Fe3+ doped together with Au deposited TiO2 (Au/Fe3+–TiO2) was successfully prepared, which shows excellent photocatalytic activity for degradation of methyl orange (MO) under both UV and visible light (λ > 420 nm) illumination. Fe3+ has been confirmed by EPR to substitute for Ti4+ in the TiO2 lattice, and Au exists as Au0 on the surface of the photocatalyst indicated by the results of XRD. Fe3+ and Au have synergistic effects on improving the photocatalytic activity of TiO2. A proposed mechanism concerning the synergistic effects is discussed to explain the improvement of the photocatalytic activities.
Similar content being viewed by others
References
A. Fujishima T.N. Rao D.A. Tryk (2000) J. Photochem. Photobiol. C 1 1 Occurrence Handle1:CAS:528:DC%2BD3cXkslOjtrc%3D Occurrence Handle10.1016/S1389-5567(00)00002-2
M.R. Hoffmann S.T. Martin W. Choi D.W. Bahnemann (1995) Chem. Rev. 95 69 Occurrence Handle1:CAS:528:DyaK2MXjtF2qur4%3D Occurrence Handle10.1021/cr00033a004
C. Hu J.C. Yu Z. Hao P.K. Wong (2003) Appl. Catal. B 42 47 Occurrence Handle1:CAS:528:DC%2BD3sXisFeqs7s%3D Occurrence Handle10.1016/S0926-3373(02)00214-X
P.V. Kamat (1993) Chem. Rew. 93 267 Occurrence Handle1:CAS:528:DyaK3sXmvFOnsA%3D%3D Occurrence Handle10.1021/cr00017a013
J.C. Yu W. Ho J. Yu H. Yip P.K. Wong J. Zhao (2005) Environ. Sci. Technol. 39 1175 Occurrence Handle1:CAS:528:DC%2BD2MXksFSmsg%3D%3D Occurrence Handle10.1021/es035374h
W. Choi A. Termin M.R. Hoffmann (1994) J. Phys. Chem. 98 13669 Occurrence Handle10.1021/j100102a038
J. Zhu F. Chen J. Zhang H. Chen M. Anpo (2004) J. Mol. Catal. A 216 35 Occurrence Handle1:CAS:528:DC%2BD2cXjvVGgurw%3D
J. Zhu Z. Deng F. Chen J. Zhang H. Chen M. Anpo J. Huang L. Zhang (2006) Appl. Catal. B 62 329 Occurrence Handle1:CAS:528:DC%2BD28XptFKhtg%3D%3D Occurrence Handle10.1016/j.apcatb.2005.08.013
K. Nagaveni M.S. Hegde G. Madras (2004) J. Phys. Chem. B 108 20204 Occurrence Handle1:CAS:528:DC%2BD2cXhtVWhsb%2FK Occurrence Handle10.1021/jp047917v
S.K. Kim S.J. Hwang W. Choi (2005) J. Phys. Chem. B 109 24260 Occurrence Handle1:CAS:528:DC%2BD2MXht1KjtrrN Occurrence Handle10.1021/jp055278y
X. You F. Chen J. Zhang M. Anpo (2005) Catal. Lett. 102 247 Occurrence Handle1:CAS:528:DC%2BD2MXmtFyjsbk%3D Occurrence Handle10.1007/s10562-005-5863-5
X.Z. Li F.B. Li (2001) Environ. Sci. Technol. 35 2381 Occurrence Handle1:CAS:528:DC%2BD3MXjtFalu7Y%3D Occurrence Handle10.1021/es001752w
V. Subramanian E.E. Wolf P.V. Kamat (2003) Langmuir 19 469 Occurrence Handle1:CAS:528:DC%2BD38XpsVSnur8%3D Occurrence Handle10.1021/la026478t
R. Zanella S. Giorgio C.R. Henry C. Louis (2002) J. Phys. Chem. B 106 7634 Occurrence Handle1:CAS:528:DC%2BD38Xlt1Cjt74%3D Occurrence Handle10.1021/jp0144810
J.C.S. Wu C.H. Chen (2004) J. Photochem. Photobiol. A 163 509 Occurrence Handle1:CAS:528:DC%2BD2cXjvFOlt78%3D Occurrence Handle10.1016/j.jphotochem.2004.02.007
M.A. Debeila N.J. Coville M.S. Scurrell G.R. Hearne M.J. Witcomb (2004) J. Phys. Chem. B 108 18254 Occurrence Handle1:CAS:528:DC%2BD2cXptValtro%3D Occurrence Handle10.1021/jp048899k
M. Graetzel R.F. Howe (1990) J. Phys. Chem. 94 2566 Occurrence Handle1:CAS:528:DyaK3cXhsFShurg%3D Occurrence Handle10.1021/j100369a064
Y.C. Liu L.C. Juang (2004) Langmuir 20 6951 Occurrence Handle1:CAS:528:DC%2BD2cXlt1arsr8%3D Occurrence Handle10.1021/la049234c
A.W. Xu Y. Gao H.Q. Liu (2002) J. Catal. 207 151 Occurrence Handle1:CAS:528:DC%2BD38XislyntLw%3D Occurrence Handle10.1006/jcat.2002.3539
A.D. Paola G. Marci L. Palmisano M. Schiavello K. Uosaki S. Ikeda B. Ohtani (2002) J. Phys. Chem. B 106 637 Occurrence Handle10.1021/jp013074l
K. Mizushima M. Tanaka A. Asai S. Iida J.B. Goodenough (1979) J. Phys. Chem. Solids 40 1129 Occurrence Handle1:CAS:528:DyaL3cXhsFGnu7g%3D Occurrence Handle10.1016/0022-3697(79)90148-3
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Xiao, L., Zhang, J., Cong, Y. et al. Synergistic effects of doped Fe3+ and deposited Au on improving the photocatalytic activity of TiO2 . Catal Lett 111, 207–211 (2006). https://doi.org/10.1007/s10562-006-0149-0
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10562-006-0149-0