Skip to main content
SpringerLink
Log in

Research on the Acidity of the Double-function Catalyst for DME Synthesis from Syngas

  • Published:
Catalysis Letters Aims and scope Submit manuscript

Two kinds of HZSM-5 zeolite (SiO2/Al2O3 = 50,300) were introduced into the STD (syngas-to-DME) reaction and the double-function catalysts containing CuO/ZnO/Al2O3 and HZSM-5 were investigated by activity evaluation and NH3-TPD. It was found that the acidity of HZSM-5 played a critical role in the performance of STD catalyst, and an appropriate acidic amount was required to obtain the best activity of STD catalyst; more and less acidic amount were both unfavorable for DME yield.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. T. Shikada K. Fujimoto M. Niyauchi H. Tominaga (1983) Appl. Catal. A: General 7 361 Occurrence Handle1:CAS:528:DyaL3sXmtFaisb8%3D

    CAS  Google Scholar 

  2. G. Cai Z. Liu R. Shi C. He L. Yang C. Sun (1995) Appl. Catal. A: General 125 29 Occurrence Handle10.1016/0926-860X(94)00291-6 Occurrence Handle1:CAS:528:DyaK2MXlsFCjtrc%3D

    Article  CAS  Google Scholar 

  3. J.B. Hansen T. Oishi (1997) Petrotech. 20 823 Occurrence Handle1:CAS:528:DyaK2sXmslKisrc%3D

    CAS  Google Scholar 

  4. Q. Ge Y. Huang F. Qiu (1998) React. Kinet. Catal. Lett. 63 137 Occurrence Handle1:CAS:528:DyaK1cXhvFaru7c%3D

    CAS  Google Scholar 

  5. K. Fujimoto, K. Asami, T. Shikada, H. Tominaga, Chem. Lett. (1984) 2051

  6. M. Jia W. Li H. Xu S. Hou C. Yu Q. Ge (2002) Catal. Lett. 84 31 Occurrence Handle10.1023/A:1021064231695 Occurrence Handle1:CAS:528:DC%2BD38Xos1Wgtbo%3D

    Article  CAS  Google Scholar 

  7. W.K. Bell and C.D. Chang, US Patent 4423155 (1983)

  8. J.L. Li X.G. Zhang T. Inui (1996) Appl. Catal. A: general 147 23 Occurrence Handle10.1016/S0926-860X(96)00208-6 Occurrence Handle1:CAS:528:DyaK28XmsVyhsLo%3D

    Article  CAS  Google Scholar 

  9. G. Qi X. Zheng J.H. Fei Z. Hou (2001) J. Mol. Catal A: Chemical 176 195 Occurrence Handle10.1016/S1381-1169(01)00257-6 Occurrence Handle1:CAS:528:DC%2BD3MXnvVSjtL0%3D

    Article  CAS  Google Scholar 

  10. Y. Fu T. Hong J. Chen A. Auroux J. Shen (2005) Thermochimica Acta 434 22 Occurrence Handle1:CAS:528:DC%2BD2MXmtlKjt74%3D

    CAS  Google Scholar 

  11. M.B. Sayed R.A. Kydd R.P. Cooney (1984) J. Catal 88 137 Occurrence Handle10.1016/0021-9517(84)90059-9 Occurrence Handle1:CAS:528:DyaL2cXksVSksrc%3D

    Article  CAS  Google Scholar 

  12. E.S. Priboczki N. Kumar T. Salmi Z. Kovacs D.Y. Murzin (2004) Catal. Lett. 93 101

    Google Scholar 

  13. J.H. Kim M.J. Park S.J. Kim O.S. Joo K.D. Jung (2004) Appl. Catal A:General 264 37 Occurrence Handle10.1016/j.apcata.2003.12.058 Occurrence Handle1:CAS:528:DC%2BD2cXjvVWktL8%3D

    Article  CAS  Google Scholar 

  14. F.S. Ramos A.M.D. Farias Particlede L.E.P. Borges J.L. Monterio M.A. Fraga E.F. Sousa-Aguiar L.G. Appel (2005) Catal. Today 101 39 Occurrence Handle10.1016/j.cattod.2004.12.007 Occurrence Handle1:CAS:528:DC%2BD2MXjs1Snu7o%3D

    Article  CAS  Google Scholar 

  15. D. Mao W. Yang J. Xia (2005) J. Catal 230 140 Occurrence Handle10.1016/j.jcat.2004.12.007 Occurrence Handle1:CAS:528:DC%2BD2MXht1Kqur4%3D

    Article  CAS  Google Scholar 

  16. T. Takeguechi K. Yanagisawa T. Inui (2000) Appl. Catal. A: General 192 201

    Google Scholar 

  17. Q. Ge Y. Huang F. Qiu (1998) Appl. Catal. A: General 167 23 Occurrence Handle10.1016/S0926-860X(97)00290-1 Occurrence Handle1:CAS:528:DyaK1cXktl2nsA%3D%3D

    Article  CAS  Google Scholar 

  18. Z. Liu, J. Liao, J. Tan, D. Li and S. Huagong(China) 28 (1999) 236

Download references

Author information

Authors and Affiliations

  1. Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian, 116023, P. R. China

    Ligang Wang, Yue Qi, Yingxu Wei, Deren Fang, Shuanghe Meng & Zhongmin Liu

  2. Graduate School of Chinese Academy of Sciences, Beijing, 100039, P. R. China

    Ligang Wang

Authors
  1. Ligang Wang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Yue Qi
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Yingxu Wei
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Deren Fang
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. Shuanghe Meng
    View author publications

    You can also search for this author in PubMed Google Scholar

  6. Zhongmin Liu
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Zhongmin Liu.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Wang, L., Qi, Y., Wei, Y. et al. Research on the Acidity of the Double-function Catalyst for DME Synthesis from Syngas. Catal Lett 106, 61–66 (2006). https://doi.org/10.1007/s10562-005-9191-6

Download citation

  • Received:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10562-005-9191-6

Keywords

Search

Navigation