Skip to main content
SpringerLink
Log in

Characterization of Pt/SiO2 Model Catalysts at UHV and Near Atmospheric Pressures

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Pt/SiO2 model catalyst samples, prepared under UHV conditions in a contiguous high pressure reactor cell surface analysis chamber, have been characterized via CO oxidation reaction kinetics under elevated pressure conditions (approaching 1 atm). Reaction kinetics are studied as a function of Pt coverage (θ Pt = 1–10 mL), along with measurements on a Pt(110) single crystal for direct comparison. CO desorption measurements and STM measurements on Pt/SiO2 films at T = 300 K have been obtained at various θ Pt. Kinetic results show agreement between observations on single crystal and catalyst samples, and general agreement and correlation is obtained for site calculations across the various methods. Results demonstrate the utility of well characterized model catalyst samples in obtaining qualitative and quantitative reactivity data at elevated pressures.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4

Similar content being viewed by others

References

  1. Ribeiro FH, Schach Von Wittenau AE, Bartholomew CH, Somorjai GA (1997) Catal Rev Sci Eng 39(1&2):49

    Article  CAS  Google Scholar 

  2. Bäumer M, Freund H-J (1999) Prog Surf Sci 61:127

    Article  Google Scholar 

  3. Goodman DW (2003) J Catal 216:213

    Article  CAS  Google Scholar 

  4. Henry CR (1998) Surf Sci Rep 31:231

    Article  CAS  Google Scholar 

  5. Rupprechter G (2007) Catal Today 126:3

    Article  CAS  Google Scholar 

  6. Poppa H (1993) Catal Rev Sci Eng 35(3):359

    Article  CAS  Google Scholar 

  7. Park JY, Aliaga C, Renzas JR, Lee H, Somorjai GA (2009) Catal Lett 129:1

    Article  CAS  Google Scholar 

  8. Grass ME, Zhang Y, Butcher DR, Park JY, Li Y, Bluhm H, Bratlie KM, Zhang T, Somorjai GA (2008) Angew Chem Int Ed 47:8893

    Article  CAS  Google Scholar 

  9. Altman EI, Gorte RJ (1986) Surf Sci 172:71

    Article  CAS  Google Scholar 

  10. Zafiris GS, Gorte RJ (1993) J Catal 140:418

    Article  CAS  Google Scholar 

  11. Altman EI, Gorte RJ (1988) J Catal 110:191

    Article  CAS  Google Scholar 

  12. Meusel I, Hoffmann J, Hartmann J, Libuda J, Freund H-J (2001) J Phys Chem B 105:3567

    Article  CAS  Google Scholar 

  13. Hayek K, Goller H, Penner S, Rupprechter G, Zimmermann C (2004) Catal Lett 92:1

    Article  CAS  Google Scholar 

  14. Wootsch A, Descorme C, Rousselet S, Duprez D, Templier C (2006) Appl Surf Sci 253:1310

    Article  CAS  Google Scholar 

  15. Zarraga-Colina J, Nix RM (2006) Surf Sci 600:3058

    Article  CAS  Google Scholar 

  16. McClure S, Lundwall M, Yang F, Zhou Z, Goodman DW (2009) J Phys Chem C 113:9688

    Article  CAS  Google Scholar 

  17. Szanyi J, Goodman DW (1993) Rev Sci Instrum 64:2350

    Article  CAS  Google Scholar 

  18. Chen MS, Santra AK, Goodman DW (2004) Phys Rev B 69:155404

    Article  Google Scholar 

  19. Xu X, Goodman DW (1992) Appl Phys Lett 61(7):774

    Article  CAS  Google Scholar 

  20. Chen MS, Cai Y, Yan Z, Gath KK, Axnanda S, Goodman DW (2007) Surf Sci 601:5326

    Article  CAS  Google Scholar 

  21. Gao F, Cai Y, Gath KK, Wang Y, Chen MS, Guo QL, Goodman DW (2009) J Phys Chem C 113:182

    Article  CAS  Google Scholar 

  22. Gao F, Wang Y, Cai Y, Goodman DW (2009) J Phys Chem C 113:174

    Article  CAS  Google Scholar 

  23. Berlowitz PJ, Peden CHF, Goodman DW (1988) J Phys Chem 92:5213

    Article  CAS  Google Scholar 

  24. Oh SH, Fisher GB, Carpenter JE, Goodman DW (1986) J Catal 100:360

    Article  CAS  Google Scholar 

  25. Goodman DW, Peden CHF (1986) J Phys Chem 90:4839

    Article  CAS  Google Scholar 

  26. Peden CHF, Goodman DW, Blair DS, Berlowitz PJ, Fisher GB, Oh SH (1988) J Phys Chem 92:1563

    Article  CAS  Google Scholar 

  27. Cant NW, Hicks PC, Lennon BS (1978) J Catal 54:372

    Article  CAS  Google Scholar 

  28. Cant NW (1980) J Catal 62:173

    Article  CAS  Google Scholar 

  29. McCarthy E, Zahradnik J, Kuczynski GC, Carberry JJ (1975) J Catal 39:29

    Article  CAS  Google Scholar 

  30. Akabuiro EC, Verykios XE, Lesnick L (1985) Appl Catal 14:215

    Article  Google Scholar 

  31. Gracia FJ, Bollmann L, Wolf EE, Miller JT, Kropf AJ (2003) J Catal 220:382

    Article  CAS  Google Scholar 

  32. Atalik B, Uner D (2006) J Catal 241:268

    Article  CAS  Google Scholar 

  33. Lundwall M, McClure SM, Goodman DW (in preparation)

  34. Zhu Y, Schmidt LD (1983) Surf Sci 129:107

    Article  CAS  Google Scholar 

  35. Freyer N, Kiskinova M, Pirug G, Bonzel HP (1986) Appl Phys A 39:209

    Article  Google Scholar 

  36. McCabe RW, Schmidt LD (1977) Surf Sci 66:101

    Article  CAS  Google Scholar 

  37. Engel T, Ertl G (1979) Adv Catal 28:1

    Article  CAS  Google Scholar 

  38. Hopstaken MJP, Niemantsverdriet JW (2000) J Chem Phys 113:5457

    Article  CAS  Google Scholar 

  39. Nehasil V, Stará I, Matolín V (1996) Surf Sci 352:305

    Article  Google Scholar 

  40. Szabó A, Henderson MA, Yates JT Jr (1992) J Chem Phys 96:6191

    Article  Google Scholar 

  41. Hendriksen BLM, Frenken JWM (2002) Phys Rev Lett 89:046101

    Article  CAS  Google Scholar 

  42. Hendriksen BLM, Bobaru SC, Frenken JWM (2004) Surf Sci 552:229

    Article  CAS  Google Scholar 

  43. Gustafson J, Westerström R, Mikkelsen A, Torrelles X, Balmes O, Bovet N, Andersen JN, Baddeley CJ, Lundgren E (2008) Phys Rev B 78:045423

    Article  Google Scholar 

  44. Carlsson P-A, Zhdanov VP, Skoglundh M (2006) Phys Chem 8:2703

    Article  CAS  Google Scholar 

  45. Gao F, McClure SM, Cai Y, Gath KK, Wang Y, Chen MS, Guo QL, Goodman DW (2009) Surf Sci 603:65

    Article  CAS  Google Scholar 

  46. Van Hardeveld R, Hartog F (1969) Surf Sci 15:189

    Article  Google Scholar 

Download references

Acknowledgement

We gratefully acknowledge the support for this work by the Department of Energy (DOE), Office of Basic Energy Sciences, Division of Chemical Sciences, Geosciences, and Biosciences (DE-FG02-95ER-14511), and the Robert A. Welch Foundation.

Author information

Authors and Affiliations

  1. Department of Chemistry, Texas A&M University, P.O. Box 30012, College Station, TX, 77842-3012, USA

    Sean M. McClure, M. Lundwall, Z. Zhou, F. Yang & D. W. Goodman

Authors
  1. Sean M. McClure
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. M. Lundwall
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Z. Zhou
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. F. Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. D. W. Goodman
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to D. W. Goodman.

Rights and permissions

Reprints and permissions

About this article

Cite this article

McClure, S.M., Lundwall, M., Zhou, Z. et al. Characterization of Pt/SiO2 Model Catalysts at UHV and Near Atmospheric Pressures. Catal Lett 133, 298–306 (2009). https://doi.org/10.1007/s10562-009-0180-z

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-009-0180-z

Keywords

Search

Navigation