Abstract
A facile synthetic protocol for the electrodeposition of diverse morphologies of silver on disposable pencil graphite electrodes (Ag/PGE) in the presence of chitosan as structure-directing agent (SDA) is reported. The influence of various electrodeposition parameters on the morphology of Ag deposited has been studied and interpreted using electron microscopic techniques. Several impressive morphologies such as hexahedron, leaf and dendrites have been observed for Ag/PGE with respect to change in experimental conditions. Furthermore, the crucial role of chitosan in determining the morphology of Ag/PGE has been elucidated with the help of three-dimensional Scharifker-Hills nucleation and growth model. The electrocatalytic activities of various Ag/PGEs towards the reduction of hydrogen peroxide (HP) and oxidation of hydrazine hydrate (HH) have been studied in detail with the help of diverse electrochemical techniques. In comparison with PGE, the Ag hexahedron- (Ag-Hex/PGE) and Ag dendrite- (Ag-Dend/PGE) modified PGEs exhibited excellent electrocatalytic activity towards HP and HH, respectively. The Ag-Hex/PGE displayed a wide linear range of 0.1–20,000 μM with a limit of detection (LOD, 3σ/m) of 0.06 μM for HP reduction. On the other hand, a linear range of 25–20,000 μM with LOD of 1.8 μM for HH oxidation has been observed for Ag-Dend/PGE. Furthermore, the modified Ag/PGEs revealed remarkable reproducibility and long-term storage stability. The practical applicability of the Ag-Hex/PGE and Ag-Dend/PGE was demonstrated through the electrocatalytic detection of HP in milk and HH in tap water samples with satisfactory recovery results.
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References
Welch CM, Compton RG (2006) The use of nanoparticles in electroanalysis: a review. Anal Bioanal Chem 384(3):601–619. https://doi.org/10.1007/s00216-005-0230-3
Holzinger M, Le Goff A, Cosnier S (2014) Nanomaterials for biosensing applications: a review. Front Chem 2:1–10. https://doi.org/10.3389/fchem.2014.00063
Akanda MR, Sohail M, Aziz MA, Kawde AN (2016) Recent advances in nanomaterial-modified pencil graphite electrodes for electroanalysis. Electroanalysis 28(3):408–424. https://doi.org/10.1002/elan.201500374
Zhu J, Hu L, Zhao P, Lee LYS, Wong K (2019) Recent advances in electrocatalytic hydrogen evolution using nanoparticles. Chem Rev 120(2):851–918. https://doi.org/10.1021/acs.chemrev.9b00248
Jena BK, Retna Raj C (2007) Ultrasensitive nanostructured platform for the electrochemical sensing of hydrazine. J Phys Chem C 111(17):6228–6232. https://doi.org/10.1021/jp0700837
Katz E, Willner I (2004) Integrated nanoparticle-biomolecule hybrid systems: synthesis, properties, and applications. Angew Chem 43(45):6042–6108. https://doi.org/10.1002/anie.200400651
Haruta M (1997) Size- and support-dependency in the catalysis of gold. Catal Today 36(1):153–166. https://doi.org/10.1016/S0920-5861(96)00208-8
Zhong CJ, Maye MM (2001) Core-shell assembled nanoparticles as catalysts. Adv Mater 13(19):1507–1511. https://doi.org/10.1002/1521-4095(200110)13:19<1507::AID-ADMA1507>3.0.CO;2-%23
Mohanraj VJ, Chen Y (2006) Nanoparticles-a review. Trop J Pharm Res 5(1):561–573. https://doi.org/10.4314/tjpr.v5i1.14634
Khan I, Saeed K, Khan I (2019) Nanoparticles: properties, applications and toxicities. Arab J Chem 12(7):908–931. https://doi.org/10.1016/j.arabjc.2017.05.011
Jeevanandam J, Barhoum A, Chan YS, Dufresne A, Danquah MK (2018) Review on nanoparticles and nanostructured materials: history, sources, toxicity and regulations. Beilstein J Nanotechnol 9:1050–1074. https://doi.org/10.3762/bjnano.9.98
Ealias AM, Saravanakumar MP (2017) A review on the classification, characterisation, synthesis of nanoparticles and their application. IOP Conf Ser Mater Sci Eng 263(3):032019–032034. https://doi.org/10.1088/1757-899X/263/3/032019
Açıkyıldız M, Gürses A, Korucu ME, Güneş K (2014) Electrocatalysis and the production of nanoparticles. Modern electrochemical methods in nano, surface and corrosion science. InTech. https://doi.org/10.5772/58340
Lee S, Jun BH (2019) Silver nanoparticles: synthesis and application for nanomedicine. Int J Mol Sci 20(4):865. https://doi.org/10.3390/ijms20040865
Rafique M, Sadaf I, Rafique MS, Tahir MB (2017) A review on green synthesis of silver nanoparticles and their applications. Artif Cell Nanomed B 45(7):1272–1291. https://doi.org/10.1080/21691401.2016.1241792
Syafiuddin A, Salmiati SMR, Kueh ABH, Hadibarata T, Nur H (2017) A review of silver nanoparticles: research trends, global consumption, synthesis, properties, and future challenges. J Chin Chem Soc 64(7):732–756. https://doi.org/10.1002/jccs.201700067
Chouhan N (2018) Silver nanoparticles: synthesis, characterization and applications. InTech. https://doi.org/10.5772/intechopen.75611
Rauwel P, Küünal S, Ferdov S, Rauwel E (2015) A review on the green synthesis of silver nanoparticles and their morphologies studied via TEM. Adv Mater Sci Eng. https://doi.org/10.1155/2015/682749
Rodríguez-Sánchez L, Blanco MC, López-Quintela MA (2000) Electrochemical synthesis of silver nanoparticles. J Phys Chem B 104(41):9683–9688. https://doi.org/10.1021/jp001761r
Starowicz M, Stypuła B, Banaś J (2006) Electrochemical synthesis of silver nanoparticles. Electrochem Commun 8(2):227–230. https://doi.org/10.1016/j.elecom.2005.11.018
Nasretdinova GR, Fazleeva RR, Mukhitova RK, Nizameev IR, Kadirov MK, Ziganshina AY, Yanikin VV (2015) Electrochemical synthesis of silver nanoparticles in solution. Electrochem Commun 50:69–72. https://doi.org/10.1016/j.elecom.2014.11.016
Kuntyi KR, Mertsalo IP, Mazur AS, Zozula GI, Bazylyak LI, Topchak RV (2019) Electrochemical synthesis of silver nanoparticles by reversible current in solutions of sodium polyacrylate. Colloid Polym Sci. 297(5):689–695. https://doi.org/10.1007/s00396-019-04488-4
Singaravelan R, Alwar SBS (2015) Electrochemical synthesis, characterisation and phytogenic properties of silver nanoparticles. Appl Nanosci 5(8):983–991. https://doi.org/10.1007/s13204-014-0396-0
Sivasubramanian R, Sangaranarayanan MV (2015) A facile formation of silver dendrites on indium tin oxide surfaces using electrodeposition and amperometric sensing of hydrazine. Sensor Actuat B Chem 213:92–101. https://doi.org/10.1016/j.snb.2015.02.065
Sivasubramanian R, Sangaranarayanan MV (2013) Electrodeposition of silver nanostructures: from polygons to dendrites. CrystEngComm. 15(11):2052–2056. https://doi.org/10.1039/c3ce26886a
Liu B, Wang M (2013) Electrodeposition of dendritic silver nanostructures and their application as hydrogen peroxide sensor. Int J Electrochem Sci 8:8572–8578 http://www.electrochemsci.org/papers/vol8/80608572.pdf. Accessed 19 March 2020
Rudnik E, Burzyńska L (2006) Influence of organic additives on morphology and purity of cathodic silver. Arch Metall Mater 51(1):137–144 https://www.infona.pl/resource/bwmeta1.element.baztech-article-BSW3-0024-0020. Accessed 19 March 2020
Roldán MV, Pellegri N, de Sanctis O (2013) Electrochemical method for Ag-PEG nanoparticles synthesis. J Nanoparticles 2013:1–7. https://doi.org/10.1155/2013/524150
Wei D, Sun W, Qian W, Ye Y, Ma X (2009) The synthesis of chitosan-based silver nanoparticles and their antibacterial activity. Carbohydr Res 344(17):2375–2382. https://doi.org/10.1016/j.carres.2009.09.001
Kalaivani R, Maruthupandy M, Muneeswaran T, Beevi AH, Anand M, Ramakritinam CH (2018) Synthesis of chitosan mediated silver nanoparticles (Ag NPs) for potential antimicrobial applications. Front Lab Med 2(1):30–35. https://doi.org/10.1016/j.flm.2018.04.002
Ray C, Dutta S, Roy A, Sahoo R, Pal T (2016) Redox mediated synthesis of hierarchical Bi2O3/MnO2 nanoflowers: a non-enzymatic hydrogen peroxide electrochemical sensor. Dalt Trans 45(11):4780–4790. https://doi.org/10.1039/c6dt00062b
Kim Y, Park JY, Kim HY, Lee M, Yi J, Choi I (2015) A single nanoparticle-based sensor for hydrogen peroxide (H2O2) via cytochrome c-mediated plasmon resonance energy transfer. Chem Commun 51(84):15370–15373. https://doi.org/10.1039/c5cc05327g
Maduraiveeran G, Kundu M, Sasidharan M (2018) Electrochemical detection of hydrogen peroxide based on silver nanoparticles via amplified electron transfer process. J Mater Sci 53(11):8328–8338. https://doi.org/10.1007/s10853-018-2141-7
Sawangphruk M, Sanguansak Y, Krittayavathananon A, Luanwuthi S, Srimuk P, Nilmaung S, Maensiri S, Meevasana W, Limtrakul J (2014) Silver nanodendrite modified graphene rotating disk electrode for nonenzymatic hydrogen peroxide detection. Carbon 70:287–294. https://doi.org/10.1016/j.carbon.2014.01.010
Metters JP, Tan F, Kadara RO, Banks CE (2012) Platinum screen printed electrodes for the electroanalytical sensing of hydrazine and hydrogen peroxide. Anal Methods 4(5):1272–1277. https://doi.org/10.1039/c2ay05934g
Becker RA, Barrows LR, Shank RC (1981) Methylation of liver DNA guanine in hydrazine hepatotoxicity: dose-response and kinetic characteristics of O6-methylguanine and formation and persistence in rats. Carcinogenesis 2(11):1181–1188. https://doi.org/10.1093/carcin/2.11.1181
Chen W, Cai S, Ren QQ, Wen W, Zhao YD (2012) Recent advances in electrochemical sensing for hydrogen peroxide: a review. Analyst 137(1):49–58. https://doi.org/10.1039/C1AN15738H
Yamada K, Yasuda K, Fujiwara N, Siroma Z, Tanaka H, Miyazaki Y, Kobayashi T (2003) Potential application of anion-exchange membrane for hydrazine fuel cell electrolyte. Electrochem Commun 5(10):892–896. https://doi.org/10.1016/j.elecom.2003.08.015
Dhara K, Mahapatra DR (2019) Recent advances in electrochemical nonenzymatic hydrogen peroxide sensors based on nanomaterials: a review. J Mater Sci 54(19):12319–12357. https://doi.org/10.1007/s10853-019-03750-y
Chen S, Yuan R, Chai Y, Hu F (2013) Electrochemical sensing of hydrogen peroxide using metal nanoparticles: a review. Microchim Acta 180(1–2):15–32. https://doi.org/10.1007/s00604-012-0904-4
Org WE, Meng Z, Liu B, Li M (2017) A sensitive hydrazine electrochemical sensor based on Ag-Ni alloy/reduced graphene oxide composite. Int J Electrochem Sci 12:10269–10278. https://doi.org/10.20964/2017.11.15
Zhou X, Wang Y, Liang Z, Jin H (2018) Electrochemical deposition and nucleation/growth mechanism of Ni–Co–Y2O3 multiple coatings. Materials 11(7):1124–1137. https://doi.org/10.3390/ma11071124
Gilani NS, Azizi SN, Ghasemi S (2017) Sensitive amperometric determination of hydrazine using a carbon paste electrode modified with silver-doped zeolite L nanoparticles. Bull Mater Sci 40(1):177–185. https://doi.org/10.1007/s12034-016-1351-3
Scharifker B, Hills G (1983) Theoretical and experimental studies of multiple nucleation. Electrochim Acta 28(7):879–889. https://doi.org/10.1016/0013-4686(83)85163-9
Raeissi K, Saatchi A, Golozar MA (2003) Effect of nucleation mode on the morphology and texture of electrodeposited zinc. J Appl Electrochem 33(7):635–642. https://doi.org/10.1023/A:1024914503902
Hwang BJ, Santhanam R, Lin YL (2001) Nucleation and growth mechanism of electroformation of polypyrrole on a heat-treated gold/highly oriented pyrolytic graphite. Electrochim Acta 46(18):2843–2853. https://doi.org/10.1016/S0013-4686(01)00495-9
Wang Y, Northwood DO (2008) An investigation into the nucleation and growth of an electropolymerized polypyrrole coating on a 316L stainless steel surface. Thin Solid Films 516(21):7427–7432. https://doi.org/10.1016/j.tsf.2008.02.049
Witten TA, Sander IM (1981) Diffusion-limited aggregation, a kinetic critical phenomenon. Phys Rev Lett 47(19):1400–1403. https://doi.org/10.1103/PhysRevLett.47.1400
Meakin P (1983) Diffusion-controlled cluster formation in two, three, and four dimensions. Phys Rev A 27(1):604–607. https://doi.org/10.1103/PhysRevA.27.604
Zhong L, Gan S, Fu X, Li F, Han D, Guo L, Niu L (2013) Electrochemically controlled growth of silver nanocrystals on graphene thin film and applications for efficient nonenzymatic H2O2 biosensor. Electrochim Acta 89:222–228. https://doi.org/10.1016/j.electacta.2012.10.161
Girija TC, Sangaranarayanan MV (2006) Analysis of polyaniline-based nickel electrodes for electrochemical supercapacitors. J Power Sources 156(2):705–711. https://doi.org/10.1016/j.jpowsour.2005.05.051
Chaudhari S, Patil PP (2011) Inhibition of nickel coated mild steel corrosion by electrosynthesized polyaniline coatings. Electrochim Acta 56(8):3049–3059. https://doi.org/10.1016/j.electacta.2010.12.096
Analytical Methods Committee (1987) Recommendations for the definition, estimation and use of the detection limit. Analyst 112(2):199–204. https://doi.org/10.1039/AN9871200199
Yang X, Bai J, Wang Y, Jiang X, He X (2012) Hydrogen peroxide and glucose biosensor based on silver nanowires synthesized by polyol process. Analyst 137(18):4362–4367. https://doi.org/10.1039/c2an35407a
Kurowska E, Brzózka A, Jarosz M, Sulka GD, Jaskuła M (2013) Silver nanowire array sensor for sensitive and rapid detection of H2O2. Electrochim Acta 104:439–447. https://doi.org/10.1016/j.electacta.2013.01.077
Wang QM, Niu HL, Mao CJ, Song JM, Zhang SY (2014) Facile synthesis of trilaminar core-shell Ag@C@Ag nanospheres and their application for H2O2 detection. Electrochim Acta 127:349–354. https://doi.org/10.1016/j.electacta.2014.02.051
Shi L, Layani M, Cai X, Zhao H, Shlomo M, Lan M (2018) An inkjet printed Ag electrode fabricated on plastic substrate with a chemical sintering approach for the electrochemical sensing of hydrogen peroxide. Sensor Actuat B Chem 256:938–945. https://doi.org/10.1016/j.snb.2017.10.035
Rastogi PK, Ganesan V, Krishnamoorthi S (2014) Palladium nanoparticles decorated gaur gum based hybrid material for electrocatalytic hydrazine determination. Electrochim Acta 125:593–600. https://doi.org/10.1016/j.electacta.2014.01.148
Kim SP, Choi HC (2015) Reusable hydrazine amperometric sensor based on Nafion®-coated TiO2-carbon nanotube modified electrode. Sensor Actuat B-Chem 207:424–429. https://doi.org/10.1016/j.snb.2014.10.029
Rao D, Sheng Q, Zheng J (2016) Preparation of flower-like Pt nanoparticles decorated chitosan-grafted graphene oxide and its electrocatalysis of hydrazine. Sensor Actuat B Chem 236:192–200. https://doi.org/10.1016/j.snb.2016.05.160
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Preethi, S., Sangaranarayanan, M.V. Shape-controlled electrodeposition of silver using chitosan as structure-directing agent on disposable pencil graphite electrodes: low-cost electrocatalysts for the detection of hydrogen peroxide and hydrazine hydrate. J Solid State Electrochem 24, 2773–2788 (2020). https://doi.org/10.1007/s10008-020-04579-1
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DOI: https://doi.org/10.1007/s10008-020-04579-1