Skip to main content
SpringerLink
Log in

Oxidative Desulfurization of Model Oil over Au/Ti-MWW

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Au/Ti-MWW catalysts were prepared by the impregnation of HAuCl4 on Ti-MWW. Its structure and properties were characterized by X-ray diffraction, N2 adsorption and UV-visible. The oxidation reactions of thiophene (TH), benzothiophene (BT), dibenzothiophene (DBT) and 4,6-dimethyl-dibenzothiophene (DMDBT) were investigated at mild reaction conditions using H2O2 as oxidant. The results showed that Au loading could significantly promote the activity of Ti-MWW for oxidative desulfurization.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5

Similar content being viewed by others

References

  1. Song CS, Ma XL (2003) Appl Catal B 41:207

    Article  CAS  Google Scholar 

  2. Li C, Jiang ZX, Gao JB, Yang YX, Wang SJ, Tian FP, Sun FX, Sun XP, Ying PL, Han CR (2004) Chem Eur J 10:2277

    Article  CAS  Google Scholar 

  3. Vela S, Song CS, Engelhard MH, Chin YH (2005) Ind Eng Chem Res 44:5740

    Article  CAS  Google Scholar 

  4. Deshpande A, Bassi A, Prakash A (2005) Energy Fuels 19:28

    Article  CAS  Google Scholar 

  5. Hulea V, Fajula F, Bousquet J (2001) J Catal 198:179

    Article  CAS  Google Scholar 

  6. Wang Y, Li G, Wang XS, Jin ZZ (2005) Chin J Catal 26:567

    Google Scholar 

  7. Komintarachat C, Trakarnpruk W (2006) Ind Eng Chem Res 45:1853

    Article  CAS  Google Scholar 

  8. Shiraishi Y, Hirai T, Komasawa I (2002) J Chem Eng Jpn 35:1305

    Article  CAS  Google Scholar 

  9. Kong LY, Li G, Wang XS (2004) Catal Lett 92:163

    Article  CAS  Google Scholar 

  10. Yang LN, Qi YT, Li J, Yuan XD, Shen J (2007) J Mol Catal A 262:114

    Article  CAS  Google Scholar 

  11. Mckinley SG, Angelici RJ (2003) Energy Fuels 17:1480

    Article  CAS  Google Scholar 

  12. Hirui T, Ogawa K, Komasawa I (1996) Ind Eng Chem Res 35:586

    Article  Google Scholar 

  13. Cheng SF, Liu YM, Gao JB, Wang LL, Liu XL, Gao GH, Wu P, He MY (2006) Chin J Catal 27:547

    Article  CAS  Google Scholar 

  14. Wu P, Tatsumi T, Komatsu T, Yashima T (2001) J Phys Chem B 105:2897

    Article  CAS  Google Scholar 

  15. Kong LY, Li G, Wang XS, Wu B (2006) Energy Fuels 20:896

    Article  CAS  Google Scholar 

  16. Kalvachev YA, Hayashi T, Tsubota S, Haruta M (1999) J Catal 186:228

    Article  CAS  Google Scholar 

  17. Lv GM, Zhao R, Qian G, Qia YX, Wang XL, Suo JS (2004) Catal Lett 97:115

    Article  Google Scholar 

  18. Joshi AM, Delgass WN, Thomson KT (2006) J Phys Chem B 110:16439

    Article  CAS  Google Scholar 

  19. Wells DH Jr, Joshi AM, Nicholas JW, Thomson KT (2006) J Phys Chem B 110:14267

    Google Scholar 

  20. Zhu K, Hu JC, Richards R (2005) Catal Lett 100:195

    Article  CAS  Google Scholar 

  21. Sacaliuc E, Beale AM, Weckhuysen BM, Nijhuis TA (2007) J Catal 248:235

    Article  CAS  Google Scholar 

  22. Wu P, Tatsumi T (2002) J Phys Chem B 106:748

    Article  CAS  Google Scholar 

  23. Chowdhury B, Brovo-Suarez JJ, Mimura N, Lu JQ, Bando KK, Tsubota S, Haruta M (2006) J Phys Chem B 110:22995

    Article  CAS  Google Scholar 

Download references

Acknowledgment

The project was supported by SRF for ROCS & SEM, National Natural Science Foundation (20590366) and SINOPEC.

Author information

Authors and Affiliations

  1. Department of Chemistry, Shanghai Key Laboratory of Green Chemistry and Chemical Process, East China Normal University, Shanghai, 200062, China

    Xiaojuan Si, Shifu Cheng, Yong Lu, Guohua Gao & Ming-Yuan He

Authors
  1. Xiaojuan Si
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Shifu Cheng
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yong Lu
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Guohua Gao
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Ming-Yuan He
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Guohua Gao.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Si, X., Cheng, S., Lu, Y. et al. Oxidative Desulfurization of Model Oil over Au/Ti-MWW. Catal Lett 122, 321–324 (2008). https://doi.org/10.1007/s10562-007-9380-6

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-007-9380-6

Keywords

Search

Navigation