:183

    Article  CAS  Google Scholar 

  3. Li XG, Meng M, Lin PY, Fu YL, Hu TD, Xie YN, Zhang J (2003) Top Catal 22:111

    Article  Google Scholar 

  4. Takahashi N, Matsunaga S, Tanaka T, Sobukawa H, Shinjoh H (2007) Appl Catal B 77:73

    Article  CAS  Google Scholar 

  5. Chang JR, Chang SL, Lin TB (1997) J Catal 169:338

    Article  CAS  Google Scholar 

  6. Suzuki H, Muramoto R, Takahashi N (1996) Toyota Tech Rev 46:68

    CAS  Google Scholar 

  7. Uy D, Wiegand KA, O’Neill AE, Dearth MA, Weber WH (2002) J Phys Chem B 106:387

    Article  CAS  Google Scholar 

  8. Wei X, Liu X, Deeba M (2005) Appl Catal B 58:41

    Article  CAS  Google Scholar 

  9. Matsumoto S, Ikeda Y, Suzuki H, Ogai M, Miyoshi N (2000) Appl Catal B 25:115

    Article  CAS  Google Scholar 

  10. Lahousse C, Mauge F, Bacheiier J, Lavalley JC (1995) J Chem Soc Faraday Trans 91:2907

    Article  CAS  Google Scholar 

  11. Dhar GM, Srinivas BN, Rana MS, Kumar M, Maity SK (2003) Catal Today 86:45

    Article  CAS  Google Scholar 

  12. Huang WQ, Duan AJ, Zhao Z, Wan GF, Jiang GY, Dou T, Chung KH, Liu J (2008) Catal Today 131:314

    Article  CAS  Google Scholar 

  13. Mishra HK, Stanciulescu M, Charland JP, Kelly JF (2008) Appl Surf Sci 254:7098

    Article  CAS  Google Scholar 

  14. Macleod N, Cropley R, Keel JM, Lambert RM (2004) J Catal 221:20

    Article  CAS  Google Scholar 

  15. Breen JP, Marell M, Pistarino C (2002) Catal Lett 80:123

    Article  CAS  Google Scholar 

  16. Yamamoto K, Kikuchi R, Takeguchi T (2006) J Catal 238:449

    Article  CAS  Google Scholar 

  17. Escobar J, De los Reyes JA, Viveros T (2000) Ind Eng Chem Res 39:666

    Article  CAS  Google Scholar 

  18. Hirata H, Hachisuka I, Ikeda Y, Tsuji S, Matsumoto S (2001) Top Catal 16:145

    Article  Google Scholar 

  19. Hadjiivanov K, Bushev V, Kantcheva M, Klissurski D (1994) Langmuir 10:464

    Article  CAS  Google Scholar 

  20. Huang HY, Long RQ, Yang RT (2001) Appl Catal B 33:127

    Article  CAS  Google Scholar 

  21. Fridell E, Skoglundh M, Westerberg B, Johansson S, Smedler G (1999) J Catal 183:196

    Article  CAS  Google Scholar 

  22. Liu Y, Meng M, Li XG, Guo LH, Zha YQ (2008) Chem Eng Res Des 86:932

    Article  CAS  Google Scholar 

  23. Toops TJ, Smith DB, Epling WS, Parks JE, Patridge WP (2005) Appl Catal B 58:255

    Article  CAS  Google Scholar 

  24. Liu Y, Meng M, Zou ZQ, Li XG, Zha YQ (2008) Catal Commun 10:173

    Article  CAS  Google Scholar 

  25. Luo JY, Meng M, Li XG, Zha YQ (2008) Microporous Mesoporous Mater 113:277

    Article  CAS  Google Scholar 

  26. de Resende NS, Eon JG, Schmal M (1999) J Catal 183:6

    Google Scholar 

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Acknowledgements

This work is financially supported by the National Natural Science Foundation of China (No. 20876110), the Specialized Research Fund for the Doctoral Program of Higher Education of China (No. 20090032110013) and the Program of New Century Excellent Talents in University of China (No. NCET-07-0599). The authors are also grateful to the support from the Cheung Kong Scholar Program for Innovative Teams of the Ministry of Education (No. IRT0641).

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  1. Tianjin Key Laboratory of Catalysis Science and Engineering, School of Chemical Engineering and Technology, Tianjin University, 300072, Tianjin, People’s Republic of China

    Jun-Jun He, Ming Meng, Zhi-Qiang Zou & Xiao-Xia He

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  1. Jun-Jun He
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  2. Ming Meng
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  3. Zhi-Qiang Zou
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Correspondence to Ming Meng.

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He, JJ., Meng, M., Zou, ZQ. et al. High-Temperature NO x Storage and Sulfur-Resistance of the Lithium-Based Lean-Burn NO x Trap Catalyst Pt/Li/TiO2–Al2O3 . Catal Lett 136, 234–242 (2010). https://doi.org/10.1007/s10562-010-0314-3

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