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Synthesis and Application of High Selective Monolithic Fibers Based on Molecularly Imprinted Polymer for SPME of Trace Methamphetamine

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Abstract

A monolithic solid-phase microextraction (SPME) fiber was fabricated based on a molecularly imprinted polymer which could be coupled with gas chromatography for extraction, pre-concentration and determination of methamphetamine (MAMP). Methacrylic acid, ethylene glycol dimethacrylate and MAMP play the roles of functional monomer, cross-linker and template, respectively. The effective factors influencing the polymerization and extraction procedures were investigated and will be detailed here. The fabricated fiber was firm, inexpensive, stable, selective and durable which gives it vital importance in SPME. Selectivity of the fabricated fiber in relation to the template in solution containing MAMP, related and unrelated compounds was also investigated. Under the optimum conditions, the calibration plot was linear in the range of 50–3,500 ng mL−1 (r 2 = 0.997). The high extraction efficiency was obtained for MAMP giving a detection limit of 14 ng mL−1. The fabricated fiber was successfully applied to SPME of MAMP from human saliva samples followed by gas chromatography-flame ionization detector analysis.

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Acknowledgments

The authors would like to thank the Research Office at the University of Tabriz for financial support.

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Authors and Affiliations

  1. Laboratory of Chromatography, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Djavanshir Djozan, Mir Ali Farajzadeh & Saeed Mohammad Sorouraddin

  2. The Research Center of Antinarcotics Police, Tehran, Iran

    Tahmineh Baheri

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  1. Djavanshir Djozan
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  2. Mir Ali Farajzadeh
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  3. Saeed Mohammad Sorouraddin
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  4. Tahmineh Baheri
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Correspondence to Djavanshir Djozan.

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Djozan, D., Farajzadeh, M.A., Sorouraddin, S.M. et al. Synthesis and Application of High Selective Monolithic Fibers Based on Molecularly Imprinted Polymer for SPME of Trace Methamphetamine. Chromatographia 73, 975–983 (2011). https://doi.org/10.1007/s10337-011-1984-8

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  • DOI: https://doi.org/10.1007/s10337-011-1984-8

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