Abstract
We studied the removal of copper and zinc ions from aqueous solutions using a lignocellulosic substrate obtained by an acido-basic treatment of wheat bran. The sorption capacity of this material was investigated through batch and column experiments. Batch experimental results showed that the retention capacity of the lignocellulosic substrate was 0.20×10−3 mol g−1 at pH 4.5 for copper(II) and 0.24×10−3 mol g−1 at pH 6.5 for zinc(II). Column experiments showed a reduced sorption capacity for both ions compared to batch experiments. Batch and column data were analysed using the Langmuir equation in order to determine the affinity constant and the binding capacity of the sorbent and to compare both retention processes.
Similar content being viewed by others
References
Aksu Z, Kutsal T (1998) Determination of kinetic parameters in the biosorption of copper(II) on Cladophora sp. in a packed bed column reactor. Proc Biochem 33:7–13
Bouanda J, Dupont L, Dumonceau J, Aplincourt M (2003) Use of a NICA-Donnan approach for analysis of proton binding to a lignocellulosic substrate extracted from wheat bran. Anal Bioanal Chem 373:174–182
Cay S, Uyanik A, Ozasik A (2004) Single and binary component adsorption of copper(II) and cadmium(II) from aqueous solutions using tea-industry waste. Separ Purific Technol 38:273–280
Chu KH (2004) Improved fixef bed models for metal biosorption. Chemical Eng J 97:233–239
Gauthier A, Derenne S, Dupont L, Guillon E, Largeau C, Dumonceau J, Aplincourt M, (2002) Characterisation and comparison of two lignocellulosic substrates by 13C CP/MAS NMR, XPS, conventional pyrolysis and thermochemolysis. Anal Bioanal Chem 373:830–838
Kratochvil D, Volesky B (1998) Advances in the biosorption of heavy metals. Trends Biotechnol 16:291–300
Taty-Costodes VC, Fauduet H, Porte C, Delacroix A (2003) Removal of Cd(II) and Pb(II) ions from aqueous solutions by adsorption onto sawdust of Pinus sylvestris. J Hazard Mater 105:121–142
Valdman E, Erijman L, Pessoa FLP, Leite SGF (2001) Continuous biosorption of Cu and Zn by immobilized waste biomass Sargassum sp. Proc Biochem 36:869–873
Villaescusa I, Fiol N, Martinez M, Miralles N, Poch J, Serarols J (2004) Removal of copper and nickel ions from aqueous solutions by grape stalks wastes. Water Res 38:992–1002
Yan G, Viraraghavan T (2001) Heavy metal removal in a biosorption column by immobilized M. rouxii biomass. Biorese Technol 78:243–249
Acknowledgements
We are grateful to the Région Champagne-Ardenne and the Département de la Marne for their financial support and for a grant to Jamila Bouanda and to the society ARD for giving the materials for column experiments.
Author information
Authors and Affiliations
Rights and permissions
About this article
Cite this article
Dupont, L., Bouanda, J., Dumonceau, J. et al. Biosorption of Cu(II) and Zn(II) onto a lignocellulosic substrate extracted from wheat bran. Environ Chem Lett 2, 165–168 (2005). https://doi.org/10.1007/s10311-004-0095-2
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10311-004-0095-2