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A study of the electrochemical behavior of an oxadiazole derivative electrodeposited on multi-wall carbon nanotube-modified electrode and its application as a hydrazine sensor

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Abstract

In this study, an oxadiazole multi-wall carbon nanotube-modified glassy carbon electrode (OMWCNT−GCE) was used as a highly sensitive electrochemical sensor for hydrazine determination. The surface charge transfer rate constant, k s, and the charge transfer coefficient, α, for electron transfer between GCE and electrodeposited oxadiazole were calculated as 19.4 ± 0.5 s−1 and 0.51, respectively at pH = 7.0. The obtained results indicate that hydrazine peak potential at OMWCNT−GCE shifted for 14, 109, and 136 mV to negative values as compared with oxadiazole-modified GCE, MWCNT−GCE, and activated GCE surface, respectively. The electron transfer coefficient, α, and the heterogeneous rate constant, k′, for the oxidation of hydrazine at OMWCNT−GCE were also determined by cyclic voltammetry measurements. Two linear dynamic ranges of 0.6 to 10.0 μM and 10.0 to 400.0 μM and detection limit of 0.17 μM for hydrazine determination were evaluated using differential pulse voltammetry. In addition, OMWCNT−GCE was shown to be successfully applied to determine hydrazine in various water samples.

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Acknowledgments

The authors express their appreciation to the Islamic Azad University (Yazd) Research Council for financial support for this work.

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Authors and Affiliations

  1. Department of Chemistry, Islamic Azad University, Yazd Branch, Yazd, Iran

    Navid Nasirizadeh & Mohammad R. Ahmadzadeh

  2. Department of Chemistry, Yazd University, P.O. Box 89195-741, Yazd, Iran

    Hamid R. Zare

  3. Department of Chemistry, Shahid Beheshti University, Tehran, Iran

    Ali R. Fakhari & Hamid Ahmar

  4. Young Researchers Club, Islamic Azad University, Khatam Branch, Yazd, Iran

    Amin Naeimi

Authors
  1. Navid Nasirizadeh
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  2. Hamid R. Zare
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  3. Ali R. Fakhari
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  4. Hamid Ahmar
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  5. Mohammad R. Ahmadzadeh
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  6. Amin Naeimi
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Correspondence to Navid Nasirizadeh.

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Nasirizadeh, N., Zare, H.R., Fakhari, A.R. et al. A study of the electrochemical behavior of an oxadiazole derivative electrodeposited on multi-wall carbon nanotube-modified electrode and its application as a hydrazine sensor. J Solid State Electrochem 15, 2683–2693 (2011). https://doi.org/10.1007/s10008-010-1259-6

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  • DOI: https://doi.org/10.1007/s10008-010-1259-6

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