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Tolerance of glucose electrocatalytic oxidation on NiO x /MnO x /GC electrode to poisoning by halides

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Abstract

This paper is devoted to the investigation of the tolerance of glucose oxidation on NiO x /MnO x /GC binary catalyst to poisoning by halide ions. NiO x /MnO x /GC electrode was prepared by the consecutive electrodeposition of MnO x followed by the deposition of NiO x nanoparticles atop the previously deposited MnO x nanoparticles. The electrode was characterized electrochemically and morphologically. Interestingly, experimental results showed that the NiO x /MnO x /GC electrode shows a superior electrocatalytic activity compared with the NiO x /GC electrode and a behavior comparable to the NiO x /GC electrode regarding tolerance to poisoning by halides, even in the presence of high concentrations of Cl− and Br− up to 0.3 M. On the other hand, it was found that iodide ions have a significant effect on glucose electrooxidation under the prevailing operating conditions and even at concentrations lower than those of the other two halide ions.

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Authors and Affiliations

  1. Department of Chemistry, Faculty of Science, Cairo University, Cairo, Egypt

    S. M. El-Refaei, M. M. Saleh & M. I. Awad

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  1. S. M. El-Refaei
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  2. M. M. Saleh
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  3. M. I. Awad
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Correspondence to M. I. Awad.

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El-Refaei, S.M., Saleh, M.M. & Awad, M.I. Tolerance of glucose electrocatalytic oxidation on NiO x /MnO x /GC electrode to poisoning by halides. J Solid State Electrochem 18, 5–12 (2014). https://doi.org/10.1007/s10008-013-2205-1

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  • DOI: https://doi.org/10.1007/s10008-013-2205-1

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