Abstract
Granite is one of the most applied building materials globally. Salt weathering affects the aesthetic properties of granite and reduces its durability. Accelerated granite weathering tests were conducted to study the combined effects of salts and wetting–drying cycles. Granite samples were soaked in solutions of Na2SO4 and MgSO4 at different concentrations (0%, 5%, 10% and 20%) before drying. The mass loss, colour, roughness and surface hardness of the granite samples were measured after repeated cycling (0, 10, 20, 30, 40, 55, 65, 80, 90 and 100). The key research findings were as follows: (1) an increase in the number of wetting–drying cycles affected the properties of the granite samples significantly (i.e. mass loss, colour, surface roughness and hardness). (2) The effects of Na2SO4 on the accelerated weathering of granite were greater than those of MgSO4. (3) Higher salt concentrations (0%–20%) accelerated granite weathering.
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References
Akin M, Özsan A (2011) Evaluation of the long-term durability of yellow travertine using accelerated weathering tests. Bull Eng Geol Environ 70(1):101–114. https://doi.org/10.1007/s10064-010-0287-x
Alonso FJ, Vázquez P, Esbert RM, Ordaz J (2008) Ornamental granite durability: evaluation of damage caused by salt crystallization test. Mater Constr 58(289–290):191–201
Alves C, Figueiredo C, Maurício A (2017) A study of salt weathering cycles impact on limestones. Procedia Earth Planet Sci 17:316–319. https://doi.org/10.1016/j.proeps.2016.12.070
Angeli M, Bigas JP, Benavente D, Menéndez B, Hébert R, David C (2007) Salt crystallization in pores: quantification and estimation of damage. Environ Geol 52:205–213. https://doi.org/10.1007/s00254-006-0474-z
Angeli M, Benavente D, Bigas J-P, Menendez B, Hebert R, David C (2008) Modification of the pore network by salt crystallization in experimentally weathered sedimentary stones. Mater Struct 41:1091–1108. https://doi.org/10.1617/s11527-007-9308-z
Angeli M, Hébert R, Menéndez B et al (2010) Influence of temperature and salt concentration on the salt weathering of a sedimentary stone with sodium sulphate. Eng Geol 115(3–4):193–199. https://doi.org/10.1016/j.enggeo.2009.06.001
Balboni E, Espinosa-Marzal RM, Doehne E, Scherer GW (2011) Can drying and re-wetting of magnesium sulphate salts leads to damage of stone? Environ Earth Sci 63:1463–1473. https://doi.org/10.1007/s12665-010-0774-1
Benavente D, Lock P, Garcia-del-Cura MA, Ordonez S (2002) Predicting the capillary imbibition of porous rocks from the microstructure. Transp Porous Media 49:59–76. https://doi.org/10.1023/a:1016047122877
Benavente D, Garcia del Cura MA, Garcia-Guinea J, Sanchez-Moral S, Ordonez S (2004) Role of pore structure in salt crystallization in unsaturated porous stone. J Cryst Growth 260:532–544. https://doi.org/10.1016/j.jcrysgro.2003.09.004
Benavente D, Martínez-Martínez J, Cueto N, García-Del-Cura MA (2007) Salt weathering in dual-porosity building dolostones. Eng Geol 94(3–4):215–226. https://doi.org/10.1016/j.enggeo.2007.08.003
Blum AE (1994) Feldspars in weathering. Feldspars and their Reactions. Springer, Netherlands. https://doi.org/10.1007/978-94-011-1106-5_15
Bradley WC, Hutton JT, Twidale CR (1978) Role of salts in development of granitic Tafoni, South Australia. J Geol 86(5):647–654. https://doi.org/10.1086/649730
Cardell C, Benavente D, Rodríguez-Gordillo J (2008) Weathering of limestone building material by mixed sulphate solutions. Characterisation of stone micro-structure, reaction products and decay forms. Mater Charact 59:1371–1385. https://doi.org/10.1016/j.matchar.2007.12.003
Chatterji S, Jensen AD (1989) Efflorescence and breakdown of building materials. Nordic concrete research. Publication no 8. Publ Nordic Concr Fed 8:56–61
Derluyn H, Moonen P, Carmeliet J (2014) Deformation and damage due to drying-induced salt crystallization in porous limestone. J Mech Phys Solids 63:242–255. https://doi.org/10.1016/j.jmps.2013.09.005
Dragovich D, Egan M (2011) Salt weathering and experimental desalination treatment of building sandstone, Sydney (Australia). Environ Earth Sci 62(2):277–288. https://doi.org/10.1007/s12665-010-0521-7
Flatt RJ (2002) Salt damage in porous materials: how high supersaturations are generated. J Cryst Growth 242:435–454. https://doi.org/10.1016/S0022-0248(02)01429-X
Ghobadi MH, Babazadeh R (2015) An investigation on the effect of accelerated weathering on strength and durability of tertiary sandstones (Qazvin province, Iran). Environ Earth Sci 73(8):4237–4250. https://doi.org/10.1007/s12665-014-3708-5
Ghobadi MH, Mousavi S (2014) The effect of pH and salt solutions on the durability of sandstones of the Aghajari formation in Khuzestan province, southwest of Iran. Arab J Geosci 7(2):641–653. https://doi.org/10.1007/s12517-012-0741-0
Goudie AS (1993) Salt weathering simulation using a single-immersion technique. Earth Surf Process Landf 18:369–373. https://doi.org/10.1002/esp.3290180406
Goudie AS, Cooke R, Evans IS (1970) Experimental investigation of rock weathering by salts. Area 4:42–48. https://doi.org/10.2139/ssrn.2149615
Heidari M, Torabi-Kaveh M, Mohseni H (2017) Assessment of the effects of freeze-thaw and salt crystallization ageing tests on Anahita Temple Stone, Kangavar, West of Iran. Geotech Geol Eng 35(1):121–136. https://doi.org/10.1007/s10706-016-0090-y
Hime WG, Mather B (1999) “sulfate attack,” or is it? Cem Concr Res 29(5):789–791. https://doi.org/10.1016/S0008-8846(99)00068-X
Hua W, Dong S, Li Y, Wang Q (2016) Effect of cyclic wetting and drying on the pure mode II fracture toughness of sandstone. Eng Fract Mech 153:143–150. https://doi.org/10.1016/j.engfracmech.2015.11.020
Hua W, Dong S, Peng F, Li K, Wang Q (2017) Experimental investigation on the effect of wetting-drying cycles on mixed mode fracture toughness of sandstone. Int J Rock Mech Min Sci 93:242–249. https://doi.org/10.1016/j.ijrmms.2017.01.017
Kwaad FJPM (1970) Experiments on the granular disintegration of the granite by salt action. Fysisch Geogr Bodemkundig Lab 16:67–80
Lee MR, Hodson ME, Parsons I (1998) The role of intragranular microtextures and microstructures in chemical and mechanical weathering; direct comparisons of experimentally and naturally weathered alkali feldspars. Geochim Cosmochim Acta 62(16):2771–2788. https://doi.org/10.1016/S0016-7037(98)00200-2
Liang Y, Yuan Y (2007) Mechanism of concrete destruction under sodium sulfate and magnesium sulfate solution. Kuei Suan Jen Hsueh Pao/ J Chin Ceram Soc 35(4):504–508 (In Chinese). https://doi.org/10.1016/S1872-5791(07)60033-5
Lindström N, Talreja T, Linnow K, Stahlbuhk A, Steiger M (2016) Crystallization behaviour of NaNO3-MgSO4 salt mixtures in sandstone and comparison of single salt behaviour. Appl Geochem 69:50–70. https://doi.org/10.1016/j.apgeochem.2015.07.007
López-Acevedo V, Viedma C, Gonzalez V, La Iglesia A (1997) Salt crystallization in porous construction materials. II Mass transport and crystallization processes. J Cryst Growth 182(1–2):103–110. https://doi.org/10.1016/s0022-0248(97)00341-2
López-Arce P, Varas-Muriel MJ, Fernández-Revuelta B, Álvarez de Buergo M, Fort R, Pérez-Soba C (2010) Artificial weathering of Spanish granites subjected to salt crystallization tests: surface roughness quantification. CATENA 83(2–3):170–185. https://doi.org/10.1016/j.catena.2010.08.009n
Loubser MJ (2013) Weathering of basalt and sandstone by wetting and drying: a process isolation study. Geogr Ann Ser A Phys Geogr 95(4):295–304. https://doi.org/10.1111/geoa.12023
Ludovico-Marques M, Chastre C (2016) Effect of artificial accelerated salt weathering on physical and mechanical behaviour of sandstone samples from surface reservoirs. Handbook of materials failure analysis with case studies from the oil and gas industry, pp. 215-233. https://doi.org/10.1016/B978-0-08-100117-2.00013-3
Luís MOS, Gonçalves BMM (2012) Color assessment of granitic rocks and implications for their ornamental utilization. Color Res Appl, 37(5):0–0. https://doi.org/10.1002/col.20681
Martins L, Vasconcelos G, Lourenço PB and Palha CAOF (2016) Influence of the salt crystallization in the durability of granites used in vernacular masonry buildings. In 16th international brick and block masonry (pp. 517-524). Taylor and Francis
Menéndez B, Petráňová V (2016) Effect of mixed vs single brine composition on salt weathering in porous carbonate building stones for different environmental conditions. Eng Geol 210:124–139. https://doi.org/10.1016/j.enggeo.2016.06.011
Min K, Park J, Han D (2005) Durability of building stones against artificial salt crystallization. AGU Fall Meeting Abstracts
Noor-E-Khud S, Albermani F, Veidt M (2017) Flexural strength of weathered granites: influence of freeze and thaw cycles. Constr Build Mater 156:891–901. https://doi.org/10.1016/j.conbuildmat.2017.09.049
Noor-E-Khuda S, Albermani F (2019a) Mechanical properties of clay masonry units: destructive and ultrasonic testing. Constr Build Mater 219:111–120
Noor-E-Khuda S, Albermani F (2019b) Flexural strength of weathered granites under wetting-drying cycles: implications to steel structures. Adv Steel Constr 15(3):225–231
Özşen H, Bozdağ A, İnce İ (2017) Effect of salt crystallization on weathering of pyroclastic rocks from Cappadocia, Turkey. Arab J Geosci 10(12):258. https://doi.org/10.1007/s12517-017-3027-8
Robinson DA, Williams RBG (2000) Experimental weathering of sandstone by combinations of salts. Earth Surf Process Landf 25:1309–1315
Rodriguez-Navarro C, Doehne E (1999) Salt weathering: influence of evaporation rate, supersaturation and crystallization pattern. Earth Surf Process Landf 24(3):191–209. https://doi.org/10.1002/1096-9837(200011)25:12<1309::AID-ESP139>3.0.CO;2-5
Rodriguez-Navarro C, Doehne E, Sebastian E (2000) How does sodium sulphate crystallize? Implications for the decay and testing of building materials. Cem Concr Res 30(10):1527–1534. https://doi.org/10.1016/S0008-8846(00)00381-1
Ruiz-Agudo E, Mees F, Jacobs P, Rodriguez-Navarro C (2007) The role of saline solution properties on porous limestone salt weathering by magnesium and sodium sulfates. Environ Geol 52(2):269–281. https://doi.org/10.1007/s00254-006-0476-x
Sato M, Hattanji T (2018) A laboratory experiment on salt weathering by humidity change: salt damage induced by deliquescence and hydration. Progr Earth Planet Sci 5(1). https://doi.org/10.1186/s40645-018-0241-2
Scherer GW (2004) Stress from crystallization of salt. Cem Concr Res 34:1613–1624. https://doi.org/10.1016/j.cemconres.2003.12.034
Schiro M, Ruiz-Agudo E, Rodriguez-Navarro C (2012) Damage mechanism of porous materials due to in-pore salt crystallization. Phys Rev Lett 109(5):265–503. https://doi.org/10.1103/PhysRevLett.109.265503
Sousa L, Siegesmund S, Wedekind W (2018) Salt weathering in granitoids: an overview on the controlling factors. Environ Earth Sci 77(13). https://doi.org/10.1007/s12665-018-7669-y
Steiger M (2005a) Crystal growth in porous materials—I: the crystallization pressure of large crystals. J Cryst Growth 282:455–469. https://doi.org/10.1016/j.jcrysgro.2005.05.007
Steiger M (2005b) Crystal growth in porous materials—II: influence of crystal size on the crystallization pressure. J Cryst Growth 282:470–481. https://doi.org/10.1016/j.jcrysgro.2005.05.007
Steiger M, Asmussen S (2008) Crystallization of sodium sulphate phases in porous materials: the phase diagram Na2SO4–H2O and the generation of stress. Geochim Cosmochim Acta 72:4291–4306. https://doi.org/10.1016/j.gca.2008.05.053
Steiger M, Linnow K, Juling H, Gülker G, El Jarad A, Brüggerhoff S, Kirchner D (2008) Hydration of MgSO4-H2O and generation of stress in porous materials. Cryst Growth Des 8:336–343. https://doi.org/10.1021/cg060688c
Steiger M, Linnow K, Ehrhardt D, Rohde M (2011) Decomposition reactions of magnesium sulfate hydrates and phase equilibria in the MgSO4–H2O and Na+–Mg2+–cl−–SO42−–H2O systems with implications for mars. Geochim Cosmochim Acta 75(12):3600–3626. https://doi.org/10.1016/j.gca.2011.03.038
Steiger M, Charola AE, Sterflinger K (2015) Weathering and deterioration. In: Snethlage R, Siegesmund S (eds) Stone in architecture. Springer, Berlin, pp 225–316
Sun Q, Zhang YL (2019) Combined effects of salt, cyclic wetting and drying cycles on the physical and mechanical properties of sandstone. Eng Geol 248:70–79. https://doi.org/10.1016/j.enggeo.2018.11.009
Sun Q, Dong Z, Jia H (2019) Decay of sandstone subjected to a combined action of repeated freezing–thawing and salt crystallization. Bull Eng Geol Environ. https://doi.org/10.1007/s10064-019-01490-6
Torabi-Kaveh M, Heidari M, Mohseni H, Ménendez B (2019) Role of petrography in durability of limestone used in construction of Persepolis complex subjected to artificial accelerated ageing tests. Environ Earth Sci 78(10). https://doi.org/10.1007/s12665-019-8308-y
Tsui N, Flatt RJ, Scherer GW (2003) Crystallization damage by sodium sulphate. J Cult Herit 4:109–115. https://doi.org/10.1016/S1296-2074(03)00022-0
Urban Å, Stigh J, Lindqvist JE, Göransson M (2003) The influence of foliation on the fragility of granitic rocks, image analysis and quantitative microscopy. Eng Geol 68(s3–4):275–288. https://doi.org/10.1016/S0013-7952(02)00233-8
Van TT, Beck K, Al’Mukhtar M (2007) Accelerated weathering tests on two highly porous limestones. Environ Geol 52:282–292. https://doi.org/10.1007/s00254-006-0532-6
Vasconcelos G, Lourenço P, Alves C, Pamplona J (2008) Ultrasonic evaluation of the physical and mechanical properties of granites. Ultrasonics 48:453–466. https://doi.org/10.1016/j.ultras.2008.03.008
Vázquez P, Alonso FJ (2015) Colour and roughness measurements as ndt to evaluate ornamental granite decay. Procedia Earth Planet Sci 15:213–218. https://doi.org/10.1016/j.proeps.2015.08.051
Vázquez P, Luque A, Alonso FJ, Grossi CM (2013) Surface changes on crystalline stones due to salt crystallisation. Environ Earth Sci 69(4):1237–1248. https://doi.org/10.1007/s12665-012-2003-6
Wellman HW, Wilson AT (1965) Salt weathering, a neglected geological erosive agent in coastal and arid environments. Nature 205(4976):1097. https://doi.org/10.1038/2051097a0
Wellman HW, Wilson AT (1968) Salt weathering or fretting. In: Geomorphology. Encyclopedia of Earth Science. Springer, Berlin Heidelberg, pp 968–970. https://doi.org/10.1007/3-540-31060-6_321
Winkler EM (1987) Weathering and weathering rates of natural stone. Environ Geol Water Sci 9:85–92. https://doi.org/10.1007/BF02449939
Winkler EM, Singer PC (1972) Crystallization pressure of salts in stone and concrete. Geol Soc Am Bull 83:3509–3514. https://doi.org/10.1130/0016-7606(1972)83[3509:CPOSIS]2.0.CO;2
Winkler EM, Wilhelm EJ (1970) Salt burst by hydration pressures in architectural stone in an urban atmosphere. Geol Soc Am Bull 81:567–572. https://doi.org/10.1130/0016-7606(1970)81[567:SBBHPI]2.0.CO;2
Yu S, Oguchi CT (2010) Is sodium sulphate invariably effective in destroying any type of rock? Geol Soc London Spec Publ 333(1):43–58. https://doi.org/10.1144/SP333.5
Zehnder K, Arnold A (1989) Crystal growth in salt efflorescence. J Cryst Growth 97:513–521. https://doi.org/10.1016/0022-0248(89)90234-0
Zhao Z, Yang J, Zhang D, Peng H (2017) Effects of wetting and cyclic wetting-drying on the tensile strength of sandstone with a low clay mineral content. Rock Mech Rock Eng 50(2):485–491. https://doi.org/10.1007/s00603-016-1087-9
Zhou Z, Cai X, Chen L, Cao W, Zhao Y, Xiong C (2017) Influence of cyclic wetting and drying on physical and dynamic compressive properties of sandstone. Eng Geol 220:1–12. https://doi.org/10.1016/j.enggeo.2017.01.017
Zhou Z, Cai X, Ma D, Chen L, Wang S, Tan L (2018) Dynamic tensile properties of sandstone subjected to wetting and drying cycles. Constr Build Mater 182:215–232. https://doi.org/10.1016/j.conbuildmat.2018.06.056
Acknowledgements
We also thank the technicians who helped during the experiments and the anonymous reviewers for their constructive comments.
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This research was supported by the National Natural Science Foundation of China (Grant Nos. 41672279 and 41807233) and the Natural Science Foundation of Jiangsu Province (Grant No. BK20180662).
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Zhao, F., Sun, Q. & Zhang, W. Combined effects of salts and wetting–drying cycles on granite weathering. Bull Eng Geol Environ 79, 3707–3720 (2020). https://doi.org/10.1007/s10064-020-01773-3
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DOI: https://doi.org/10.1007/s10064-020-01773-3