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Catalytic oxidation of sulfides in middle distillates from medium-sulfur crude

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Chemistry and Technology of Fuels and Oils Aims and scope

Abstract

The catalytic properties of acids, metal compounds, and carbonyl compounds in reactions of oxidation of medium-sulfur crude diesel cut sulfides with hydrogen peroxide are examined. Comparative data on the effectiveness of these catalysts are reported. The mechanisms of formation of sulfoxides and sulfones with these catalysts are generalized. The possible mechanism of the effect of the catalysts is discussed. Optimum reactor designs which ensure minimal residence time of diesel cut sulfides in the reaction zone with effective heat and mass exchange are described.

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References

  1. G. F. Bol’shakov, Organosulfur Compounds in Petroleum [in Russian], Nauka, Novosibirsk (1986).

    Google Scholar 

  2. C. W. Cumper and A. I. Vogel, J. Chem. Soc., No. 5, 3521–3525 (1959).

  3. F. M. Collins, A. R. Lucy, and C. Sharp, J. Mol. Catal., 117, No. 12, 397–403 (1997).

    Article  CAS  Google Scholar 

  4. E. L. Robert, S. R. Alkis, J. D. Stephen, et al., Hydrocarb. Proc., 80, No. 5, 817–824 (2001).

    Google Scholar 

  5. V. S. Nikitina, N. K. Lyapina, and F. G. Sattarova, Neftekhimiya, 11, No. 2, 264–269 (1971).

    CAS  Google Scholar 

  6. G. D. Gal’pern, T. S. Bobruiskaya, E. S. Brodskii, et al., Ibid., 10, No. 5, 741–745 (1970).

    CAS  Google Scholar 

  7. R. M. Masagutor, E. A. Kruglov, J. N. Popov, et al., in: Tenth Intern. Sympos. on the Organic Chemistry of Sulphur, Univ. College of North Wales, Bangor (1982), pp. 129–131.

    Google Scholar 

  8. N. K. Lyapina, Chemistry and Physical Chemistry of Organosulfur Compounds in Petroleum Distillates [in Russian], Nauka, Moscow (1980).

    Google Scholar 

  9. E. N. Karaulova, Chemistry of Petroleum Sulfides [in Russian], Nauka, Moscow (1970).

    Google Scholar 

  10. A. Kh. Sharipov, I. S. Faizrakhmanov, and Z. A. Suleimanova, Khim. Tekhnol. Topl. Masel, No. 5, 40–42 (2001).

  11. V. L. Antonovskii, Advances in the Chemistry of Organic Peroxides [in Russian], TsNIITEneftekhim, Moscow (1992).

    Google Scholar 

  12. A. Kh. Sharipov, Z. A. Suleimanova, I. S. Faizrakhmanov, et all., Neftekhimiya, 31, No. 1, 86–92 (1991).

    CAS  Google Scholar 

  13. A. A. Khitrik, R. Sh. Latypov, and T. P. Burmistrova, Ibid., 16, No. 2, 289–292 (1976).

    Google Scholar 

  14. A. Kh. Sharipov, V. R. Nigmatullin, I. R. Nigmatullin, et al., Fabrication of Concentrates of Organosulfur Compounds from Petroleum Feedstock [in Russian], GOSNITI, Moscow (2002).

    Google Scholar 

  15. F. J. Hughes and D. S. Martin, J. Phys. Chem., 59, No. 5, 410–421 (1955).

    Article  CAS  Google Scholar 

  16. V. A. Lunenok-Burmakina and A. G. Miroshnichenko, Zh. Neorg. Khim., No. 12, 3273–3276 (1967).

  17. R. R. Samatov and A. Kh. Sharipov, Neftepererab. Neftekhim., No. 2, 32–35 (2002).

  18. T. P. Burmistrova, V. G. Ivanov, A. A. Emekeev, et al., in: Proceedings of the XVI Conference on Chemistry and Technology of Organic Sulfur Compounds and Medium-Sulfur Crude Oils, Riga, Institute of Organic Synthesis, Academy of Sciences of the Latvian SSR, June 12–16, 1984 [in Russian], Zinatne, Riga (1984), pp. 24–26.

    Google Scholar 

  19. G. A. Tolstikov, Hydroperoxide Oxidation Reactions [in Russian], Nauka, Moscow (1976), p. 136.

    Google Scholar 

  20. R. R. Samatov and A. Kh. Sharipov, Neftepererab. Neftekhim., No. 4, 37–39 (2001).

  21. A. Kh. Sharipiov, R. M. Masagutov, Z. A. Suleimanova, et al., Neftekhimiya, 30, No. 5, 692–694 (1990).

    Google Scholar 

  22. A. Kh. Sharipov, R. G. Nigmatullin, N. R. Saifullin, et al., Ibid., 35, No. 6, 628–630 (1995).

    Google Scholar 

  23. R. R. Samatov and A. Kh. Sharipov, Neftepererab. Neftekhim., No. 3, 29–31 (2002).

  24. Peter Sykes, A Guidebook to Mechanisms in Organic Chemistry, Academic Press, New York (1990).

    Google Scholar 

  25. M. E. Pozin, Hydrogen Peroxide and Peroxide Compounds [in Russian], Khimiya, Moscow (1951).

    Google Scholar 

  26. E. J. Howard and L. S. Levitt, J. Am. Chem. Soc., 75, 6170–6174 (1953).

    Article  CAS  Google Scholar 

  27. A. Kh. Sharipov, R. M. Masagutov, Z. A. Suleimanova, et al., Neftekhimiya, 29, No. 4, 551–555 (1989).

    CAS  Google Scholar 

  28. R. Adams (ed.), Organic Reactions, Vol. 9, Wiley, New York (1955), p. 1212.

    Google Scholar 

  29. A. I. Rakhimov, Chemistry and Technology of Unsubstituted Organic Peroxides [in Russian], Khimiya, Moscow (1979).

    Google Scholar 

  30. Vsevolod Karnojitzki, Les Peroxides Organiques, Hermann, Paris (1958).

    Google Scholar 

  31. A. Kh. Sharipov, Ross. Khim. Zh., 39, No. 5, 74–87 (1995).

    CAS  Google Scholar 

  32. L. I Bagal, Chemistry and Technology of Initiating Explosives [in Russian], Mashinostroenie, Moscow (1975).

    Google Scholar 

  33. V. M. Olevskii and V. R. Ruchinskii, Rotor-Membrane Heat and Mass Exchange Equipment in Russian], Khimiya, Moscow (1977).

    Google Scholar 

  34. M. E. Pozin, I. P. Mukhlenov, E. S. Tumarkina, et al., The Foam Method of Processing Gases and Liquids [in Russian], Khimiya, Moscow (1995).

    Google Scholar 

  35. E. G. Korotkova and V. P. Tutbabina, Khim. Promyshl., No. 11, 60–63 (1982).

  36. A. A. Khitrik, R. Sh. Latypov, and T. P. Burmistrova, Trudy Kaz. Khim.-Tekhnol. Inst., 50, 99–103 (1972).

    Google Scholar 

  37. A. Kh. Sharipov, V. R. Nigmatullin, I. R. Nigmatullin, et al., Organic Sulfur Compound Technology [in Russian], Tekhinform, Moscow (2001).

    Google Scholar 

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Authors and Affiliations

  1. Institute of Petrochemistry and Catalysis, Academy of Sciences of the Republic of Bashkortostan, Russia

    A. Kh. Sharipov, V. R. Nigmatullin, I. R. Nigmatullin & R. V. Zakirov

  2. Ufa Science Center, Russian Academy of Sciences, Russia

    A. Kh. Sharipov, V. R. Nigmatullin, I. R. Nigmatullin & R. V. Zakirov

  3. Institute of Petrochemical Processing, Russia

    A. Kh. Sharipov, V. R. Nigmatullin, I. R. Nigmatullin & R. V. Zakirov

Authors
  1. A. Kh. Sharipov
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  2. V. R. Nigmatullin
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  3. I. R. Nigmatullin
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  4. R. V. Zakirov
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__________

Translated from Khimiya i Tekhnologiya Topliv i Masel, No. 6, pp. 45–51, Novemmber–December, 2006.

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Sharipov, A.K., Nigmatullin, V.R., Nigmatullin, I.R. et al. Catalytic oxidation of sulfides in middle distillates from medium-sulfur crude. Chem Technol Fuels Oils 42, 451–461 (2006). https://doi.org/10.1007/s10553-006-0106-z

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