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Surface Characterization of a Novel D-π-D Type Ligand by IGC at Infinite Dilution

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Abstract

The adsorption properties and acid–base contributions to the surface energy of (E)-N-((E)-3-(4-(dimethylamino)phenyl)allylidene)-4-(4-((E)-((E))-3-(4(dimethylamino)phenyl)allylidene)amino)-3-methylnaphthalen-1-yl)-2-ethylnaphthalen-1-amine which is a new D-π-D Type Schiff base ligand (L) were determined by inverse gas chromatography (IGC) at infinite dilution. The retentions of several organic solvents on L were measured in the temperature range from 40 to 100 °C by IGC. The dispersive component of the surface energy, \( \gamma_{S}^{D} \) of studied adsorbent surface was estimated using retention times of different nonpolar organics in the infinite dilution region. Thermodynamic parameters of adsorption (free energy, \( \Updelta G_{A}^{S} , \) enthalpy, \( \Updelta H_{A}^{S} \) and entrophy, \( \Updelta S_{A}^{S} \)), dispersive components of the surface energies, \( \gamma_{S}^{D} \) and the acid, K A and base, K D constants for the L were calculated. The obtained results proved that IGC is an efficient and successful technique for the characterization of adsorption properties and acid–base quantity of these kinds of materials.

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Acknowledgments

This research has been supported by Yildiz Technical University Scientific Research Projects Coordination Department.

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Authors and Affiliations

  1. Department of Chemistry, Yildiz Technical University, Davutpasa Campus, 34220, Istanbul, Turkey

    Gulnur Keser Karaoglan & Dolunay Sakar

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  1. Gulnur Keser Karaoglan
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  2. Dolunay Sakar
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Correspondence to Dolunay Sakar.

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Karaoglan, G.K., Sakar, D. Surface Characterization of a Novel D-π-D Type Ligand by IGC at Infinite Dilution. Chromatographia 73, 93–98 (2011). https://doi.org/10.1007/s10337-010-1819-z

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  • DOI: https://doi.org/10.1007/s10337-010-1819-z

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