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Properties of Desilicated ZSM-5, ZSM-12, MCM-22 and ZSM-12/MCM-41 Derivatives in Isomerization of α-Pinene

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Abstract

Limited information is available on the isomerization of α-pinene proceeding on zeolites and related desilicated materials. We wish therefore to report on the title reaction proceeding over ZSM-5, ZSM-12 and MCM-22 type zeolites, parent and modified by the sodium hydroxide treatment. The NaOH solutions of various concentrations (0.05–1 M) were used as a desilicating agent. Such treatments with basic solutions were applied: (i) under atmospheric pressure, and (ii) under hydrothermal conditions. It was shown that ZSM-12 was more resistant towards the basic solutions treatment, and its structure was retained over a whole range of NaOH concentrations studied. Nitrogen sorption revealed strong influence of the desilication process on the pore structure of modified materials—the mesopores system was formed in the zeolite crystals. Finally, catalytic studies were carried out using ZSM-5, ZSM-12, MCM-22, their desilicated derivatives and a ZSM-12/MCM-41 composite material. Catalytic properties of the samples studied were affected to a large extent by the NaOH treatment.

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Acknowledgment

We are grateful to the Ministry of Science and Higher Education, Warsaw, for support (grants Nos. N2O4 1240 33 and PBZ-KBN-116/T09/2004).

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Authors and Affiliations

  1. Institute of Catalysis and Surface Chemistry, ul. Niezapominajek 8, 30-239, Krakow, Poland

    Łukasz Mokrzycki & Bogdan Sulikowski

  2. The Henryk Niewodniczański Institute of Nuclear Physics, ul. Radzikowskiego 152, 31-342, Krakow, Poland

    Zbigniew Olejniczak

Authors
  1. Łukasz Mokrzycki
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  2. Bogdan Sulikowski
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  3. Zbigniew Olejniczak
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Correspondence to Bogdan Sulikowski.

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Mokrzycki, Ł., Sulikowski, B. & Olejniczak, Z. Properties of Desilicated ZSM-5, ZSM-12, MCM-22 and ZSM-12/MCM-41 Derivatives in Isomerization of α-Pinene. Catal Lett 127, 296–303 (2009). https://doi.org/10.1007/s10562-008-9678-z

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  • DOI: https://doi.org/10.1007/s10562-008-9678-z

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