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High trans-1,4 (co)polymerization of β-myrcene and isoprene with an iminophosphonamide lanthanum catalyst

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Abstract

β-Iminophosphonamide ligated lanthanum bis(benzyl) complex (NPNDipp)La(CH2Ph-4-Me)2(THF) (NPNDipp = Ph2P(NC6H3 iPr2-2,6)2), upon activation of AlEt3 and [Ph3C][B(C6F5)4], exhibited high catalytic activity and high trans-1,4 stereoselectivity for the polymerization of bio-sourced β-myrcene (MY). Based on which, a series of novel trans-1,4 regulated elastomers could be generated by random/block copolymerization of MY and isoprene (IP).

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References

  1. Mecking, S., Angew. Chem., Int. Ed., 2004, 43: 1078

    Article  CAS  Google Scholar 

  2. Williams, C.K. and Hillmyer, M.A., Polym. Rev., 2008, 48: 1

    Article  CAS  Google Scholar 

  3. Gandini, A., Macromolecules, 2009, 41: 9491

    Article  Google Scholar 

  4. Yao, K. and Tang, C., Macromolecules, 2013, 46: 1689

    Article  CAS  Google Scholar 

  5. Zhang, Y. and Chen, E.Y.X., Angew. Chem., Int. Ed., 2012, 51: 2465

    Article  CAS  Google Scholar 

  6. Zhang, Y., Gustafson, L.O. and Chen, E.Y.X., J. Am. Chem. Soc., 2011, 133: 13674

    Article  CAS  Google Scholar 

  7. Chen, X., Caporaso, L., Cavallo, L. and Chen, E.Y.X., J. Am. Chem. Soc., 2012, 134: 7278

    Article  CAS  Google Scholar 

  8. Zhang, Y., Miyake, G.M. and Chen, E.Y.X., Angew. Chem., Int. Ed., 2010, 49: 10158

    Article  CAS  Google Scholar 

  9. Mou, Z., Liu, B., Liu, X., Xie, H., Rong, W., Li, L., Li, S. and Cui, D., Macromolecules, 2014, 47: 2233

    Article  CAS  Google Scholar 

  10. Wang, Y., Zhao, W., Liu, X., Cui, D. and Chen, E.Y.X., Macromolecules, 2012, 45: 6957

    Article  CAS  Google Scholar 

  11. Zhao, W., Cui, D., Liu, X. and Chen, X., Macromolecules, 2010, 43: 6678

    Article  CAS  Google Scholar 

  12. Zhao, W., Wang, Y., Liu, X., Chen, X., Cui, D. and Chen, E.Y.X., Chem. Commun., 2012, 48: 6375

    Article  CAS  Google Scholar 

  13. Witt, T. and Mecking, S., Green Chem., 2013, 15: 23615

    Article  Google Scholar 

  14. Stempfle, F., Ortmann, P. and Mecking, S., Macromol. Rapid Commun., 2013, 34: 47

    Article  CAS  Google Scholar 

  15. Chikkali, S., Stempfle, F. and Mecking, S., Macromol. Rapid Commun., 2012, 33: 1126

    Article  CAS  Google Scholar 

  16. Stempfle, F., Ritter, B.S., Mülhaupt, R. and Mecking, S., Green Chem., 2014, 16: 2008

    Article  CAS  Google Scholar 

  17. Marvel, C.S. and Hwa, C.C.L., J. Polym. Sci., 1960, 45: 25

    Article  CAS  Google Scholar 

  18. Newmark R.A. and Majumdar, R.N., J. Polym. Sci., Part A: Polym. Chem., 1988, 26: 71

    Article  CAS  Google Scholar 

  19. Trumbo, D.L., Polym. Bull., 1993, 31: 629

    Article  CAS  Google Scholar 

  20. Loughmari, S., Hafid, A., Bouazza, A., Bouadili, A.E., Zinck, P. and Visseaux, M., J. Polym. Sci., Part A: Polym. Chem., 2012, 50: 2898

    Article  CAS  Google Scholar 

  21. Georges, S., Toure, A.O., Zinck, P. and Visseaux, M., Macromolecules, 2014, 48: 4538

    Article  Google Scholar 

  22. Georges, S., Bria, M., Zinck, P. and Visseaux, M., Polymer, 2014, 55: 3869

    Article  CAS  Google Scholar 

  23. Raynaud, J., Wu, J.Y. and Ritter, T., Angew. Chem., Int. Ed., 2012, 51: 11805

    Article  CAS  Google Scholar 

  24. Liu, B., Li, L., Sun, G., Liu, D., Li, S. and Cui, D., Chem. Comm., 2015, 51: 1039

    Article  CAS  Google Scholar 

  25. Liu, B., Han, B., Zhang, C., Li, S., Sun, G. and Cui, D., Chinese J. Polym. Sci., 2015, 33(5): 792

    Article  CAS  Google Scholar 

  26. Meermann, C., Tornroos, K., Nerdal, W. and Anwander, R., Angew. Chem., Int. Ed., 2007, 46: 6508

    Article  CAS  Google Scholar 

  27. Zhang, L., Suzuki, T., Luo, Y., Nishiura, M. and Hou, Z., Angew. Chem., Int. Ed., 2007, 46: 1909

    Article  CAS  Google Scholar 

  28. Gao, W. and Cui, D., J. Am. Chem. Soc., 2008, 130: 4984

    Article  CAS  Google Scholar 

  29. Zimmermann, M., Tornroos, K., Nerdal, W. and Anwander, R., Angew. Chem., Int. Ed., 2008, 47: 775

    Article  CAS  Google Scholar 

  30. Rong, W., Liu, D., Zuo, H., Pan, Y., Jian, Z., Li, S. and Cui, D., Organometallics, 2013, 32: 1166

    Article  CAS  Google Scholar 

  31. Liu, H., He, J., Liu, Z., Du, G., Zhang, S. and Li, X., Macromolecules, 2013, 46: 3257

    Article  CAS  Google Scholar 

  32. Zhang, L., Luo, Y. and Hou, Z., J. Am. Chem. Soc., 2005, 127: 14562

    Article  CAS  Google Scholar 

  33. Zhang, L., Nishiura, M., Yuki, M., Luo, Y. and Hou, Z., Angew. Chem., Int. Ed., 2008, 47: 2642

    Article  CAS  Google Scholar 

  34. Liu, B., Li, L., Sun, G., Liu, J., Wang, M., Li, S. and Cui, D., Macromolecules, 2014, 47: 4971

    Article  CAS  Google Scholar 

  35. Ashitaka, H., Jinda, K. and Ueno, H., J. Polym. Sci., Polym. Chem. Ed., 1983, 21: 1989

    Article  CAS  Google Scholar 

  36. Ricci, G., Forni, A., Boglia, A., Motta, T., Zannoni, G., Canetti, M. and Bertini, F., Macromolecules, 2005, 38: 1064

    Article  CAS  Google Scholar 

  37. Zhang, Z., Cui, D., Wang, B., Liu, B. and Yang, Y., Struct. Bond, 2010, 137: 49

    Article  CAS  Google Scholar 

  38. Liu, B., Sun, G., Li, S., Liu, D. and Cui, D., Organometallics, 2015, 34: 4063

    Article  CAS  Google Scholar 

  39. Magnus, P., Lacour, J. and Weber, W., J. Am. Chem. Soc., 1993, 115: 9347

    Article  CAS  Google Scholar 

  40. Piers, W.E. and Chivers, T., Chem. Soc. Rev., 1997, 26: 345

    Article  CAS  Google Scholar 

  41. Stasch, A., Chem. Eur. J., 2012, 18: 15105

    Article  CAS  Google Scholar 

  42. Valente, A., Mortreux, A., Visseaux, M. and Zinck, P., Chem. Rev., 2013, 113: 3836

    Article  CAS  Google Scholar 

  43. Jian, Z., Cui, D., Hou, Z. and Li, X., Chem. Commun., 2010, 46: 3022

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. Key Laboratory of Automobile Materials of Ministry of Education, Department of Materials Science and Engineering, Jilin University, Changchun, 130022, China

    Bo Liu & Guang-ping Sun  (孙广平)

  2. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China

    Dong-tao Liu, Shi-hui Li  (李世辉) & Dong-mei Cui

Authors
  1. Bo Liu
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  2. Dong-tao Liu
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  3. Shi-hui Li  (李世辉)
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  4. Guang-ping Sun  (孙广平)
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  5. Dong-mei Cui
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Corresponding authors

Correspondence to Shi-hui Li  (李世辉) or Guang-ping Sun  (孙广平).

Additional information

This work was financially supported by the National Natural Science Foundation of China (Nos. 51321062 and 21304088) and the Department of Science and Technology of Jilin Province for Project No. 20150204079GX.

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Liu, B., Liu, Dt., Li, Sh. et al. High trans-1,4 (co)polymerization of β-myrcene and isoprene with an iminophosphonamide lanthanum catalyst. Chin J Polym Sci 34, 104–110 (2016). https://doi.org/10.1007/s10118-016-1729-0

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  • DOI: https://doi.org/10.1007/s10118-016-1729-0

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