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Deformation temperature and lamellar thickness dependency of Form I to Form III phase transition in syndiotactic polypropylene during tensile stretching

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Abstract

Phase transition from form I to form III in syndiotactic polypropylene crystallized at different conditions during tensile deformation at different temperatures was investigated by using in situ synchrotron wide angle X-ray diffraction technique. In all cases, the occurrence of this phase transition was observed. The onset strain of this transition was found to be crystalline thickness decided by crystallization temperature and drawing temperature dependent. The effect of drawing temperature on this phase transition is understood by the changes in mechanical properties with temperature. Moreover, crystalline thickness dependency of the phase transition reveals that this form I to from III phase transition occurs first in those lamellae with their normal along the stretching direction which have not experienced stress induced melting and recrystallization.

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Authors and Affiliations

  1. State Key Laboratory of Polymer Physics and Chemistry, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, University of Chinese Academy of Sciences, Changchun, 130022, China

    Ying Lu, Ying-ying Sun, Ran Chen & Yong-feng Men  (门永锋)

  2. SSRF, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201800, China

    Xiu-hong Li

Authors
  1. Ying Lu
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  2. Ying-ying Sun
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  3. Ran Chen
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  4. Xiu-hong Li
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  5. Yong-feng Men  (门永锋)
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Corresponding author

Correspondence to Yong-feng Men  (门永锋).

Additional information

This work was financially supported by the National Natural Science Foundation of China (No. 21134006).

Invited paper for the special issue of “Polymer Crystallization”

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Lu, Y., Sun, Yy., Chen, R. et al. Deformation temperature and lamellar thickness dependency of Form I to Form III phase transition in syndiotactic polypropylene during tensile stretching. Chin J Polym Sci 32, 1210–1217 (2014). https://doi.org/10.1007/s10118-014-1494-x

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  • DOI: https://doi.org/10.1007/s10118-014-1494-x

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