Abstract
An amorphous Co-B catalyst was prepared by chemical reduction method and characterized by isothermal N2 adsorption/desorption, XRD, ICP-AES and HR-TEM. The catalytic activity of the Co-B catalyst in the hydroformylation of 1-octene was evaluated in a 100 mL stainless autoclave. Fresh amorphous Co-B catalyst showed a relatively high activity in the hydroformylation of 1-octene. The thermal stability of fresh Co-B catalyst was also examined. When fresh Co-B catalyst was thermally treated in N2 or H2 atmosphere at 200–500 °C for 2 h, the specific surface area and the catalytic activity of the Co-B catalyst decreased. When Co-B was supported on SiO2, the activity of the catalyst increased obviously. Compared with conventional supported Co/SiO2 catalyst, Co-B/SiO2 showed much higher activity than Co/SiO2. The influences of solvents and reaction conditions on the catalytic activity of the amorphous Co-B catalyst were also studied. The recycle test of the amorphous Co-B catalyst was done.
Similar content being viewed by others
References
Ungvary F (1997) Coord Chem Rev 167:233
Fell B (1998) Tenside Surfactants Detergents 35(5):326
Paulik FE (1972) Catal Rev 6:49
Beller M, Cornils B, Frohning CD, Kohlpaintner CW (1995) J Mol Catal A 104:17
Dieguez M, Pamies O, Claver C (2004) Tetrahedron Asymmetr 15(14):2113
Klingler RJ, Chen MJ, Rathke JW, Kramarz KW (2007) Organometallics 26(2):352
Lin Q, Jiang WD, Fu HY, Chen H, Li XJ (2007) Appl Catal A 328(1):83
Riisager A, Eriksen KM, Hjortkjaer J, Fehrmann R (2003) J Mol Catal A 193(1–2):259
Fu HY, Li M, Chen H, Li XJ (2006) J Mol Catal A 259(1–2):156
Fierro JLG, Merchan MD, Rojas S, Terreros P (2001) J Mol Catal A 166(2):255
Kainulainen TA, Nieme MK, Krause AOI (1997) J Mol Catal A 122:39
Kainulainen TA, Niemela MK, Krause AOI (1999) J Mol Catal A 140:173
Li B, Li X, Asami K, Fujimoto K (2003) Energy Fuels 17:810
Sordelli L, Guidotti M, Andreatta D, Vlaic G, Psaro R (2003) J Mol Catal A 204–205:509
Zhang Y, Nagasaka K, Qiu X, Tsubaki N (2004) Appl Catal A 276:103
Zhang Y, Nagasaka K, Qiu X, Tsubaki N (2005) Catal Today 104:48
Zhang H, Qiu J, Liang C, Li Z, Wang X, Wang Y, Feng Z, Li C (2005) Catal Lett 101:211
Zhu H, Ding Y, Yan L, He D, Wang T, Chen W, Lin L (2004) Chinese J Catal 25(8):653
Chen YZ, Liaw BJ, Chiang SJ (2005) Appl Catal A 284:97
Chiang SJ, Yang CH, Chen YZ, Liaw BJ (2007) Appl Catal A 326(2):180
Ma Y, Li W, Zhang M, Zhou Y, Tao K (2003) Appl Catal A 243(2):215
Ge S, Wu Z, Zhang M, Li W, Tao K (2006) Ind Eng Chem Res 45:2229
Wu C, Wu F, Bai Y, Yi BL, Zhang HM (2005) Mater Lett 59:1748
Wonterghem JV, Morup S, Koch CJW, Charles SW, Wells S (1986) Nature 322:622
Zong BN (2007) Catal Surv Asia 11:87
Ma ZY, Zhang LX, Chen RZ, Xing WH, Xu NP (2008) Chem Eng J 138:517
Jiang Z, Yang HW, Wei Z, Xie Z, Zhong WJ, Wei SQ (2005) Appl Catal A 279:165
Falbe J (1980) New synthesis with carbon monoxide. Springer, New York
He DH, Pang DC, Chen Y, Wang TE, Liu Y, Liu JY, Zhu QM (2001) J Mol Catal A 174:21
Brewester EAV, Pruett RL (1977) UCC company, US Patent 4247486
Reichardt C (1990) Solvents and solvent effects in organic chemistry. VCH, Weinheim
Massick SM, Bulttner T, Ford PC (2003) Inorg Chem 42(2):575
Goh SK, Marynick DS (2002) Organometallics 21:2262
Suvanto S, Hirva P, Pakkanen TA (2000) Surf Sci 465:277
Piacenti F, Calderazzo F, Bianchi M, Rosi L, Frediani P (1997) Organometallics 16:4235
Moroz BL, Moudrakovski IL, Likholobov VA (1996) J Mol Catal A 112:217
Usami S, Nishimura K, Koyama T, Fukushi S (1969) Bull Chem Soc Jpn 2:2966
Cornils B, Herrmann WA (1996) Applied homogeneous catalysis with organometallic compounds. VCH, Weinheim
Abboud JLM, Notario R (1999) Pure Appl Chem 71:645
Stark A, Ajam M, Green M, Raubenheimer HG, Ranwell A, Ondruschka B (2006) Adv Synth Catal 348:1934
Acknowledgments
This work is supported by the National Natural Science Foundation of China (20373031) and the Analytical Foundation of Tsinghua University, China.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ma, L., Peng, Q. & He, D. Catalytic Behaviors of Amorphous Co-B Catalysts in Hydroformylation of 1-Octene. Catal Lett 130, 137–146 (2009). https://doi.org/10.1007/s10562-009-9839-8
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10562-009-9839-8