Abstract
In the field of polymer/graphene nanocomposites, massive production and commercial availability of graphene are essential. Exfoliation of graphite to obtain graphene is one of the most promising ways to large-scale production at extremely low cost. In this work we illustrate a facile strategy for mass production of few-layered (≤ 10) graphene (FLG) via the newly explored ball milling. The achieved FLG concentration was determined by UV/Vis spectroscopy. The formation of FLG was proved by measuring the flake thickness by atomic force microscopy (AFM). Further Raman spectral studies indicated that the crystal structure of exfoliated flakes was preserved satisfactorily during this shear-force dominating process. To increase the maximum concentration obtainable, it’s critical to make a good parameter assessment. N-methylpyrrolidone (NMP) was used as a dispersing medium and the effect of milling parameters was systematically and quantitatively investigated, thus providing a criterion to optimize the milling process. We established the optimal values for solvent volume and initial weight of graphite. As for milling time, the production of FLG was enhanced with continuous milling according to the power law, but not linearly with increasing milling time. Moreover, the possible mechanism involved in milling process was also explored. Our work provides a simple method for graphite exfoliation and has great potential for improving thermal and electrical conductivity of polymer composites in the fields of engineering.
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Kim, K.S., Zhao, Y., Jang, H., Lee, S.Y., Kim, J.M., Kim, K.S., Ahn, J.H., Kim, P., Choi, J.Y. and Hong, B.H., Nature, 2009, 457(7230): 706
Li, W., Geng, X., Guo, Y., Rong, J., Gong, Y., Wu, L., Zhang, X., Li, P., Xu, J. and Cheng, G., ACS nano, 2011, 5(9): 6955
Dai, L., Acc. Che. Res., 2012, 46(1): 31
Wang, H., Liang, Y., Mirfakhrai, T., Chen, Z., Casalongue, H.S. and Dai, H., Nano Res., 2011, 4(8): 729
Wu, L.M., Liao, S.Q., Zhang, S.J., Bai, X.Y. and Hou, X., Chinese J. Polym. Sci., 2015, 33(7): 1058
Lee, C., Wei, X., Li, Q., Carpick, R., Kysar, J.W. and Hone, J., Phys. Status Solidi (b), 2009, 246(11-12): 2562
Neto, A.C., Guinea, F., Peres, N., Novoselov, K.S. and Geim, A.K., Rev. Mod. Phys., 2009, 81(1): 109
Geim, A.K. and Novoselov, K.S., Nat. Mater., 2007, 6(3): 183
Obraztsov, A.N., Nat. Nanotechnol., 2009, 4(4): 212
Sutter, P.W., Flege, J.I. and Sutter, E.A., Nat. Mater., 2008, 7(5): 406
Dreyer, D.R., Park, S., Bielawski, C.W. and Ruoff, R.S., Chem. Soc. Rev., 2010, 39(1): 228
Ma, W.S., Wu, L., Yang, F. and Wang, S.F., J. Mater. Sci., 2014, 49(2): 562
Cui, X., Zhang, C., Hao, R. and Hou, Y., Nanoscale, 2011, 3(5): 2118
Zhou, X., Wu, T., Ding, K., Hu, B., Hou, M. and Han, B., Chem. Commun., 2010, 46(3): 386
Wang, H., Xia, B., Yan, Y., Li, N., Wang, J.Y. and Wang, X., J. Phys. Chem. B, 2013, 117(18): 5606
Gudarzi, M.M., Moghadam, M.H.M. and Sharif, F., Carbon, 2013, 64: 403
Khan, U., O’ Neill, A., Lotya, M., De, S. and Coleman, J.N., Small, 2010, 6(7): 864
Lotya, M., King, P.J., Khan, U., De, S. and Coleman, J.N., ACS Nano, 2010, 4(6): 3155
Vadukumpully, S., Paul, J. and Valiyaveettil, S., Carbon, 2009, 47(14): 3288
Lin, T., Tang, Y., Wang, Y., Bi, H., Liu, Z., Huang, F., Xie, X. and Jiang, M., Energ. Environ. Sci., 2013, 6(4): 1283
Knieke, C., Berger, A., Voigt, M., Taylor, R.N.K., Röhrl, J. and Peukert, W., Carbon, 2010, 48(11): 3196
Zhao, W., Fang, M., Wu, F., Wu, H., Wang, L. and Chen, G., J. Mater. Chem., 2010, 20(28): 5817
Zhao, W., Wu, F., Wu, H. and Chen, G., J. Nanomater., 2010, 2010: 1
Liu, L., Xiong, Z., Hu, D., Wu, G. and Chen, P., Chem. Commun., 2013, 49(72): 7890
Lv, Y., Yu, L., Jiang, C., Chen, S. and Nie, Z., RSC Adv., 2014, 4(26): 13350
Leon, V., Quintana, M., Herrero, M.A., Fierro, J.L., de la Hoz, A., Prato, M. and Vazquez, E., Chem. Commun., 2011, 47(39): 10936
Jeon, I.Y., Choi, H.J., Jung, S.M., Seo, J.M., Kim, M.J., Dai, L. and Baek, J.B., J. Am. Chem. Soc., 2013, 135(4): 1386
Nandhini, R., Mini, P.A., Avinash, B., Nair, S.V. and Subramanian, K.R.V., Mater. Lett., 2012, 87: 165
Aparna, R., Sivakumar, N., Balakrishnan, A., Sreekumar Nair, A., Nair, S.V. and Subramanian, K.R.V., J. Renew. Sustain. Ener., 2013, 5(3): 033123
Yao, Y., Lin, Z., Li, Z., Song, X., Moon, K.S. and Wong, C.P., J. Mater. Chem., 2012, 22(27): 13494
Mao, M., Chen, S., He, P., Zhang, H. and Liu, H., J. Mater. Chem. A, 2014, 2(12): 4132
Lin, T., Chen, J., Bi, H., Wan, D., Huang, F., Xie, X. and Jiang, M., J. Mater. Chem. A, 2013, 1(3): 500
Hernandez, Y., Nicolosi, V., Lotya, M., Blighe, F.M., Sun, Z., De, S., McGovern, I., Holland, B., Byrne, M. and Gun’ Ko, Y.K., Nat. Nanotechnol., 2008, 3(9): 563
Ferralis, N., J. Mater. Sci., 2010, 45(19): 5135
Stankovich, S., Dikin, D.A., Piner, R.D., Kohlhaas, K.A., Kleinhammes, A., Jia, Y., Wu, Y., Nguyen, S.T. and Ruoff, R.S., Carbon, 2007, 45(7): 1558
Khan, U., O’Neill, A., Porwal, H., May, P., Nawaz, K. and Coleman, J.N., Carbon, 2012, 50(2): 470
O’Neill, A., Khan, U., Nirmalraj, P.N., Boland, J. and Coleman, J.N., J. Phys. Chem. C, 2011, 115(13): 5422
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This work was financially supported by the National Natural Science Foundation of China (Nos. 51421061 and 51210005). We would like to express our sincere thanks to Guangdong Shengyi Technology Limited Corporation.
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Deng, S., Qi, Xd., Zhu, Yl. et al. A facile way to large-scale production of few-layered graphene via planetary ball mill. Chin J Polym Sci 34, 1270–1280 (2016). https://doi.org/10.1007/s10118-016-1836-y
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DOI: https://doi.org/10.1007/s10118-016-1836-y