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Determination of Trace Chloroanilines in Environmental Water Samples Using Hollow Fiber-Based Liquid Phase Microextraction

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Abstract

A liquid phase microextraction method using hollow fiber to support extraction solvent was developed for enrichment of trace level chloroanilines in environmental water samples. Target analytes, 2-chloroaniline, 3-chloroaniline, 2,3-dichloroaniline, 2,4-dichloroaniline, 3,4-dichloroaniline, and 3,5-dichloroaniline were determined using gas chromatography-flame ionization detector after extraction. Experimental conditions that affect extraction efficiency were investigated and optimized. The proposed method showed a wide linear range from lower μg L−1 to 1,000 μg L−1, low detection limits (≤5.1 μg L−1), and reasonable relative standard deviations (RSDs < 13%). Feasibility of the method was evaluated by analyzing river water samples collected from the Hudson River and the East River in New York City.

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Acknowledgments

Support for undergraduate research training provided by US Department of Education Title V grant for institutional development to John Jay College and the PRISM program at John Jay College are gratefully acknowledged.

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Author notes

  1. Anna Young & Amy Yuen

    Present address: New York Police Department Forensic Laboratory, 150-14 Jamaica Avenue, Jamaica, NY, USA

  2. Guida Lai

    Present address: Macau Science Center, Avenida Dr. Sun Yat-Sen, Macau, China

Authors and Affiliations

  1. Department of Sciences, John Jay College, The City University of New York, 445 W59th Street, New York, NY, 10019, USA

    Anna Young, Guida Lai, Brian Hung, Amy Yuen & Yi He

Authors
  1. Anna Young
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  2. Guida Lai
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  3. Brian Hung
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  4. Amy Yuen
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  5. Yi He
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Corresponding author

Correspondence to Yi He.

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Young, A., Lai, G., Hung, B. et al. Determination of Trace Chloroanilines in Environmental Water Samples Using Hollow Fiber-Based Liquid Phase Microextraction. Chromatographia 74, 83–88 (2011). https://doi.org/10.1007/s10337-011-2022-6

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  • DOI: https://doi.org/10.1007/s10337-011-2022-6

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