Abstract
The possibility of using limestone dust waste (LDW) as a filler in natural rubber (NR) was investigated. First, the basic properties of LDW were characterized; LDW was then incorporated into NR and the compound properties were determined. Comparison of the reinforcing effect of LDW and other commercial fillers such as light-precipitated calcium carbonate (PCC) and nanoprecipitated calcium carbonate (NPCC) was made. The results revealed that even though the addition of LDW has little effect on compound processability, it has a negative effect on most mechanical properties, e.g., tensile strength, tear strength, and abrasion resistance, of the vulcanizate. Among the three fillers, the degree of reinforcement could be placed in the following order: NPCC > PCC > LDW. Due to their relatively low specific surface area and thus low reinforcement ability, both LDW and PCC can be grouped as nonreinforcing fillers, whereas NPCC, the specific surface area of which is relatively high, could be grouped as a semi-reinforcing filler for rubber.
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Turgut P, Murat Algin H (2007) Limestone dust and wood sawdust as brick material. Build Environ 42:3399–3403
Kim JA, Kim JH, Han C, Kim H, Ahn JW (2005) A study on the calcination characteristics of the PCC synthesis from waste limestone. Resour Recyc Technol 2005:225–227
Galetakis M, Raka S (2004) Utilization of limestone dust for artificial stone production: an experimental approach. Miner Eng 17(2):355–357
Flory PJ, Rhener J (1943) Statistical mechanics of cross-linked polymer networks II. Swelling. J Chem Phys 11:521–526
Lamminmäki J, Li SY, Hanhi K (2006) Feasible incorporation of devulcanized rubber waste in virgin natural rubber. J Mater Sci 41:8301–8307
Sae-oui P, Sirisinha C, Thepsuwan U, Hatthapanit K (2007) Dependence of mechanical and aging properties of chloroprene rubber on silica and ethylene thiourea loadings. Eur Polym J 43: 185–193
Poh BT, Ismail H, Tan KS (2002) Effect of filler loading on tensile and tear properties of SMR L/ENR 25 and SMR L/SBR blends cured via a semi-efficient vulcanization system. Polym Test 21(7):801–806
Sajjayanukul T, Sae-Oui P, Sirisinha C (2005) Experiment analysis of viscoelastic properties in carbon black-filled natural rubber compounds. J Appl Polym Sci 97:2197–2203
Phewthongin N, Sae-Oui P, Sirisinha C (2006) Rheological behavior of CPE/NR blends filled with precipitated silica. J Appl Polym Sci 100:2565–2571
Sae-oui P, Rakdee C, Thanmathorn P (2002) Use of rice husk ash as filler in natural rubber vulcanizated in comparison with other commercial fillers. J Polym Sci 83:2485–2493
Morton M (1987) Rubber technology, 3rd edn. Van Nostrand Reinhold, New York, p 90
Dannenberg EM (1975) Rubber effects of surface chemical interactions on the properties of filler-reinforced rubbers. Rubber Chem Technol 48(3):410–444
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Sae-oui, P., Sirisinha, C. & Thaptong, P. Utilization of limestone dust waste as filler in natural rubber. J Mater Cycles Waste Manag 11, 166–171 (2009). https://doi.org/10.1007/s10163-008-0230-4
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DOI: https://doi.org/10.1007/s10163-008-0230-4