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Synthesis and properties of sulfonated poly(ether ketone)s containing 3,5-dimethyl phthalazinone moieties as proton exchange membrane materials

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Abstract

Sulfonated poly(ether ketone)s containing 3,5-dimethyl phthalazinone moieties (SPPEK-DMs) with different degrees of sulfonation (DS) were synthesized via direct polycondensation from 4-(3,5-dimethyl-4-hydroxyphenyl)-2,3-phthalazinone, 4,4′-difluorobenzophenone and 3,3′-disulfonate-4,4′-difluorobenzophenone. The chemical structure of SPPEK-DMs was characterized by FTIR and 1H-NMR. Thermal stability of SPPEK-DMs was characterized by the thermogravimetric analysis. The membranes prepared from SPPEK-DMs exhibited ion exchange capacities (IEC) ranging from 0.93 mmol·g−1 to 1.86 mmol·g−1. Water uptake, swelling, oxidative stability and methanol permeability of SPPEKDMs membranes were investigated. SPPEK-DMs membranes exhibited high oxidative stability. The methanol permeability values of SPPEK-DMs membranes were in the range 5.15 × 10−8–6.61 × 10−7 cm2·s−1, which was much lower than those of Nafion117. The proton conductivity of SPPEK-DM40 membranes was 1.1 × 10−2 S·cm−1 at 70°C.

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Authors and Affiliations

  1. State Key Laboratory of Fine Chemicals, Liaoning High Performance Polymer Engineering Research Center, Liaoning Key Laboratory of Polymer Science and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian, 116024, China

    Shou-hai Zhang, Juan Zhou & Xi-gao Jian  (蹇锡高)

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  1. Shou-hai Zhang
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  2. Juan Zhou
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  3. Xi-gao Jian  (蹇锡高)
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Corresponding author

Correspondence to Xi-gao Jian  (蹇锡高).

Additional information

This work was financially supported by the Natural Science Foundation of Liaoning Province of China (No. 20041076).

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Zhang, Sh., Zhou, J. & Jian, Xg. Synthesis and properties of sulfonated poly(ether ketone)s containing 3,5-dimethyl phthalazinone moieties as proton exchange membrane materials. Chin J Polym Sci 30, 511–519 (2012). https://doi.org/10.1007/s10118-012-1129-z

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  • DOI: https://doi.org/10.1007/s10118-012-1129-z

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