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Improved photoelectric performance of DSSCs based on TiO2 nanorod array/Ni-doped TiO2 compact layer composites film

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Abstract

In spite of the TiO2 compact layer (TCL) being widely used, it still needs more study. This paper took Ni-doped TCLs as the research target, using an innovative two-step method perfectly prepared Ni-doped TCLs with different thicknesses. And then on the basis of Ni-doped TCLs, the TiO2 nanorod array (TNA) films were successfully prepared. The effects of Ni-doped TCLs with different thicknesses on the morphology, structure, and photoelectric performance of TNA films were investigated. The results indicated that Ni-doped TCLs with appropriate thickness can significantly improve performance of TNA films and obtain satisfactory PCE stability with time. Compared with the TNA films based on Ni:TCL5, Ni:TCL10, and Ni:TCL30, the TNA film with Ni:TCL20 exhibited better comprehensive photoelectric performance, the DSSCs based on this TNA film achieved the highest Jsc (10.191 mA cm−2), Voc (0.574 V), PCE (4.42%), and the most excellent PCE stability with time.

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Funding

This work was supported by the Chinese Postdoctoral Science Fund (2343/185179), the Chinese 02 Special Fund (2017ZX02408003), the Key Research Projects of Colleges and Universities in Henan province (15A430023), and the Henan International Science and Technology Cooperation Programs (152102410035).

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Authors and Affiliations

  1. School of Materials Science and Engineering, Henan University of Science and Technology, Luoyang, 471023, People’s Republic of China

    Yafeng Deng, Zhanhong Ma, Fengzhang Ren & Guangxin Wang

  2. Henan Collaborative Innovation Centre of Non-Ferrous Generic Technology, Luoyang, 471023, People’s Republic of China

    Zhanhong Ma & Fengzhang Ren

  3. Henan Key Laboratory of Non-Ferrous Materials Science and Processing Technology, Luoyang, 471023, People’s Republic of China

    Guangxin Wang

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  1. Yafeng Deng
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Correspondence to Zhanhong Ma or Fengzhang Ren.

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Deng, Y., Ma, Z., Ren, F. et al. Improved photoelectric performance of DSSCs based on TiO2 nanorod array/Ni-doped TiO2 compact layer composites film. J Solid State Electrochem 23, 3031–3041 (2019). https://doi.org/10.1007/s10008-019-04399-y

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