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Ta(V)-Single Site BEA Zeolite by Two-Step Postsynthesis Method: Preparation and Characterization

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Abstract

Ta1.0SiBEA and Ta2.0SiBEA zeolites are prepared by a two-step postsynthesis method involving first the creation of vacant T-atom sites associated with silanol groups by dealumination of TEABEA zeolite with nitric acid and then the impregnation of the resulting SiBEA zeolite with tantalum ethoxide (Ta(OC2H5)5 precursor. This postsynthesis procedure allows to incorporate Ta into the BEA framework as isolated mononuclear Ta(V) ions and to obtain Ta(V)-single site BEA zeolite as evidenced by XRD, 29Si MAS NMR, 1H–29Si CP MAS NMR, IR, 1H MAS NMR, DR UV–Vis.

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Acknowledgment

S.D. gratefully acknowledges the CNRS (France) for financing his Research position.

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Authors and Affiliations

  1. Laboratoire de Réactivité de Surface, UPMC Univ. Paris 6, UMR 7197, 4 Place Jussieu, 75252, Paris Cedex 05, France

    Stanislaw Dzwigaj & Michel Che

  2. Laboratoire de Réactivité de Surface, CNRS, UMR 7197, 4 Place Jussieu, 75252, Paris Cedex 05, France

    Stanislaw Dzwigaj & Michel Che

  3. Laboratoire des Systèmes Interfaciaux à l’Echelle Nanométrique, UPMC Univ. Paris 6, UMR 7142, 4 Place Jussieu, 75252, Paris Cedex 05, France

    Yannick Millot

  4. Laboratoire des Systèmes Interfaciaux à l’Echelle Nanométrique, CNRS, UMR 7142, 4 Place Jussieu, 75252, Paris Cedex 05, France

    Yannick Millot

  5. Institut Universitaire de France, Paris, France

    Michel Che

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  1. Stanislaw Dzwigaj
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  2. Yannick Millot
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  3. Michel Che
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Correspondence to Stanislaw Dzwigaj.

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Dzwigaj, S., Millot, Y. & Che, M. Ta(V)-Single Site BEA Zeolite by Two-Step Postsynthesis Method: Preparation and Characterization. Catal Lett 135, 169–174 (2010). https://doi.org/10.1007/s10562-010-0284-5

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  • DOI: https://doi.org/10.1007/s10562-010-0284-5

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