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Conversion of Methylesters to Hydrocarbons Over Zn-Modified H-ZSM-5 Zeolite Catalyst

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Abstract

The conversion of methyloctanoate has been studied on Zn- and H-ZSM-5 catalysts. While the addition of Zn has a promoting effect in the aromatization of light alkanes, the effect is much lower when the feed is a methylester. Direct ring closure at the C adjacent to the CO group has been identified.

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Acknowledgments

This work has been partially supported by the Oklahoma Secretary of Energy, and the Oklahoma Bioenergy Center, the Thailand Research Fund (TRF) under the Royal Golden Jubilee Ph.D. programs, Center for Petroleum, Petrochemicals, and Advanced Materials (PPAM), and the Petrochemical and Environmental Catalysis Research Unit of Ratchadapiseksompote Endowment, Chulalongkorn University.

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Authors and Affiliations

  1. The Petroleum and Petrochemical College and Center for Petroleum, Petrochemicals, and Advanced Materials, Chulalongkorn University, Pathumwan, Bangkok, 10330, Thailand

    Tanate Danuthai, Siriporn Jongpatiwut, Thirasak Rirksomboon & Somchai Osuwan

  2. School of Chemical, Biological, and Materials Engineering, University of Oklahoma, Norman, OK, 73019, USA

    Daniel E. Resasco

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  1. Tanate Danuthai
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  2. Siriporn Jongpatiwut
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  3. Thirasak Rirksomboon
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  4. Somchai Osuwan
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  5. Daniel E. Resasco
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Correspondence to Daniel E. Resasco.

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Danuthai, T., Jongpatiwut, S., Rirksomboon, T. et al. Conversion of Methylesters to Hydrocarbons Over Zn-Modified H-ZSM-5 Zeolite Catalyst. Catal Lett 132, 197–204 (2009). https://doi.org/10.1007/s10562-009-0088-7

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  • DOI: https://doi.org/10.1007/s10562-009-0088-7

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