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Application of successive self-nucleation and annealing to study the stereo-defects distribution of biaxially oriented polypropylene

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Abstract

The stereo-defects distribution of polypropylene of the two industry biaxially oriented polypropylene (BOPP) samples T28FE and F28SO with different processing properties was studied through successive self-nucleation and annealing (SSA) technique. It was found that there were more medium isotactic components in sample F28SO, and the isotactic sequence length of polypropylene of sample F28SO was shorter and the isotactic sequence length distribution of polypropylene of sample F28SO was broader, which could be processed well at high-speed orientation during the processing of BOPP films. This result indicates that the isotactic sequence length distribution of polypropylene is related to the processing speed during preparing BOPP films, and the stereo-defects distribution of polypropylene has an important influence on its processing ability.

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References

  1. Qiao, J., Guo, M., Wang, L., Liu, D., Zhang, X., Yu, L., Song, W. and Liu, Y., Polym. Chem., 2011, 2(8): 1611

    Article  CAS  Google Scholar 

  2. Masuda, J. and Ohkura, M., J. Appl. Polym. Sci., 2007, 106(6): 4031

    Article  CAS  Google Scholar 

  3. Hu, J., Han, B., Shen, X.R., Fu, Z.S. and Fan, Z.Q., Chinese J. Polym. Sci., 2013, 31(4): 583

    Article  CAS  Google Scholar 

  4. Liu, Y.G. and Bo, S.Q., Int. J. Polym. Anal. Ch., 2003, 8(4): 225

    Article  CAS  Google Scholar 

  5. Yao, W.G., Jia, Y.X., An, L.J. and Li, B.Y., Polym-Plast. Technol., 2005, 44(3): 447

    Article  CAS  Google Scholar 

  6. Xu, J.T., Feng, L.X., Yang, S.L., Yang, Y.Q. and Kong, X.M., Macromolecules, 1997, 30(25): 7655

    Article  CAS  Google Scholar 

  7. Kioka, M., Makio, H., Mizuno, A. and Kashiwa, N., Polymer, 1994, 35(3): 580

    Article  CAS  Google Scholar 

  8. Xu, J.T., Feng, J.X., Yang, S.L., Yang, Y.Q. and Kong, X.M., Eur. Polym. J., 1998, 34(3–4): 431

    CAS  Google Scholar 

  9. Kang, J., Yang, F., Wu, T., Li, H.L., Liu, D.M., Cao, Y. and Xiang, M., J. Appl. Polym. Sci., 2012, 125(4): 3076

    Article  CAS  Google Scholar 

  10. Kang, J., Yang, F., Wu, T., Li, H.L., Cao, Y. and Xiang, M., Eur. Polym. J., 2012, 48(2): 425

    Article  CAS  Google Scholar 

  11. Lou, J.Q., Tu, S.T. and Fan, Z.Q., Iran. Polym. J., 2010, 19(12): 927

    CAS  Google Scholar 

  12. Boger, A., Imhof, C., Heise, B., Marti, O., Troll, C., Rieger, B. and Hild, S., J. Appl. Polym. Sci., 2008, 112(1): 188

    Article  Google Scholar 

  13. Phillips, R.A. and Nguyen, T., J. Appl. Polym. Sci., 2001, 80(13): 2400

    Article  CAS  Google Scholar 

  14. Muller, A.J., Hernandez, Z.H., Arnal, M.L. and Sanchez, J.J., Polym. Bull., 1997, 39(4): 465

    Article  CAS  Google Scholar 

  15. Fillon, B., Wittmann, J.C., Lotz, B. and Thierry, A., J. Polym. Sci. Part B: Polym. Phys., 1993, 31(10): 1383

    Article  CAS  Google Scholar 

  16. Fan, Y.D., Zhang, C.Y., Xue, Y.H., Zhang, X.Q., Ji, X.L. and Bo, S.Q., Polymer, 2011, 52(2): 557

    Article  CAS  Google Scholar 

  17. Song, S.J., Wu, P.Y., Feng, J.C., Ye, M.X. and Yang, Y.L., Polymer, 2009, 50(1): 286

    Article  CAS  Google Scholar 

  18. Pérez, C.J. and Carella, J.M., Polym. Degrad. Stab., 2007, 92(7): 1213

    Article  Google Scholar 

  19. Müller, A.J. and Arnal, M.L., Prog. Polym. Sci., 2005, 30(5): 559

    Article  Google Scholar 

  20. Virkkunen, V., Laari, P., Pitkänen, P. and Sundholm, F., Polymer, 2004, 45(14): 4623

    Article  CAS  Google Scholar 

  21. Chang, H.F., Ren, S.T., Zheng, T., Dang, X.F., Yang, Y., Zhang, L.Y. and Li, H.Y., Acta Polymerica Sinica (in Chinese), 2013, (2): 199

  22. Arnal, M.L., Balsamo, V., Ronca, G., Sanchez, A., Muller, A.J., Canizales, E. and de Navarro, C.U., J. Therm. Anal. Calorim., 2000, 59(1–2): 451

    Article  CAS  Google Scholar 

  23. Marquez, L., Rivero, I. and Muller, A.J., Macromol. Chem. Phys., 1999, 200(2): 330

    Article  CAS  Google Scholar 

  24. Michell, R.M., Muller, A.J., Deshayes, G. and Dubois, P., Eur. Polym. J., 2010, 46(6): 1334

    Article  CAS  Google Scholar 

  25. Alamo, R.G., Blanco, J.A., Agarwal, P.K. and Randall, J.C., Macromolecules, 2003, 36(5): 1559

    Article  CAS  Google Scholar 

  26. Lorenzo, A.T., Arnal, M.L., Müller, A.J., Boschetti de Fierro, A. and Abetz, V., Macromol. Chem. Phys., 2006, 207(1): 39

    Article  CAS  Google Scholar 

  27. Chang, H.F., Zhang, Y., Ren, S.T., Dang, X.F., Zhang, L.Y., Li, H.Y. and Hu, Y.L., Polym. Chem., 2012, 3(10): 2909

    Article  CAS  Google Scholar 

  28. Tu, S.T., Lou, J.Q., Fu, Z.S. and Fan, Z.Q., E-Polymers, 2011, (50): 1

  29. Muller, A.J., Arnal, M.L., Spinelli, A.L., Canizales, E., Puig, C.C. and Wang, H., Macromol. Chem. Phys., 2003, 204(12): 1497

    Article  Google Scholar 

  30. Chang, H.F., Ren, S.T., Dang, X.F., Zhang, L.Y., Li, H.Y. and Hu, Y.L., J. Appl. Polym. Sci., 2013, 129(3): 1026

    Article  CAS  Google Scholar 

  31. Xue, Y.H., Fan, Y.D., Bo, S.Q. and Ji, X.L., Eur. Polym. J., 2011, 47(8): 1646

    Article  CAS  Google Scholar 

  32. Suarez, I., Caballero, M.J. and Coto, B., Eur. Polym. J., 2011, 47(2): 171

    Article  CAS  Google Scholar 

  33. Lu, X.Y., Yi, J.J., Chen, S.T., Zu, F.H. and Li, R.B., Chinese J. Polym. Sci., 2012, 30(1): 122

    Article  CAS  Google Scholar 

  34. Kakugo, M., Miyatake, T., Naito, Y. and Mizunuma, K., Macromolecules, 1988, 21(2): 314

    Article  CAS  Google Scholar 

  35. Xu, J.T. and Feng, L.X., Eur. Polym. J., 2000, 36(5): 867

    Article  CAS  Google Scholar 

  36. Chang, H.F., Li, H.Y., Zheng, T., Zhang, L.Y., Yuan, W., Li, L., Huang, H. and Hu, Y.L., J. Polym. Res., 2013, DOI 10.1007/s10965-013-0207-4

    Google Scholar 

  37. Moore, E.P., “Polypropylene Handbook: Polymerization, Characterization, Properties, Processing, Applications”, Hanser Publishers, 1996

    Google Scholar 

  38. Brandrup, J. and Immergut, E.H., “Polymer Handbook, 3rd ed.”, Wiley, New York, 1989, p. 27

    Google Scholar 

  39. Lorenzo, A.T., Arnal, M.L., Muller, A.J., Lin, M.C. and Chen, H.L., Macromol. Chem. Phys., 2011, 212(18): 2009

    Article  CAS  Google Scholar 

  40. Müller, A.J., Lorenzo, A.T. and Arnal, M.L. Recent Advances and Applications of “Successive Self-Nucleation and Annealing” (SSA) High Speed Thermal Fractionation. Wiley Online Library, 2009. p. 207

    Google Scholar 

  41. Muller, A.J., Balsamo, V., Arnal, M.L., Jakob, T., Schmalz, H. and Abetz, V., Macromolecules, 2002, 35(8): 3048

    Article  Google Scholar 

  42. Pijpers, T.F.J., Mathot, V.B.F., Goderis, B., Scherrenberg, R.L. and van der Vegte, E.W., Macromolecules, 2002, 35(9): 3601

    Article  CAS  Google Scholar 

  43. Gedde, U.W., “Polymer physics”, Chapman & Hall, London, 1995

    Google Scholar 

  44. Iijima, M. and Strobl, G., Macromolecules, 2000, 33(14): 5204

    Article  CAS  Google Scholar 

  45. Bond, E.B., Spruiell, J.E. and Lin, J.S., J. Polym. Sci. Part B: Polym. Phys., 1999, 37(21): 3050

    Article  CAS  Google Scholar 

  46. Wlochowicz, A. and Eder, M., Polymer, 1984, 25(9): 1268

    Article  CAS  Google Scholar 

  47. Keating, M., Lee, I.H. and Wong, C.S., Thermochim. Acta., 1996, 284(1): 47

    Article  CAS  Google Scholar 

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Authors and Affiliations

  1. College of Chemistry and Chemical Engineering, University of Chinese Academy of Sciences, Beijing, 100049, China

    He-fei Chang, Tao Zheng, Qian Zhou & Liao-yun Zhang  (张辽云)

  2. Beijing National Laboratory for Molecular Sciences, CAS Key Laboratory of Engineering Plastics, Institute of Chemistry, Chinese Academy of Sciences, Beijing, 100190, China

    Hua-yi Li  (李化毅) & You-liang Hu

  3. Performance Materials R&D Center, National Institute of Clean-and-Low-Carbon Energy, Beijing, 102211, China

    He-fei Chang

Authors
  1. He-fei Chang
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  2. Hua-yi Li  (李化毅)
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  3. Tao Zheng
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  4. Qian Zhou
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  5. Liao-yun Zhang  (张辽云)
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  6. You-liang Hu
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Corresponding authors

Correspondence to Hua-yi Li  (李化毅) or Liao-yun Zhang  (张辽云).

Additional information

This work was financially supported by the National Natural Science Foundation of China (No. 51073170).

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Chang, Hf., Li, Hy., Zheng, T. et al. Application of successive self-nucleation and annealing to study the stereo-defects distribution of biaxially oriented polypropylene. Chin J Polym Sci 32, 362–370 (2014). https://doi.org/10.1007/s10118-014-1412-2

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  • DOI: https://doi.org/10.1007/s10118-014-1412-2

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