Skip to main content
SpringerLink
Log in

Stripping voltammetry method for determination of manganese as complex with oxine at the carbon paste electrode with and without modification with montmorillonite clay

  • Original Paper
  • Published:
Journal of Solid State Electrochemistry Aims and scope Submit manuscript

Abstract

Oxine (8-hydroxyquinoline) was used as an efficient and selective ligand for stripping voltammetry trace determination of Mn(II). A validated square-wave adsorptive cathodic stripping voltammetry method has been developed for determination of Mn(II) selectively as oxine complex using both the bare carbon paste electrode (CPE) and the modified CPE with 7 % (w/w) montmorillonite-Na clay. Modification of carbon paste with montmorillonite clay was found to greatly enhance its adsorption capacity. Limits of detection of 45 ng l−1 (8.19 × 10−10 mol L−1) and 1.8 ng l−1 (3.28 × 10−11 mol L−1) Mn(II) were achieved using the bare and modified CP electrodes, respectively. The achieved limits of detection of Mn(II) as oxine complex using the modified CPE are much sensitive than the detection limits obtained by most of the reported electrochemical methods. The developed stripping voltammetry method using both electrodes was successfully applied for trace determination of Mn(II) in various water samples without interferences from various organic and inorganic species.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Scheme 1
Fig. 3
Fig. 4
Scheme 2
Fig. 5
Fig. 6
Fig. 7
Fig. 8

Similar content being viewed by others

References

  1. Siegel A, Siegel H (2000) Metal ions in biological systems: manganese and its role in biological processes. CRC Press, Boca Raton

    Google Scholar 

  2. Michalke B (2004) J Chromatogr A 1050:69–76

    Article  CAS  Google Scholar 

  3. Gerber GB, Leonard A, Hantson P (2002) Crit Rev Oncol Hematol 42:25–34

    Article  CAS  Google Scholar 

  4. Pearson GF, Greenway GM (2005) Trends Anal Chem 24:803–809

    Article  CAS  Google Scholar 

  5. Tang B, Han F (2001) Anal Lett 34:1353–1368

    Article  CAS  Google Scholar 

  6. Klamtet J (2006) Nu Sci J 2:165–173

    Google Scholar 

  7. Kumar AP, Reddy PR, Reddy VK (2009) Eurasian J Anal Chem 4:66–75

    Google Scholar 

  8. Abbasi-Tarighat M, Shahbazi E, Niknam K (2013) Food Chem 138:991–997

    Article  CAS  Google Scholar 

  9. Su L, Li JG, Ma HB, Tao GH (2004) Anal Chim Acta 522:281–288

    Article  CAS  Google Scholar 

  10. Pourreza N, Kamran-HeKani S, Rastegarzadeh S (1998) Can J Anal Sci Spectr 43:149–152

    CAS  Google Scholar 

  11. Pohl P, Sergiel I (2010) Microchim Acta 168:9–15

    Article  CAS  Google Scholar 

  12. Truus K, Viitak A, Vaher M, Muinasmaa U, Paasrand K, Tuvikene R, Levandi T (2007) Proc Estonian Acad Sci Chem 56:122–133

    CAS  Google Scholar 

  13. Anjos AP, Ponce LC, Cadore S, Baccan N (2007) Talanta 71:1252–1256

    Article  Google Scholar 

  14. Mohan AM, Mandakolathur SS (2003) J AOAC Int 86:1218–1224

    Google Scholar 

  15. Korn MA, -de Freitas Santos AJ, Jaeger HV, Silva NMS, Spínola Costa AC (2004) J Braz Chem Soc 15:212–218

  16. Cesur H (2003) Turk J Chem 27:307–314

    CAS  Google Scholar 

  17. Milne A, Landing W, Bizimis M, Morton P (2010) Anal Chim Acta 665(2010):200–207

    Article  CAS  Google Scholar 

  18. Chen S, Xiao M, Lu D, Wang Z (2007) Spectrochim Acta Part B 62:1216–1221

    Article  Google Scholar 

  19. Hasegawa S, Kobayashi T, Hasegawa R (2000) Mater Trans JIM 41:841–845

    CAS  Google Scholar 

  20. Sohrin Y, Urushihara S, Nakatsuka S, Kono T, Higo E, Minami T, Norisuye K, Umetani S (2008) Anal Chem 80:6267–6273

    Article  CAS  Google Scholar 

  21. Welz B, Sperling M (1999) Atomic absorption spectrometry, 3rd edn. VCH, Weinheim

    Google Scholar 

  22. Gupta VK, Jain R, Pal MK (2010) Int J Electrochem Sci 5:1164–1178

    CAS  Google Scholar 

  23. Gholivand MB, Gorji M, Joshaghani M (2009) Collect Czech Chem Commun 74:1411–1424

    Article  CAS  Google Scholar 

  24. Colombini MP, Fuoco R (1983) Talanta 30:901–905

    Article  CAS  Google Scholar 

  25. Radhi MM, Tan WT, Ab Rahman MZB, Kassim AB (2010) Int J Electrochem Sci 5:254–266

    CAS  Google Scholar 

  26. Ching YM, Tee TW, Zainal Z (2011) Int J Electrochem Sci 6:5305–5313

    CAS  Google Scholar 

  27. Rezaei B, Ghiaci M, Sedaghat ME (2008) Sensors Actuators B 131:439–447

    Article  CAS  Google Scholar 

  28. Piech R, Baś B, Kubiak WW (2008) J Electroanal Chem 621:43–48

    Article  CAS  Google Scholar 

  29. Ghoneim MM, Hassanein AM, Hammam E, Beltagi AM (2000) Fresenius J Anal Chem 367:378–383

    Article  CAS  Google Scholar 

  30. Locatelli C, Torsi G (2001) J Electroanal Chem 509:80–89

    Article  CAS  Google Scholar 

  31. Yue W, Bange A, Riehl BL, Riehl BD, Johnson JM, Papautsky I, Heineman WR (2012) Electroanalysis 24:1909–1914

    Article  CAS  Google Scholar 

  32. Di J, Zhang F (2003) Talanta 60:31–36

    Article  CAS  Google Scholar 

  33. Jin J-Y, Xu F, Miwa T (2000) Electroanalysis 12:610–615

    Article  CAS  Google Scholar 

  34. Saterlay AJ, Foord JS, Compton RG (1999) Analyst 124:1791–1796

    Article  CAS  Google Scholar 

  35. Khoo SB, Soh MK, Cai Q, Khan MR, Guo SX (1997) Electroanalysis 9:45–51

    Article  CAS  Google Scholar 

  36. Stozhko NY, Inzhevatova OV, Kolyadina LI, Lipunova GN (2005) J Anal Chem 60:163–168

    CAS  Google Scholar 

  37. Filipe OMS, Brett CMA (2003) Talanta 61:643–650

    Article  CAS  Google Scholar 

  38. Rievaj M, Tomcik P, Janosikova Z, Bustin D, Compton RG (2008) Chem Anal 53:153–161

    CAS  Google Scholar 

  39. Zhou J, Neeb R (1994) Fresenius J Anal Chem 350:593–598

    Article  CAS  Google Scholar 

  40. Wang J, Lu J (1995) Talanta 42:331–335

    Article  CAS  Google Scholar 

  41. El-Maali NA, El-Hady DA (1998) Anal Chim Acta 370:239–249

    Article  Google Scholar 

  42. Ghoneim EM (2010) Talanta 15:646–652

    Article  Google Scholar 

  43. Beltagi1 AM, Ismail IM, Ghoneim MM (2013) Am J Anal Chem 4:197–206

    Google Scholar 

  44. Korn MGA, Ferreira AC, Teixeira LSG, Costa ACS (1999) J Braz Chem Soc 10:46–50

    Article  CAS  Google Scholar 

  45. Villalba MM, Davis J (2008) J Solid State Electrochem 12:1245–1254

    Article  CAS  Google Scholar 

  46. Kamal MM, Ahmed SM, Shahata MM, Temerk YM (2002) Anal Bioanal Chem 372:843–848

    Article  CAS  Google Scholar 

  47. Ramenskaya LM, Kraeva OV (2006) Russ J Phys Chem 80:90–94

    Article  CAS  Google Scholar 

  48. Stević MC, Ignjatović LM, Ćirić-Marjanović G, Stanišić SM, Stanković DM, Zima J (2011) Int J Electrochem Sci 6:2509–2525

    Google Scholar 

  49. Patel KB, Kharadi GJ, Nimavat KS (2012) J Chem Pharm Res 4:2422–2428

    CAS  Google Scholar 

  50. Ujinaga T, Takagi O (1975) Bull Inst Chem Res 53:460–463

    Google Scholar 

  51. Devol I, Bardez E (1998) J Colloid Interface Sci 200:241–248

    Article  CAS  Google Scholar 

  52. Campos MLAM, van den Berg CMG (1994) Anal Chim Acta 284:481–496

    Article  Google Scholar 

  53. Yardım Y, Keskin E, Levent A, Ozsoz M, Senturk Z (2010) Talanta 80:1347–1355

    Article  Google Scholar 

  54. Gupta VK, Jain R (2011) Int J Electrochem Sci 6:37–51

    CAS  Google Scholar 

  55. Jirgensons B, Starumans ME (1962) Colloid chemistry. Macmillan, New York

    Google Scholar 

  56. Miller JN (1991) Analyst 116:3–14

    Article  CAS  Google Scholar 

  57. The United States Pharmacopeial Convention (2010) The United States Pharmacopeia, USP 33-NF 28, Rockville, MD

  58. Brum MC, Oliveira JF (2007) Miner Eng 20:945–949

    Article  CAS  Google Scholar 

  59. Wang CS, Boyle E, Bruland KW, Burton JD, Goldberg ED (1983) Trace metals in sea water. Plenum, London

    Book  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Analytical and Electrochemistry Research Unit, Chemistry Department, Faculty of Science, Tanta University, 31527, Tanta, Egypt

    Hanaa S. El-Desoky & Mohamed M. Ghoneim

  2. Department of Chemistry, Faculty of Science, and Center of Excellence in Environmental Studies, King Abdul Aziz University, 21589, Jeddah, Saudi Arabia

    Iqbal M. Ismail

Authors
  1. Hanaa S. El-Desoky
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Iqbal M. Ismail
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mohamed M. Ghoneim
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mohamed M. Ghoneim.

Rights and permissions

Reprints and permissions

About this article

Cite this article

El-Desoky, H.S., Ismail, I.M. & Ghoneim, M.M. Stripping voltammetry method for determination of manganese as complex with oxine at the carbon paste electrode with and without modification with montmorillonite clay. J Solid State Electrochem 17, 3153–3167 (2013). https://doi.org/10.1007/s10008-013-2204-2

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10008-013-2204-2

Keywords

Search

Navigation