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Enantioselective Hydrogenation of (E)-α-phenylcinnamic Acid over Cinchonidine-modified Pd Catalysts Supported on TiO2 and CeO2

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Abstract

The effects of the catalyst support, reaction temperature, and concentration of the modifier were examined to optimize supported Pd-catalysts and reaction conditions for the achievement of higher enantiomeric excess in the hydrogenation of (E)-α-phenylcinnamic acid. Over 90% of enantioselectivity was achieved using a cinchonidine-modified 40 wt% Pd/TiO2 catalyst at 288 K.

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Authors and Affiliations

  1. Department of Material Science, Shimane University, 1060 Nishikawatsu, Matsue, 690-8504, Japan

    Takeshi Kubota, Hiroaki Kubota, Toshihisa Kubota, Emi Moriyasu & Yasuaki Okamoto

  2. Guraduate School of Material Science, University of Hyogo, 3-2-1 Kohto, Kamigori, Ako-gun, Hyogo, 678-1297, Japan

    Takayuki Uchida, Yuriko Nitta & Takashi Sugimura

Authors
  1. Takeshi Kubota
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  2. Hiroaki Kubota
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  3. Toshihisa Kubota
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  4. Emi Moriyasu
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  5. Takayuki Uchida
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  6. Yuriko Nitta
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  7. Takashi Sugimura
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  8. Yasuaki Okamoto
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Correspondence to Yasuaki Okamoto.

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Kubota, T., Kubota, H., Kubota, T. et al. Enantioselective Hydrogenation of (E)-α-phenylcinnamic Acid over Cinchonidine-modified Pd Catalysts Supported on TiO2 and CeO2 . Catal Lett 129, 387–393 (2009). https://doi.org/10.1007/s10562-009-9852-y

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  • DOI: https://doi.org/10.1007/s10562-009-9852-y

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