A colloidal ruthenium catalyst stabilized by silica was prepared through microemulsion processing. Ruthenium colloids with particle size about 4 nm are highly dispersed in silica. The selective hydrogenation of benzene to cyclohexene was studied over the catalyst. Much higher activity and selectivity was obtained compared with its supported counterparts.
Similar content being viewed by others
References
A.G. Shastri J. Schwank S. Galvagno (1986) J. Catal. 100 446 Occurrence Handle1:CAS:528:DyaL28Xlt1Wmtrk%3D Occurrence Handle10.1016/0021-9517(86)90111-9
S.C. Hu Y.W. Chen (2001) J. Chem. Technol. Biotechnol. 76 954 Occurrence Handle1:CAS:528:DC%2BD3MXmsFKrsL0%3D Occurrence Handle10.1002/jctb.454
V. Mazzieri F. Coloma-Pascual A. Arcoya P. L’Argentiere N.S. Figoli (2003) Appl. Surf. Sci. 210 222 Occurrence Handle1:CAS:528:DC%2BD3sXisFSltro%3D Occurrence Handle10.1016/S0169-4332(03)00146-6
C. Milone G. Neri A. Donato M.G. Musolino (1996) J. Catal. 159 253 Occurrence Handle1:CAS:528:DyaK28XivFCgtrk%3D Occurrence Handle10.1006/jcat.1996.0086
L. Ronchin L. Toniolo (2001) Catal. Today 66 363 Occurrence Handle1:CAS:528:DC%2BD3MXjt1Whsrc%3D Occurrence Handle10.1016/S0920-5861(00)00632-5
E.T. Silveira A.P. Umpierre L.M. Rossi G. Machado J. Morais G.V. Soares I.L.R. Baumvol S.R. Teixeira P.F.P. Fichtner J. Dupont (2004) Chem.-Eur. J. 10 3734 Occurrence Handle1:CAS:528:DC%2BD2cXmvFeju7k%3D Occurrence Handle10.1002/chem.200305765
H. Ichihashi and H. Yoshioka, J P 62142126 (1987).
O.L.A.C. Marina C. Paniel (1987) J. Mol. Catal. 39 341 Occurrence Handle10.1016/0304-5102(87)80079-2
E. Galicia G. Diaz S. Fuentes (1987) Stud. Surf. Sci. Catal. 38 11 Occurrence Handle1:CAS:528:DyaL1MXntl2q Occurrence Handle10.1016/S0167-2991(09)60638-8
S. Galvagno A. Donato G. Neri D. Pietropaolo (1988) React. Kinet. Catal. Lett. 37 443 Occurrence Handle1:CAS:528:DyaL1MXhslaksLg%3D Occurrence Handle10.1007/BF02062097
E. Dietzsch U. Rymsa D. Honicke (1999) Chem. Eng. Technol. 22 130 Occurrence Handle1:CAS:528:DyaK1MXhsVamtrg%3D Occurrence Handle10.1002/(SICI)1521-4125(199902)22:2<130::AID-CEAT130>3.0.CO;2-O
H. Imamura T. Nuruyu T. Kawasaki T. Teranishi Y. Sakata (2004) Catal. Lett. 96 185 Occurrence Handle1:CAS:528:DC%2BD2cXksFGks7s%3D Occurrence Handle10.1023/B:CATL.0000030118.52064.39
H. Imamura T. Kumai K. Nishimura T. Nuruyu Y. Sakata (2002) Catal. Lett. 82 69 Occurrence Handle1:CAS:528:DC%2BD38Xns1CmtLw%3D Occurrence Handle10.1023/A:1020613208478
F. Hartog (1963) J. Catal. 2 79 Occurrence Handle1:CAS:528:DyaF2cXislCktA%3D%3D Occurrence Handle10.1016/0021-9517(63)90142-8
W.C. Drinkard, NL 7205832 (1972).
J. Struijk M. Dangremond W.J.M. Lucasderegt J.J.F. Scholten (1992) Appl. Catal. A 83 263 Occurrence Handle1:CAS:528:DyaK38XktFShtL8%3D Occurrence Handle10.1016/0926-860X(92)85039-E
J.A. Don J.J.F. Scholten (1981) Appl. Catal. 41 146
S. Kidambi J. Dai J. Li M.L. Bruening (2004) J. Am. Chem. Soc. 126 2658 Occurrence Handle1:CAS:528:DC%2BD2cXht1Gju7w%3D Occurrence Handle10.1021/ja038804c
X.D. Mu J.Q. Meng Z.C. Li Y. Kou (2005) J. Am. Chem. Soc. 127 9694 Occurrence Handle1:CAS:528:DC%2BD2MXltVylsr0%3D Occurrence Handle10.1021/ja051803v
C.C. Cassol A.P. Umpierre G. Machado S.I. Wolke J. Dupont (2005) J. Am. Chem. Soc. 127 3298 Occurrence Handle1:CAS:528:DC%2BD2MXhtl2nt78%3D Occurrence Handle10.1021/ja0430043
J.C. Garcia-Martinez R. Lezutekong R.M. Crooks (2005) J. Am. Chem. Soc. 127 5097 Occurrence Handle1:CAS:528:DC%2BD2MXitVClsLY%3D Occurrence Handle10.1021/ja042479r
S.H. Xie M.H. Qiao H.X. Li W.J. Wang J.F. Deng (1999) Appl. Catal. A 176 129 Occurrence Handle1:CAS:528:DyaK1MXotlShsg%3D%3D Occurrence Handle10.1016/S0926-860X(98)00232-4
I. Capek (2004) Adv. Colloid Interface Sci. 110 49 Occurrence Handle1:CAS:528:DC%2BD2cXjvFOnsbk%3D Occurrence Handle10.1016/j.cis.2004.02.003
S. Eriksson U. Nylen S. Rojas M. Boutonnet (2004) Appl. Catal. A 265 207 Occurrence Handle1:CAS:528:DC%2BD2cXktVCjtLk%3D Occurrence Handle10.1016/j.apcata.2004.01.014
J.Q. Wang P.J. Guo S.R. Yan M.H. Qiao H.X. Li K.N. Fan (2004) J. Mol. Catal. A 222 229 Occurrence Handle1:CAS:528:DC%2BD2cXotlWjt78%3D Occurrence Handle10.1016/j.molcata.2004.08.009
B.Z. Zhan M.A. White T.K. Sham J.A. Pincock R.J. Doucet K.V.R. Rao K.N. Robertson T.S. Cameron (2003) J. Am. Chem. Soc. 125 2195 Occurrence Handle1:CAS:528:DC%2BD3sXntF2qug%3D%3D Occurrence Handle10.1021/ja0282691
J. Struijk J.J.F. Scholten (1992) Appl. Catal. A 82 277 Occurrence Handle1:CAS:528:DyaK38XhslKntbw%3D Occurrence Handle10.1016/0926-860X(92)85010-9
J.Q. Wang Y.Z. Wang S.H. Zhe M.H. Qiao H.X. Li K.N. Fan (2004) Appl. Catal. A 272 29 Occurrence Handle1:CAS:528:DC%2BD2cXmslWjtL8%3D Occurrence Handle10.1016/j.apcata.2004.04.038
K.H.V. Prasad K.B.S. Prasad M.M. Mallikarjunan R. Vaidyeswaran (1983) J. Catal. 84 65 Occurrence Handle1:CAS:528:DyaL2cXjtl2ntA%3D%3D Occurrence Handle10.1016/0021-9517(83)90086-6
L. Ronchin L. Toniolo (2001) Appl. Catal. A 208 77 Occurrence Handle1:CAS:528:DC%2BD3MXpt1Wruw%3D%3D Occurrence Handle10.1016/S0926-860X(00)00690-6
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Ning, J., Xu, J., Liu, J. et al. Selective Hydrogenation of Benzene to Cyclohexene Over Colloidal Ruthenium Catalyst Stabilized by Silica. Catal Lett 109, 175–180 (2006). https://doi.org/10.1007/s10562-006-0075-1
Received:
Accepted:
Issue Date:
DOI: https://doi.org/10.1007/s10562-006-0075-1