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A facile synthesis of hyperbranched polyimides from 2,6,12-triaminotriptycene

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Abstract

Based on monomer 2,6,12-triaminotriptycene, hyperbranched polyimides with high molecular weight modified with different terminal functional groups were obtained by polymerization of A2 + B3 system. The prepared hyperbranched polyimides had good solubility in CHCl3, DMF and THF, and performed no detective T gs in the range of 50–330°C and high T ds (5%) above 455°C.

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Authors and Affiliations

  1. Department of Materials Science & Engineering, Huaqiao University, Xiamen, 361021, China

    Lin Cheng  (程琳), Zhen Xu, Xing-quan Xiong, Jia-xi Wang & Bin Jing

Authors
  1. Lin Cheng  (程琳)
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  2. Zhen Xu
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  3. Xing-quan Xiong
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  4. Jia-xi Wang
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  5. Bin Jing
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Corresponding author

Correspondence to Lin Cheng  (程琳).

Additional information

This work was financially supported by the National Natural Science Foundation of China (Nos. 50673031 and 50973036) and the Natural Science Foundation of Fujian Province (No. 2008F3067).

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Cheng, L., Xu, Z., Xiong, Xq. et al. A facile synthesis of hyperbranched polyimides from 2,6,12-triaminotriptycene. Chin J Polym Sci 28, 69–76 (2010). https://doi.org/10.1007/s10118-010-8192-0

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  • DOI: https://doi.org/10.1007/s10118-010-8192-0

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