A new general method to heterogenise porphyrins and different metalloporphyrins (Co, Fe) on silica, mesoporous MCM-41 and delaminated zeolites ITQ-2 and ITQ-6 yields stable materials, which act as active catalysts for the electrochemical oxygen reduction, without catalyst desorption from the electrode.
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Fuerte, A., Corma, A., Iglesias, M. et al. A cooperative effect between support and the heterogenised metalloporphyrins on electrocatalytic oxygen reduction. Catal Lett 101, 99–103 (2005). https://doi.org/10.1007/s10562-004-3756-7
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DOI: https://doi.org/10.1007/s10562-004-3756-7