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Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen over Palladium Catalyst Supported on SO3H-Functionalized SBA-15

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Abstract

Palladium catalyst supported on SO3H-functionalized SBA-15 (denoted as Pd/SO3H-SBA-15) was applied to the direct synthesis of hydrogen peroxide from hydrogen and oxygen. For comparison, palladium catalyst supported on SBA-15 (denoted as Pd/SBA-15) was also employed for the direct synthesis of hydrogen peroxide. Selectivity for hydrogen peroxide, yield for hydrogen peroxide, and final concentration of hydrogen peroxide over Pd/SO3H-SBA-15 catalyst were much higher than those over Pd/SBA-15 catalyst. The high catalytic performance of Pd/SO3H-SBA-15 catalyst was attributed to the enhanced acid amount of SO3H-SBA-15 support, which served as an alternate acid source in the direct synthesis of hydrogen peroxide from hydrogen and oxygen.

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Acknowledgments

The authors wish to acknowledge supports from Ministry of Knowledge Economy and SK Energy Corporation.

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Authors and Affiliations

  1. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, Seoul, 151-744, South Korea

    Sunyoung Park & In Kyu Song

  2. SK Energy Corporation, Yuseong-ku, Daejeon, 305-712, South Korea

    Tae Jin Kim, Young-Min Chung & Seung-Hoon Oh

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  1. Sunyoung Park
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  2. Tae Jin Kim
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  3. Young-Min Chung
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  4. Seung-Hoon Oh
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  5. In Kyu Song
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Correspondence to In Kyu Song.

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Park, S., Kim, T.J., Chung, YM. et al. Direct Synthesis of Hydrogen Peroxide from Hydrogen and Oxygen over Palladium Catalyst Supported on SO3H-Functionalized SBA-15. Catal Lett 130, 296–300 (2009). https://doi.org/10.1007/s10562-009-9990-2

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  • DOI: https://doi.org/10.1007/s10562-009-9990-2

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