Abstract
Rapid surface oxidation of gallium-based liquid metals complicates their manipulation but can also be used to stabilize them into 3D shapes. We show that GaInSn can readily flow within such structures. The oxide skin microchannel walls are flexible and, if ruptured, are restored through oxidation of exposed liquid metal. These flexible-wall microchannels can be repeatedly deflated and refilled with the liquid metal.
References
Boley JW, White EL, Chiu GTC, Kramer RK (2014) Direct writing of gallium–indium alloy for stretchable electronics. Adv Funct Mater 24:3501–3507
Bor J, Bartholomew C (1967) The optical properties of indium, gallium and thallium. Proc Phys Soc 90:1153
Cademartiri L et al (2012) Electrical resistance of AgTS–S(CH2)n − 1CH3/Ga2O3/EGaIn tunneling junctions. J Phys Chem C 116:10848–10860. doi:10.1021/jp212501s
Cao A, Yuen P, Lin L (2007) Microrelays with bidirectional electrothermal electromagnetic actuators and liquid metal wetted contacts. J Microelectromech Syst 16:700–708
Chiechi RC, Weiss EA, Dickey MD, Whitesides GM (2008) Eutectic gallium–indium (EGaIn): a moldable liquid metal for electrical characterization of self-assembled monolayers. Angew Chem Int Ed 120:148–150
Cumby BL, Hayes GJ, Dickey MD, Justice RS, Tabor CE, Heikenfeld JC (2012) Reconfigurable liquid metal circuits by Laplace pressure shaping. Appl Phys Lett 101:174102
Dickey MD, Chiechi RC, Larsen RJ, Weiss EA, Weitz DA, Whitesides GM (2008) Eutectic Gallium–Indium (EGaIn): a liquid metal alloy for the formation of stable structures in microchannels at room temperature. Adv Funct Mater 18:1097–1104
Doudrick K, Liu S, Klein KL, Mutunga EM, Varanasi KK, Rykaczewski K (2014) Different shades of oxide: from nanoscale wetting to imprinting of gallium-based liquid metals. Langmuir 30:6867–6877
Dumke MF, Tombrello TA, Weller RA, Housley RM, Cirlin EH (1983) Sputtering of the gallium–indium eutectic alloy in the liquid phase. Surf Sci 124:407–422. doi:10.1016/0039-6028(83)90800-2
Fassler A, Majidi C (2013) 3D structures of liquid-phase GaIn alloy embedded in PDMS with freeze casting. Lab Chip 13:4442–4450
Fassler A, Majidi C (2015) Liquid-phase metal inclusions for a conductive polymer composite. Adv Mater 27:1928–1932
Goldstein J, Newbury DE, Echlin P, Joy DC, Romig AD Jr, Lyman CE, Fiori C, Lifshin E (2012) Scanning electron microscopy and X-ray microanalysis: a text for biologists, materials scientists, and geologists. Springer, New York.
Gozen BA, Tabatabai A, Ozdoganlar OB, Majidi C (2014) High-density soft-matter electronics with micron-scale line width. Adv Mater 26:5211–5216. doi:10.1002/adma.201400502
Irshad W, Peroulis D (2009) A silicon-based galinstan magnetohydrodynamic pump. In: Power MEMS, Washinton DC, pp 127–129
Jeong SH, Hagman A, Hjort K, Jobs M, Sundqvist J, Wu Z (2012) Liquid alloy printing of microfluidic stretchable electronics. Lab Chip 12:4657–4664. doi:10.1039/C2LC40628D
Joshipura ID, Ayers HR, Majidi C, Dickey MD (2015) Methods to pattern liquid metals. J Mater Chem C 3:3834–3841. doi:10.1039/C5TC00330J
Khan MR, Hayes GJ, Zhang S, Dickey MD, Lazzi G (2012) A pressure responsive fluidic microstrip open stub resonator using a liquid metal alloy. IEEE Microw Wirel Compon Lett 22:577–579. doi:10.1109/LMWC.2012.2223754
Khan MR, Eaker CB, Bowden EF, Dickey MD (2014a) Giant and switchable surface activity of liquid metal via surface oxidation. Proc Natl Acad Sci USA 111:14047–14051
Khan MR, Trlica C, Dickey MD (2014b) Recapillarity: electrochemically controlled capillary withdrawal of a liquid metal alloy from microchannels. Adv Funct Mater 25:671–678
Khan MR, Trlica C, So J-H, Valeri M, Dickey MD (2014c) Influence of water on the interfacial behavior of gallium liquid metal alloys. ACS Appl Mater Interfaces 6:22467–22473. doi:10.1021/am506496u
Khan MR, Trlica C, Dickey MD (2015) Microfluidics: recapillarity: electrochemically controlled capillary withdrawal of a liquid metal alloy from microchannels. Adv Funct Mater 25:654
Kim H-J, Son C, Ziaie B (2008) A multiaxial stretchable interconnect using liquid-alloy-filled elastomeric microchannels. Appl Phys Lett 92:011904
Kim D, Lee D-W, Choi W, Lee J-B (2013a) A super-lyophobic 3-D PDMS channel as a novel microfluidic platform to manipulate oxidized Galinstan. J Microelectromech Syst 22:1267–1275
Kim D, Thissen P, Viner G, Lee D-W, Choi W, Chabal YJ, Lee J-B (2013b) Recovery of nonwetting characteristics by surface modification of gallium-based liquid metal droplets using hydrochloric acid vapor. ACS Appl Mater Interfaces 5:179–185. doi:10.1021/am302357t
Kim D, Lee Y, Lee D-W, Choi W, Lee J-BJ (2013b) Hydrochloric acid-impregnated paper for liquid metal microfluidics. In: 2013 The 17th international conference on transducers and Eurosensors XXVII. IEEE, pp 2620–2623
Knoblauch M, Hibberd JM, Gray JC, van Bel AJ (1999) A galinstan expansion femtosyringe for microinjection of eukaryotic organelles and prokaryotes. Nat Biotech 17:906–909
Koo C, LeBlanc BE, Kelley M, Fitzgerald HE, Huff GH, Han A (2014) Manipulating liquid metal droplets in microfluidic channels with minimized skin residues toward tunable RF applications. J Microelectromech Syst 24:1069–1076
Kramer RK, Majidi C, Sahai R, Wood RJ (2011a) Soft curvature sensors for joint angle proprioception. In: IEEE/RSJ international conference on intelligent robots and systems. IEEE, San Francisco, pp 1919–1926. doi:10.1109/IROS.2011.6094701
Kramer RK, Majidi C, Wood RJ (2011b) Wearable tactile keypad with stretchable artificial skin. IEEE/RSJ international conference on robots and Automation. IEEE, Shanghai, pp 1103–1107. doi:10.1109/ICRA.2011.5980082
Kramer RK, Boley JW, Stone HA, Weaver JC, Wood RJ (2013a) Effect of microtextured surface topography on the wetting behavior of eutectic gallium–indium alloys. Langmuir 30:533–539. doi:10.1021/la404356r
Kramer RK, Majidi C, Wood RJ (2013b) Masked deposition of gallium–indium alloys for liquid-embedded elastomer conductors. Adv Funct Mater 23:5292–5296. doi:10.1002/adfm.201203589
Kubo M, Li X, Kim C, Hashimoto M, Wiley BJ, Ham D, Whitesides GM (2010) Stretchable microfluidic radiofrequency antennas. Adv Mater 22:2749–2752. doi:10.1002/adma.200904201
Ladd C, So J-H, Muth J, Dickey MD (2013) 3D printing of free standing liquid metal microstructures. Adv Mater 25:5081–5085. doi:10.1002/adma.201301400
Li M, Yu B, Behdad N (2010) Liquid-tunable frequency selective surfaces. IEEE Microw Wirel Compon Lett 20:423–425
Li H, Yang Y, Liu J (2012) Printable tiny thermocouple by liquid metal gallium and its matching metal. Appl Phys Lett 101:073511
Li G, Parmar M, Kim D, Lee J-BJ, Lee D-W (2014) PDMS based coplanar microfluidic channels for the surface reduction of oxidized Galinstan. Lab Chip 14:200–209
Liu S, Sun X, Hildreth OJ, Rykaczewski K (2015) Design and characterization of a single channel two-liquid capacitor and its application to hyperelastic strain sensing. Lab Chip 15:1376–1384. doi:10.1039/C4LC01341G
Ma K-Q, Liu J (2007) Nano liquid-metal fluid as ultimate coolant. Phys Lett A 361:252–256
Michaud HO, Teixidor J, Lacour SP (2015) Soft metal constructs for large strain sensor membrane. Smart Mater Struct 24:035020
Mohammed MG, Dickey MD (2013) Strain-controlled diffraction of light from stretchable liquid metal micro-components. Sens Actuat A 193:246–250
Ota H et al (2014) Highly deformable liquid-state heterojunction sensors. Nat Commun. doi:10.1038/ncomms6032
Paik JK, Kramer RK, Wood RJ (2011) Stretchable circuits and sensors for robotic origami. In: IEEE/RSJ international Conference on intelligent robots and systems. IEEE, San Francisco, pp 414–420. doi:10.1109/IROS.2011.6094746
Park J et al (2012) Three-dimensional nanonetworks for giant stretchability in dielectrics and conductors. Nat Comm 3:916
Ponce Wong RD, Posner JD, Santos VJ (2012) Flexible microfluidic normal force sensor skin for tactile feedback. Sens Actuat A 179:62–69
Regan M, Pershan PS, Magnussen O, Ocko B, Deutsch M, Berman L (1997a) X-ray reflectivity studies of liquid metal and alloy surfaces. Phys Rev B 55:15874
Regan M, Tostmann H, Pershan PS, Magnussen O, DiMasi E, Ocko B, Deutsch M (1997b) X-ray study of the oxidation of liquid-gallium surfaces. Phys Rev B 55:10786
Scharmann F, Cherkashinin G, Breternitz V, Knedlik C, Hartung G, Weber T, Schaefer JA (2004) Viscosity effect on GaInSn studied by XPS. Surf Interface Anal 36:981–985. doi:10.1002/sia.1817
Sen P, Chang-Jin K (2009) Microscale liquid-metal switches—a review. IEEE Trans Ind Electron 56:1314–1330. doi:10.1109/TIE.2008.2006954
Shan F, Liu G, Lee W, Lee G, Kim I, Shin B (2005) Structural, electrical, and optical properties of transparent gallium oxide thin films grown by plasma-enhanced atomic layer deposition. J Appl Phys 98:023504
Sivan V, Tang SY, O’Mullane AP, Petersen P, Eshtiaghi N, Kalantar-zadeh K, Mitchell A (2013) Liquid metal marbles. Adv Funct Mater 23:144–152
Speckbrock G, Kamitz S, Alt M, Schmitt H (1997) Low melting gallium, indium, and tin eutectic alloys, and thermometers employing same. US Patent US6019509A
Swensen JP, Odhner LU, Araki B, Dollar AM (2014) Printing 3D electrical traces in additive manufactured parts for injection of low melting temperature metals. J Mech Robot 7:021004
Tabatabai A, Fassler A, Usiak C, Majidi C (2013) Liquid-phase gallium–indium alloy electronics with microcontact printing. Langmuir 29:6194–6200
Thelen J, Dickey MD, Ward T (2012) A study of the production and reversible stability of EGaIn liquid metal microspheres using flow focusing. Lab Chip 12:3961–3967
Vetrovec J, Litt AS, Copeland DA, Junghans J, Durkee R (2013) Liquid metal heat sink for high-power laser diodes. SPIE Proc 8605:1–7. doi:10.1117/12.2005357
Wenjiang S, Edwards RT, Kim JY (2006) Electrostatically actuated metal-droplet microswitches integrated on CMOS chip. J Microelectromech Syst 15:879–889. doi:10.1109/JMEMS.2006.878877
Wissman J, Lu T, Majidi C (2013) Soft-matter electronics with stencil lithography. IEEE Sens. doi:10.1109/ICSENS.2013.6688217
Yang H, Lightner CR, Dong L (2011) Light-emitting coaxial nanofibers. ACS Nano 6:622–628. doi:10.1021/nn204055t
Zhang Q, Liu J (2013) Nano liquid metal as an emerging functional material in energy management, conversion and storage. Nano Energy 2:863–872. doi:10.1016/j.nanoen.2013.03.002
Zhang Q, Gao Y, Liu J (2013) Atomized spraying of liquid metal droplets on desired substrate surfaces as a generalized way for ubiquitous printed electronics. Appl Phys A 1–7
Zheng Y, He Z-Z, Yang J, Liu J (2013a) Fully automatic liquid metal printer towards personal electronics manufacture arXiv:1312.0617
Zheng Y, Zhang Q, Liu J (2013b) Pervasive liquid metal based direct writing electronics with roller-ball pen. AIP Adv 3:112117-1–112117-6
Acknowledgments
KR acknowledges startup funding from Ira A. Fulton Schools of Engineering at Arizona State University.
Author information
Authors and Affiliations
Corresponding author
Electronic supplementary material
Below is the link to the electronic supplementary material.
Supplementary material 2 (AVI 4074 kb)
Rights and permissions
About this article
Cite this article
Liu, S., Sun, X., Kemme, N. et al. Can liquid metal flow in microchannels made of its own oxide skin?. Microfluid Nanofluid 20, 3 (2016). https://doi.org/10.1007/s10404-015-1665-2
Received:
Accepted:
Published:
DOI: https://doi.org/10.1007/s10404-015-1665-2