Abstract
Oxygen-rich activated carbon with a three-dimensional network structure was prepared by chemical activation of coal tar residues with potassium hydroxide and subsequent carbonization treatment. Nanostructured Fe3O4/AC composites were then prepared by simple chemical coprecipitation method and were used as active electrode materials for supercapacitors. The electrochemical behaviors of Fe3O4/AC nanocomposites were characterized by cyclic voltammetry, galvanostatic charge–discharge and electrochemical impedance spectroscopy in 1.0 M Na2SO3 electrolyte. It was shown that the specific capacitance of Fe3O4/AC nanocomposites reached 150 F g−1 at a current density of 3.0 A g−1 and was a great improvement over Fe3O4 or AC alone. Furthermore, as-prepared Fe3O4/AC nanocomposites exhibited long cycle life without obvious capacitance fading even after 1,000 charge/discharge cycles. Compared with pure Fe3O4 and AC, the significant enhanced electrochemical performance of Fe3O4/AC nanocomposites could be reasonably attributed to the positive synergetic effect between Fe3O4 and AC.
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Acknowledgments
This work was supported by the Open Project of Key Laboratory of Solid Waste Treatment and Resource Recycle of Ministry of Education (11zxgk11) and the Foundation from the Technology R&D Program of Sichuan Province (No. 2010GZ0300). We are also grateful for the help of Analytical and Testing Center of Southwest University of Science and Technology.
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Wang, Y., He, P., Zhao, X. et al. Coal tar residues-based nanostructured activated carbon/Fe3O4 composite electrode materials for supercapacitors. J Solid State Electrochem 18, 665–672 (2014). https://doi.org/10.1007/s10008-013-2303-0
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DOI: https://doi.org/10.1007/s10008-013-2303-0