Abstract
Because of their excellent properties, such as corrosion resistance, fatigue strength and biocompatibility, cobalt-based alloys are widely used in total hip and knee replacements, dental devices and support structures for heart valves. In this work, CoCrMo alloys were synthesized using a novel method based on combustion synthesis (CS), an advanced technique to produce a wide variety of materials including alloys and near-net shape articles. This method possesses several advantages over conventional processes, such as low energy requirements, short processing times and simple equipment. The evaluated material properties included density and yield measurements, composition and microstructure analysis, hardness, friction and tensile tests. It was shown that microstructure of CS-material is finer and more uniform as compared to the conventional standard. It was also found that among various additives, Cr3C2 is the most effective one for increasing material hardness. In addition, synthesized CoCrMo alloys exhibited good friction and mechanical properties.
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Martinelli KA, Lemaitre DT, Lee TJ (2001, November 21) Orthopedic Industry: Update and Company Models. Merrill Lynch, New York, p 1
Saleh KJ (2001) Clinical Orthopedic and Related Research 392:153
Cushner F, Friedman RJ (1988) South Med J 81:1379
Keller JC, Lautenschlager EP (1986) Metals and alloys. In: von Recuum AF (ed) Handbook of biomaterials evaluation. Macmillan, New York, p 3
Granchi D, Ciapetti G, Stea S, Savarino L, Filippini F, Sudanese A, Zinghi G, Montanaro L (1999) Biomater 20:1079
Muster D, Hage-Ali M, Rie KT, Stucky T, Cornet A, Mainard D (2000) MRS Bull 25:25
Asphahani AI (1988) Corrosion of cobalt-base alloy. In: ASM metal handbook, 9th edition. ASM International, Metals Park, Ohio, 13:658
Shetty RH, Ottersberg WH (1995) Metals in orthopaedic surgery. In: Wise DL (ed) Encyclopedic handbook of biomaterials and bioengineering, Part B; Applications. Marcel Dekker, New York, p 509
Gómez M, Mancha H, Salinas A, Rodríguez JL, Escobedo J, Castro M, Méndez M (1997) J Biomed Mater Res 34:157
Munir ZA, Anselmi-Tamburini U (1989) Mater Sci Rep 3:277
Varma A, Mukasyan AS (1998) Combustion synthesis of advanced materials. In: Powder metal technologies and applications, ASM Handbook. ASM International, Materials Park, Ohio, p 523
Merzhanov AG (1990) Self-propagating high-temperature synthesis: twenty years of search and findings. In: Munir ZA, Holt JB (eds) Combustion and plasma synthesis of high-temperature materials. VCH, New York, p 1
Yukhvid VI (1992) Pure & Appl Chem 64:977
Odawara O (1996) Key Eng Mater 122:463
Seshadri R (2000) Metals Mater Proc 12:233
Ohmi T, Murota Y, Kudoh M (2001) Mater Trans 42:298
Yukhvid VI, Sanin VN, Nersesyan MD, Luss D (2002) Int J SHS 11:65
Shiryaev A (1995) Int J SHS 4:351
Varma A, Li B, Mukasyan A (2002) Adv Eng Mater 4:482
Lau C, Mukasyan AS, Varma A (2002) Proc Combust Inst 29:1101
Odawara O (1990) J Am Ceram Soc 73:629
Halverson DC, Ewald KH, Munir ZA (1995) J Mater Sci 30:3697
Tandon R (1999) Net-shaping of Co-Cr-Mo (F-75) via metal injection molding. In: Disegi JA, Kennedy RL, Pilliar R (eds) Cobalt-base alloys for biomedical applications.,ASTM STP 1365.: ASTM, West Conshohocken, PA, p 3
Mancha H, Gomez M, Castro M, Mendez M, Juarez J (1996) J Mater Syn Process 4:217
Huang P, Lopez HF (1999) Adv Sci Technol 28:111
Que L, Timmie LD, Parks NL (2000) J Biomed Mater Res 53:111
Saikko V, Calonius O, Keranen (2001) J Biomed Mater Res 57:506
Jinno T, Goldberg VM, Davy D, Stevenson S (1998) J Biomed Mater Res 42:20
Acknowledgements
The financial support by the 21st Century Research & Technology Fund, State of Indiana, is gratefully acknowledged. We also thank Dr. Ravi Shetty, Zimmer, Inc., Warsaw, IN for his interest in this work and assistance with materials characterization.
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Li, B., Mukasyan, A. & Varma, A. Combustion synthesis of CoCrMo orthopedic implant alloys: microstructure and properties. Mat Res Innovat 7, 245–252 (2003). https://doi.org/10.1007/s10019-003-0260-4
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DOI: https://doi.org/10.1007/s10019-003-0260-4