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Electrocatalytic oxidation of methanol onto platinum particles decorated nanostructured poly (1,5-diaminonaphthalene) film

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Abstract

In this work, platinum particles decorated nanostructured poly (1,5-diaminonaphthalene) modified glassy carbon electrode (Pt/Nano-PDAN/MGCE) is prepared. The composite catalysts are characterized by scanning electron microscopy, energy dispersive spectroscopy, and electrochemical methods. The electrochemical methanol oxidation reaction is studied at the surface of this modified electrode. At same Pt loading, the Pt/Nano-PDAN/MGCE can act as higher efficient catalyst for methanol oxidation than that Pt/MGCE. Then, the influence of some parameters such as potential scan rates, switching potential, and methanol concentration on its oxidation as well as long-term stability of the modified electrode have studied by electrochemical methods. Also, ability of the modified electrode toward electrocatalytic oxidation of formaldehyde as an intermediate in methanol oxidation has been investigated.

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Authors and Affiliations

  1. Department of Analytical Chemistry, Faculty of Chemistry, University of Mazandaran, 3rd Kilometer of Air Force Road, 47416-95447, Babolsar, Iran

    Jahan Bakhsh Raoof, Reza Ojani & Sayed Reza Hosseini

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  1. Jahan Bakhsh Raoof
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  2. Reza Ojani
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  3. Sayed Reza Hosseini
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Correspondence to Jahan Bakhsh Raoof.

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Raoof, J.B., Ojani, R. & Hosseini, S.R. Electrocatalytic oxidation of methanol onto platinum particles decorated nanostructured poly (1,5-diaminonaphthalene) film. J Solid State Electrochem 16, 2699–2708 (2012). https://doi.org/10.1007/s10008-012-1697-4

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  • DOI: https://doi.org/10.1007/s10008-012-1697-4

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