Skip to main content
SpringerLink
Log in

One-pot electrosynthesis and physicochemical properties of multifunctional material based on graphene oxide, poly-o-phenylenediamine, and silicotungstic acid

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

The methods of silicotungstic acid (SiW) immobilization on conducting substrates were studied. For SiW immobilization by codeposition, poly-o-phenylenediamine (PPD) redox polymer was used. The most effective codeposition of SiW and PPD was demonstrated on a graphene oxide (GO) film. Meanwhile, GO is reduced to form RGO-PPD-SiW electroactive composite. The structure of the novel material was evidenced by cyclic voltammetry and IR and Raman spectra. PPD-SiW and RGO-PPD-SiW composites were studied by impedance spectroscopy, where an equivalent circuit was proposed. Film resistance Rf was shown to decrease in the series of PPD → RGO-PPD → RGO-PPD-SiW. Further, RGO-PPD-SiW has better transfer properties (bulk film diffusion rate). This enabled suggesting that the composite has better electrocatalytic properties than PPD and RGO-PPD as was evidenced for example of [Fe(CN)6]4−/3− redox transfer on the electrode coated with the novel material.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3
Fig. 4
Fig. 5
Fig. 6
Fig. 7
Fig. 8
Fig. 9
Fig. 10
Fig. 11
Fig. 12
Fig. 13

Similar content being viewed by others

Notes

  1. Avtocom, Moscow, http://www.membrans.ru/

  2. www.graphenox-ru.com

  3. Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Russia

  4. Produced by Electrochemical Instruments (Chernogolovka, Moscow Region). http://potentiostat.ru

References

  1. Peresypkina EV, Virovets AV, Adonin SA, Abramov PA, Rogachev AV, Sinkevich PL, Korenev VS, Sokolov MN (2014) Crystal structure of two salts derived from paratungstate in the [H2W12O42]10− anion. J Struct Chem 55:295–298

    Article  CAS  Google Scholar 

  2. Prudent R, Moucadel V, Laudet B, Barette C, Lafanechère L, Hasenknopf B, Li J, Bareyt S, Lacôte E, Thorimbert S, Malacria M, Gouzerh P, Cochet C (2008) Identification of polyoxometalates as nanomolar noncompetitive inhibitors of protein kinase. CK2 Chem Biol 15(7):83–692

    Google Scholar 

  3. Rhule JT, Hill CL, Judd DA (1998) Polyoxometalates in medicine. Chem Rev 98:327–357

    Article  CAS  Google Scholar 

  4. Li T, Zhang Z, Li W, Liu C, Zhou H, An L (2016) Electrospinning preparation, characterization, and enhanced photocatalytic activity of an silicotungstic acid (H4SiW12O40)/poly(vinyl alcohol)/poly(methyl methacrylate) composite nanofiber membrane. J Appl Polym Sci 133:43193

    Google Scholar 

  5. Herrmann S, Ritchie C, Streb C (2015) Polyoxometalate – conductive polymer composites for energy conversion, energy storage and nanostructured sensors. Dalton Trans 44:7092–7104

    Article  CAS  Google Scholar 

  6. Tamirat AG, Guan X, Liu J, Luo J, Xia Y (2020) Redox mediators as charge agents for changing electrochemical reactions. Chem Soc Rev 49:7454

    Article  CAS  Google Scholar 

  7. Sadakane M, Steckhan E (1998) Electrochemical properties of polyoxometalates as electrocatalysts. Chem Rev 98(1):219–237

    Article  CAS  Google Scholar 

  8. Guo D, Zhou C, Tan L, Ma H, He R, Pang H, Wang X (2020) Electrochemical ascorbic acid sensor of composite film based on Keggin-type Vanadium-substituted polyoxometalates decorated with graphene and Ru (bpy)32+. Colloids Surf A 592:124550

    Article  CAS  Google Scholar 

  9. Liu L, Wang B, Du Y, Borgna A (2015) Supported H4SiW12O40/Al2O3 solid acid catalysts for dehydration of glycerol to acrolein: avolution of catalyst structure and performance with calcination temperature. Appl Catal A: Gen 489:32–41

    Article  CAS  Google Scholar 

  10. Pisarevskaya EY, Efimov ON (2019) Graphene oxide as a basis for molecular design. Prot Met Phys Chem Surf 55:468–472

    Article  CAS  Google Scholar 

  11. Wang B, Dong S (1996) Electrochemical study of isopoly- and heteropoly-oxometalates film modified microelectrodes —vi preparation and redox properties of 12-molybdophosphoric acid and 12-molybdosilicic acid modified carbon fiber microelectrodes. Electrochim Acta 41:895–902

    Article  CAS  Google Scholar 

  12. Pisarevskaya EY, Makarychev YB, Dremova NN, Girina GP, Efimov ON (2018) A study of a novel nanocomposite material based on reduced graphene oxide and poly(o-phenylenediamine). Prot Met Phys Chem Surf 54:393–401

    Article  CAS  Google Scholar 

  13. Pisarevskaya EY, Rychagov AY, Gorbunov AM, Averin AA, Makarychev YB, Efimov ON (2018) Synthesis of nanostructured conducting composite films based on reduced graphene oxide and o-phenylenediamine. Synth Met 243:1–7

    Article  CAS  Google Scholar 

  14. Pisarevskaya EY, Kolesnichenko II, Averin AA, Gorbunov AM, Efimov ON (2020) A novel multifunctional composite based on reduced graphene oxide, poly-o-phenylenediamine and silicotungstic acid. Synth Met 270:116596

    Article  CAS  Google Scholar 

  15. Aparicio-Anglès X, Clotet A, Bo C, Poblet JM (2011) Towards the computational modelling of polyoxoanions on metal surfaces: IR spectrum characterisation of [SiW12O40]4− on Ag(111). Phys Chem Chem Phys 13(33):15143–15147

    Article  Google Scholar 

  16. Gurunathan S, Han JW, Kim E, Park JH, Kim J (2015) Reduction of graphene oxide by resveratrol: a novel and simple biological method for the synthesis of an effective anticancer nanotherapeutic molecule. Int J Nanomed 10:2951–2969

    Article  CAS  Google Scholar 

  17. Pisarevskaya EYu, Averin AA, Makarychev YB, Efimov ON (2019) Modifying graphene oxide and poly-o-phenylene diamine-graphene oxide composite with palladium particles. 257:116153

  18. Ucar A, Findik M, Gubbuk IH, Kocak N, Bingol H (2017) Catalytic degradation of organic dye using reduced graphene oxide–polyoxometalate nanocomposite. Mater Chem Phys 196:21–28

    Article  CAS  Google Scholar 

  19. Bilal S, Shah A-u-HA, Holze R (2011) Spectroelectrochemistry of poly(o-phenylenediamine): polyaniline-like segments in the polymer structure. Electrochim Acta 56(9):3353–3358

    Article  CAS  Google Scholar 

  20. Wu L-L, Luo J, Lin Z-H (1996) Spectroelectrochemical studies of poly-o-phenylenediamine part 1 In situ resonance Raman spectroscopy. J Electroanal Chem 417(1-2):53–58

    Article  CAS  Google Scholar 

  21. Martinusz K, Láng G, Inzelt G (1997) Impedance analysis of poly(o-phenylenediamine) electrodes. J Electroanal Chem 433(1-2):1–8

    Article  CAS  Google Scholar 

  22. Láng GG, Ujvári M, Inzelt G (2004) Analysis of the impedance spectra of Pt|poly(o-phenylenediamine) electrodes - hydrogen adsorption and the brush model of the polymer films. J Electroanal Chem 572(2):283–297

    Article  Google Scholar 

  23. Orasem ME, Tribollet B (2008) Electrochemical impedance spectroscopy. Wiley, The Electrochemical Society series ISBN 978-0-470-04140-6

    Book  Google Scholar 

  24. Levi MD, Pisarevskaya EY (1992) Cyclic and steady-state voltammetric studies of the mechanism and kinetics of some solute inorganic redox-species reactions at a gold electrode covered with poly-o-phenylenediamine. Electrochim Acta 37:635–641

    Article  CAS  Google Scholar 

Download references

Acknowledgments

The work was performed within the State Program of IPCE RAS and IPCP RAS (no. of state registration are АААА-А19-119041890032-6 and АААА-А19-119071190044-3).

Author information

Authors and Affiliations

  1. A. N. Frumkin Institute of Physical Chemistry and Electrochemistry, Russian Academy of Sciences, Leninskiy Prospect, 31, Moscow, Russia, 119071

    E. Yu. Pisarevskaya, A. L. Klyuev, A. A. Averin & A. M. Gorbunov

  2. Institute for Problems of Chemical Physics, Russian Academy of Sciences, 1 Acad. Semenov Ave., Chernogolovka, Moscow Region, Russia, 142432

    O. N. Efimov

Authors
  1. E. Yu. Pisarevskaya
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. A. L. Klyuev
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. A. Averin
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. A. M. Gorbunov
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. O. N. Efimov
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to E. Yu. Pisarevskaya.

Additional information

Publisher’s note

Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations.

Supplementary information

ESM 1

(DOC 596 kb)

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Pisarevskaya, E.Y., Klyuev, A.L., Averin, A.A. et al. One-pot electrosynthesis and physicochemical properties of multifunctional material based on graphene oxide, poly-o-phenylenediamine, and silicotungstic acid. J Solid State Electrochem 25, 859–868 (2021). https://doi.org/10.1007/s10008-020-04859-w

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-020-04859-w

Keywords

Search

Navigation