Skip to main content
SpringerLink
Log in

A New Oxidation Catalyst System using Fluorous Cobalt(II) Species in Water-supercritical Carbon dioxide (C–H free environment)

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Abstract

Stabilized water droplet dispersed in supercritical carbon dioxide fluid is demonstrated to be an excellent alternative solvent system to acetic acid for air oxidation of a number of alkyl aromatic hydrocarbons using Co(II) species at mild conditions.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. A.K. Suresh (2000) Ind. Eng. Chem. Res. 39 3958 Occurrence Handle10.1021/ie0002733 Occurrence Handle1:CAS:528:DC%2BD3cXntFentb0%3D

    Article  CAS  Google Scholar 

  2. M.P. Czytko G.K. Bub (1981) Ind. Eng. Chem. Prod. Rev. Dev. 20 481 Occurrence Handle1:CAS:528:DyaL3MXksl2ksr4%3D

    CAS  Google Scholar 

  3. W. Partenheimer (1990) Chem. Ind. 40 321 Occurrence Handle1:CAS:528:DyaK3MXhtVartLo%3D

    CAS  Google Scholar 

  4. S.A. Chavan S.B. Halligudi D. Srinivas P. Ratnasmy (2000) J. Mol. Catal. 161 49 Occurrence Handle10.1016/S1381-1169(00)00361-7 Occurrence Handle1:CAS:528:DC%2BD3cXmtF2lsL0%3D

    Article  CAS  Google Scholar 

  5. E. Sahle-Demessie M.A. Gonzalez J. Enriquez Q. Zhao (2000) Ind. Eng. Chem. Res. 39 4858 Occurrence Handle10.1021/ie000175h Occurrence Handle1:CAS:528:DC%2BD3cXnslShsr0%3D

    Article  CAS  Google Scholar 

  6. A. Baiker (1999) Chem. Rev. 99 453 Occurrence Handle10.1021/cr970090z Occurrence Handle1:CAS:528:DyaK1cXnvFensr4%3D

    Article  CAS  Google Scholar 

  7. A.M. Steele J. Zhu S.C. Tsang (2001) Catal. Lett. 73 9 Occurrence Handle10.1023/A:1009021331659 Occurrence Handle1:CAS:528:DC%2BD3MXjsl2gsb0%3D

    Article  CAS  Google Scholar 

  8. K.P. Johnston et al. (1996) Science 271 624 Occurrence Handle1:CAS:528:DyaK28XptVyisA%3D%3D

    CAS  Google Scholar 

  9. M. Ji X. Chen C.M. Wai J.L. Fulton (1999) J. Am. Chem. Soc. 121 2631 Occurrence Handle1:CAS:528:DyaK1MXhs1elsrc%3D

    CAS  Google Scholar 

  10. G.B. Jacobson C.T. Lee K.P. Johnston W. Tumas (1999) J. Am. Chem. Soc. 121 11902 Occurrence Handle10.1021/ja993208x Occurrence Handle1:CAS:528:DyaK1MXnslWiurs%3D

    Article  CAS  Google Scholar 

  11. H. Ohde C.M. Wai H. Kim J. Kim M. Ohde (2002) J. Am. Chem. Soc. 124 4540 Occurrence Handle10.1021/ja012232j Occurrence Handle1:CAS:528:DC%2BD38XisFSgt78%3D

    Article  CAS  Google Scholar 

  12. J. Zie, A. Robertson and S.C. Tsang. Chem. Commun. (2002) 2044.

  13. A.K. Suresh M.M. Sharma T. Sridhar (2000) Ind. Eng. Chem. Res. 39 3958 Occurrence Handle10.1021/ie0002733 Occurrence Handle1:CAS:528:DC%2BD3cXntFentb0%3D

    Article  CAS  Google Scholar 

  14. R.G. Zielinski S.R. Kline E.W. Kaler N. Rosov (1997) Langmuir 13 393 Occurrence Handle10.1021/la9700836

    Article  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Surface and Catalysis Research Centre, School of Chemistry, University of Reading, Whiteknights, Reading, RG6 6AD, UK

    Shik Chi Tsang, Jie Zhu & Kai Man K. Yu

Authors
  1. Shik Chi Tsang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Jie Zhu
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Kai Man K. Yu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Shik Chi Tsang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Tsang, S.C., Zhu, J. & Yu, K.M.K. A New Oxidation Catalyst System using Fluorous Cobalt(II) Species in Water-supercritical Carbon dioxide (C–H free environment). Catal Lett 106, 123–126 (2006). https://doi.org/10.1007/s10562-005-9618-0

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-005-9618-0

Keywords

Search

Navigation