Skip to main content
SpringerLink
Log in

Preparation and Oxidation Catalysis of H5PMo10V2O40 Catalyst Immobilized on Nitrogen-Containing Spherical Carbon

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Nitrogen-containing spherical carbon (N-SC) with a diameter of ca. 12 μm was synthesized by a hydrothermal method using melamine-formaldehyde resin as a carbon precursor. The N-SC was then modified to have a positive charge, and thus, to provide a site for the immobilization of H5PMo10V2O40 (PMo10V2) catalyst. The PMo10V2 catalyst was chemically immobilized on the surface-modified N-SC support by taking advantage of the overall negative charge of [PMo10V2O40]5−. Characterization results showed that nitrogen in the N-SC support played an important role in forming a nitrogen-derived functional group (amine group) and that PMo10V2 catalyst was chemically immobilized on the nitrogen-derived functional group of N-SC support. PMo10V2/N-SC catalyst showed a higher 2-propanol conversion than the unsupported PMo10V2 catalyst in the vapor-phase 2-propanol conversion reaction. Moreover, the PMo10V2/N-SC catalyst showed an enhanced oxidation catalytic activity (formation of acetone) and a suppressed acid catalytic activity (formation of propylene and isopropyl ether) than the unsupported PMo10V2 catalyst. The enhanced oxidation activity of PMo10V2/N-SC catalyst was due to fine dispersion of [PMo10V2O40]5− on the N-SC support formed via chemical immobilization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7

Similar content being viewed by others

References

  1. Kozhevnikov IV (1995) Catal Rev Sci Eng 37:311–352

    Article  CAS  Google Scholar 

  2. Kozhevnikov IV (1998) Chem Rev 98:171–198

    Article  CAS  Google Scholar 

  3. Okuhara T, Mizuno N, Misono M (1996) Adv Catal 41:113–252

    Article  CAS  Google Scholar 

  4. Song IK, Barteau MA (2002) Korean J Chem Eng 19:567–573

    Article  CAS  Google Scholar 

  5. Song IK, Lee JK, Lee WY (1994) Appl Catal A Gen 119:107–119

    Article  CAS  Google Scholar 

  6. Kozhevnikov IV, Sinnema A, van Bekkum H (1995) Catal Lett 34:213–221

    Article  CAS  Google Scholar 

  7. Mukai SR, Sugiyama T, Tamon H (2003) Appl Catal A Gen 256:99–105

    Article  CAS  Google Scholar 

  8. He N-Y, Woo C-S, Kim H-G, Lee H-I (2005) Appl Catal A Gen 281:167–178

    Article  CAS  Google Scholar 

  9. Kim H, Jung JC, Park DR, Lee HW, Lee J, Lee SH, Baeck S-H, Lee K-Y, Yi J, Song IK (2008) Catal Today 132:58–62

    Article  CAS  Google Scholar 

  10. Kim H, Jung JC, Park DR, Baeck S-H, Song IK (2007) Appl Catal A Gen 320:159–165

    Article  CAS  Google Scholar 

  11. Hasik M, Turek W, Stochmal E, Lapkowski M, Proń A (1994) J Catal 147:544–551

    Article  CAS  Google Scholar 

  12. Kim H, Jung JC, Yeom SH, Lee K-Y, Song IK (2006) J Mol Catal A Chem 248:21–25

    Article  CAS  Google Scholar 

  13. La KW, Kim H, Jung JC, Lee J, Park DR, Lee SH, Song IK (2007) Korean J Chem Eng 25:710–713

    Article  Google Scholar 

  14. Wang Q, Li H, Chen L, Huang X (2001) Carbon 39:2211–2214

    Article  CAS  Google Scholar 

  15. Miao J-Y, Hwang DW, Chang C-C, Lin S-H, Narasimhulu KV, Hwang L-P (2003) Diam Relat Mater 12:1368–1372

    Article  CAS  Google Scholar 

  16. Zimmerman JL, Williams R, Khabashesku VN, Margrave JL (2001) Nano Lett 1:731–734

    Article  CAS  Google Scholar 

  17. Kim P, Joo JB, Kim W, Kim J, Song IK, Yi J (2006) Catal Lett 112:213–218

    Article  CAS  Google Scholar 

  18. Hampsey JE, Hu Q, Rice L, Pang J, Wu Z, Lu Y (2005) Chem Commun 28:3606–3608

    Article  Google Scholar 

  19. Mi Y, Hu W, Dan Y, Liu Y (2008) Mater Lett 62:1194–1196

    Article  CAS  Google Scholar 

  20. Zhu Z, Li A, Zhong S, Liy F, Zhang Q (2008) J Appl Polym Sci 109:1692–1698

    Article  CAS  Google Scholar 

  21. Fuertes AB (2003) J Mater Chem 13:3085–3088

    Article  CAS  Google Scholar 

  22. Kim H, Kim P, Lee K-Y, Yeom SH, Yi J, Song IK (2006) Catal Today 111:361–365

    Article  CAS  Google Scholar 

  23. Sing KSW, Everett DH, Haul RAW, Moscou L, Pierotti RA, Rouquérol J, Siemieniewska T (1985) Pure Appl Chem 57:602–619

    Article  Google Scholar 

  24. Li ZQ, Lu CJ, Xia ZP, Zhou Y, Luo Z (2007) Carbon 45:1686–1695

    Article  CAS  Google Scholar 

  25. Lee JK, Song IK, Lee WY, Kim J-J (1996) J Mol Catal A Chem 104:311–318

    Article  CAS  Google Scholar 

Download references

Acknowledgments

This work was supported by the Korea Science and Engineering Foundation (KOSEF) grant funded by the Korea government (MEST) (No. 2009-0078115).

Author information

Authors and Affiliations

  1. School of Chemical and Biological Engineering, Institute of Chemical Processes, Seoul National University, Shinlim-dong, Kwanak-ku, Seoul, 151-744, South Korea

    Ung Gi Hong, Dong Ryul Park, Sunyoung Park, Jeong Gil Seo, Yongju Bang, Sunhwan Hwang, Min Hye Youn & In Kyu Song

Authors
  1. Ung Gi Hong
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Dong Ryul Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Sunyoung Park
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Jeong Gil Seo
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Yongju Bang
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Sunhwan Hwang
    View author publications

    You can also search for this author in PubMed Google Scholar

  7. Min Hye Youn
    View author publications

    You can also search for this author in PubMed Google Scholar

  8. In Kyu Song
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to In Kyu Song.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Hong, U.G., Park, D.R., Park, S. et al. Preparation and Oxidation Catalysis of H5PMo10V2O40 Catalyst Immobilized on Nitrogen-Containing Spherical Carbon. Catal Lett 132, 377–382 (2009). https://doi.org/10.1007/s10562-009-0118-5

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-009-0118-5

Keywords

Search

Navigation