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Extension of the Theory of Volume Filling of Micropores to Adsorption in Supermicropores

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Abstract

An enhancement in characteristic energy of adsorption in large micropores is analyzed. The effect is due to the overlapping of potential fields from opposite walls of pores and to reduction of the surface adsorption film on filling the micropore volume. The effects of both factors are comparable in magnitude and dependent on the micropore size.

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Authors and Affiliations

  1. Institute of Physical Chemistry, Russian Academy of Sciences, 31 Leninsky Prosp., 119991, Moscow, Russian Federation

    N. S. Polyakov & G. A. Petukhova

Authors
  1. N. S. Polyakov
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  2. G. A. Petukhova
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Correspondence to G. A. Petukhova.

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This work is devoted to memory of the professor W. Schirmer

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Polyakov, N.S., Petukhova, G.A. Extension of the Theory of Volume Filling of Micropores to Adsorption in Supermicropores. Adsorption 11, 357–362 (2005). https://doi.org/10.1007/s10450-005-5424-7

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  • DOI: https://doi.org/10.1007/s10450-005-5424-7

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