Abstract
LiNi0.8Co0.15Al0.05O2 (NCA) material was decorated with different contents of Cr2O3 (0.01–2 wt%) via a precipitation technique followed by calcination at 600 °C. The existence of the coating on the NCA particles was confirmed by SEM and elemental EDS mapping. XRD analysis showed that the addition of Cr2O3 did not change the crystalline structure of NCA. The electrochemical performance of samples was evaluated by cyclability, cyclic voltammetry, electrochemical impedance spectroscopy, and rate capability tests. Electrochemical evaluations revealed that the addition of 0.25–0.5 wt% Cr2O3 not only enhanced the electrochemical reversibility of NCA but also improved its rate capability. The capacity retention of 92.1% after 50 cycles at the 0.5C rate was obtained for the optimized material, while the bare NCA retained a capacity of 69%. At a rate of 2C, the specific discharge capacity of the optimized material was 162.2 mAh g−1, while it was 149.7 mAh g−1 for the bare one. These enhancements may be attributed to the stability of the surface film on the NCA, reduction of the SEI layer thickness, and reduction of charge-transfer resistance of the electrode due to the Cr2O3 protection layer on the cathode material, which reduced the side reactions of the cathode material with the electrolyte.
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References
Soloveichik GL (2011) Battery technologies for large-scale stationary energy storage. Annu Rev Chem Biomol Eng 2(1):503–527
Baker J (2008) New technology and possible advances in energy storage. Energy Policy 36(12):4368–4373
Moghim MH, Eqra R, Babaiee M, Zarei-Jelyani M, Loghavi MM (2017) Role of reduced graphene oxide as nano-electrocatalyst in carbon felt electrode of vanadium redox flow battery. J Electroanal Chem 789:67–75
Chang C, Xiang J, Li M, Han X, Yuan L, Sun J (2009) Improved disordered carbon as high performance anode material for lithium ion battery. J Solid State Electrochem 13(3):427–431
Yu C, Bai Y, Yan D, Li X, Zhang W (2014) Improved electrochemical properties of Sn-doped TiO2 nanotube as an anode material for lithium ion battery. J Solid State Electrochem 18(7):1933–1940
Loghavi MM, Askari M, Babaiee M, Ghasemi A (2019) Improvement of the cyclability of Li-ion battery cathode using a chemical-modified current collector. J Electroanal Chem 841:107–110
Dehghan F, Mohammadi-Manesh H, Loghavi MM (2019) Investigation of lithium-ion diffusion in LiCoPO4 cathode material by molecular dynamics simulation. J Struct Chem 60(5):727–735
Zhao B, Ran R, Liu M, Shao Z (2015) A comprehensive review of Li4Ti5O12-based electrodes for lithium-ion batteries: the latest advancements and future perspectives. Mater Sci Eng R 98:1–71
Pistoia G (2005) Batteries for portable devices. Elsevier, Amsterdam
Cao H, Xia B, Xu N, Zhang C (2004) Structural and electrochemical characteristics of Co and Al co-doped lithium nickelate cathode materials for lithium-ion batteries. J Alloys Compd 376(1-2):282–286
Delmas C, Saadoune I, Rougier A (1993) The cycling properties of the LixNi1−yCoyO2 electrode. J Power Sources 44(1-3):595–602
Palacin M, Larcher D, Audemer A, Sac-Épée N, Amatucci G, Tarascon JM (1997) Low-temperature synthesis of LiNiO2 reaction mechanism, stability, and electrochemical properties. J Electrochem Soc 144:4226–4236
Levi E, Levi M, Salitra G, Aurbach D, Oesten R, Heider U, Heider L (1999) Electrochemical and in-situ XRD characterization of LiNiO2 and LiCo0.2Ni0.8O2 electrodes for rechargeable lithium cells. Solid State Ionics 126(1-2):97–108
Hildebrand S, Vollmer C, Winter M, Schappacher FM (2017) Al2O3, SiO2 and TiO2 as coatings for safer LiNi0.8Co0.15Al0.05O2 cathodes: electrochemical performance and thermal analysis by accelerating rate calorimetry. J Electrochem Soc 164(9):A2190–A2198
Dai G, Yu M, Shen F, Cao J, Ni L, Chen Y, Tang Y, Chen Y (2016) Improved cycling performance of LiNi0.8Co0.15Al0.05O2/Al2O3 with core-shell structure synthesized by a heterogeneous nucleation-and-growth process. Ionics 22(11):2021–2026
Ruan Z, Zhu Y, Teng X (2016) Effect of pre-thermal treatment on the lithium storage performance of LiNi0.8Co0.15Al0.05O2. J Mater Sci 51(3):1400–1408
Wang Z, Liu H, Wu J, Lau W-M, Mei J, Liu H, Liu G (2016) Hierarchical LiNi0.8Co0.15Al0.05O2 plates with exposed {010} active planes as a high performance cathode material for Li-ion batteries. RSC Adv 6(38):32365–32369
Jiang Q, Gao Y, Peng J, Li H, Liu Q, Jiang L, Lu X, Hu A (2018) Effects of polyvinyl alcohol on the electrochemical performance of LiNi0.8Co0.15Al0.05O2 cathode material. J Solid State Electrochem 22(12):3807–3813
Chen T, Wang F, Li X, Yan X, Wang H, Deng B, Xie Z, Qu M (2019) Dual functional MgHPO4 surface modifier used to repair deteriorated Ni-rich LiNi0.8Co0.15Al0.05O2 cathode material. Appl Surf Sci 465:863–870
Luo Z, Zhang H, Yu L, Huang D, Shen J (2019) Improving long-term cyclic performance of LiNi0.8Co0.15Al0.05O2 cathode by introducing a film forming additive. J Electroanal Chem 833:520–526
Li X, Xie Z, Liu W, Ge W, Wang H, Qu M (2015) Effects of fluorine doping on structure, surface chemistry, and electrochemical performance of LiNi0.8Co0.15Al0.05O2. Electrochim Acta 174:1122–1130
Huang B, Li X, Wang Z, Guo H, Xiong X (2014) Synthesis of Mg-doped LiNi0.8Co0.15Al0.05O2 oxide and its electrochemical behavior in high-voltage lithium-ion batteries. Ceram Int 40(8):13223–13230
Yoon S, Jung K-N, Yeon S-H, Jin CS, Shin K-H (2012) Electrochemical properties of LiNi0.8Co0.15Al0.05O2–graphene composite as cathode materials for lithium-ion batteries. J Electroanal Chem 683:88–93
Zhang L, Fu J, Zhang C (2017) Mechanical composite of LiNi0.8Co0.15Al0.05O2/carbon nanotubes with enhanced electrochemical performance for lithium-ion batteries. Nanoscale Res Lett 12:376
Wu N, Wu H, Liu H, Zhang Y (2016) Solvothermal coating LiNi0.8Co0.15Al0.05O2 microspheres with nanoscale Li2TiO3 shell for long lifespan Li-ion battery cathode materials. J Alloys Compd 665:48–56
Liu W, Hu G, Du K, Peng Z, Cao Y, Liu Q (2012) Synthesis and characterization of LiCoO2-coated LiNi0.8Co0.15Al0.05O2 cathode materials. Mater Lett 83:11–13
Liu W, Hu G, Du K, Peng Z, Cao Y (2013) Surface coating of LiNi0.8Co0.15Al0.05O2 with LiCoO2 by a molten salt method. Surf Coat Technol 216:267–272
Du K, Huang J, Cao Y, Peng Z, Hu G (2013) Study of effects on LiNi0.8Co0.15Al0.05O2 cathode by LiNi1/3Co1/3Mn1/3O2 coating for lithium ion batteries. J Alloys Compd 574:377–382
Şahan H, Göktepe H, Patat Ş, Ülgen A (2010) Effect of the Cr2O3 coating on electrochemical properties of spinel LiMn2O4 as a cathode material for lithium battery applications. Solid State Ionics 181(31-32):1437–1444
Li X, Lin Y, Lin Y, Lai H, Huang Z (2012) Surface modification of LiNi1/3Co1/3Mn1/3O2 with Cr2O3 for lithium ion batteries. Rare Metals 31(2):140–144
Xiao L-N, Ding X, Tang Z-F, He X-D, Liao J-Y, Cui Y-H, Chen C-H (2018) Layered LiNi0.8Co0.15Al0.05O2 as cathode material for hybrid Li+/Na+ batteries. J Solid State Electrochem 22(11):3431–3442
Exner KS (2019) Recent advancements towards closing the community gap between electrocatalysis and battery science: the computational lithium electrode and activity-stability volcano plots. ChemSusChem 12(11):2330–2344
Eom J, Kim MG, Cho J (2008) Storage characteristics of LiNi0.8Co0.1+xMn0.1−xO2 (x= 0, 0.03, and 0.06) cathode materials for lithium batteries. J Electrochem Soc 155(3):A239–A245
Lai Y-Q, Xu M, Zhang Z-A, Gao C-H, Wang P, Yu Z-Y (2016) Optimized structure stability and electrochemical performance of LiNi0. 8Co0.15Al0.05O2 by sputtering nanoscale ZnO film. J Power Sources 309:20–26
Han CJ, Yoon JH, Cho WI, Jang H (2004) Electrochemical properties of LiNi0.8Co0.2−xAlxO2 prepared by a sol–gel method. J Power Sources 136(1):132–138
Abraham D, Kawauchi S, Dees D (2008) Modeling the impedance versus voltage characteristics of LiNi0.8Co0.15Al0.05O2. Electrochim Acta 53(5):2121–2129
Exner KS (2017) Constrained ab initio thermodynamics: transferring the concept of surface Pourbaix diagrams in electrocatalysis to electrode materials in lithium-ion batteries. ChemElectroChem 4(12):3231–3237
Exner KS (2018) A short perspective of modeling electrode materials in lithium-ion batteries by the ab initio atomistic thermodynamics approach. J Solid State Electrochem 22(10):3111–3117
Zhang M, Hu G, Liang L, Peng Z, Du K, Cao Y (2016) Improved cycling performance of Li2MoO4-inlaid LiNi0.5Co0.2Mn0.3O2 cathode materials for lithium-ion battery under high cutoff voltage. J Alloys Compd 673:237–248
You Y, Celio H, Li J, Dolocan A, Manthiram A (2018) Modified high-nickel cathodes with stable surface chemistry against ambient air for lithium-ion batteries. Angew Chem Int Ed 57(22):6480–6485
Mohanty D, Dahlberg K, King DM, David LA, Sefat AS, Wood DL, Daniel C, Dhar S, Mahajan V, Lee M (2016) Modification of Ni-rich FCG NMC and NCA cathodes by atomic layer deposition: preventing surface phase transitions for high-voltage lithium-ion batteries. Sci Rep 6(1):26532–26547
Chang M, Wang H, Zheng Y, Li N, Chen S, Wan Y, Yuan F, Shao W, Xu S (2019) Surface modification of hollow microsphere Li1.2Ni1/3Co1/3Mn1/3O2 cathode by coating with CoAl2O4. J Solid State Electrochem 23(2):607–613
Huang B, Li X, Wang Z, Guo H, Shen L, Wang J (2014) A comprehensive study on electrochemical performance of Mn-surface-modified LiNi0.8Co0.15Al0.05O2 synthesized by an in situ oxidizing-coating method. J Power Sources 252:200–207
Makimura Y, Zheng S, Ikuhara Y, Ukyo Y (2012) Microstructural observation of LiNi0.8Co0.15Al0.05O2 after charge and discharge by scanning transmission electron microscopy. J Electrochem Soc 159(7):A1070–A1073
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Loghavi, M.M., Mohammadi-Manesh, H. & Eqra, R. LiNi0.8Co0.15Al0.05O2 coated by chromium oxide as a cathode material for lithium-ion batteries. J Solid State Electrochem 23, 2569–2578 (2019). https://doi.org/10.1007/s10008-019-04342-1
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DOI: https://doi.org/10.1007/s10008-019-04342-1